公开(公告)号：US4209378A

公开(公告)日：1980-06-24

申请号：US36379

申请日：1979-05-04

申请人： Hiroshi Schinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto ,  Toshinobu Furutani ,  Hiroshi Wakizaka

发明人： Hiroshi Schinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto ,  Toshinobu Furutani ,  Hiroshi Wakizaka

IPC分类号： G01N27/409 ,  G01N27/407 ,  G01N27/413 ,  H01M8/12 ,  H01M12/06 ,  G01N27/58

CPC分类号： G01N27/4076 ,  H01M12/06 ,  H01M8/12

摘要： Low temperature operability of an oxygen sensing element, which comprises a solid electrolyte member composed of sintered material, and a means for providing a reference oxygen partial pressure, composed of a sintered product of a finely divided metal or metal-metal oxide mixture powder and being completely embedded within the solid electrolyte member, is improved by the incorporation of from 0.5 to 10% by weight, based on the total weight of the sintered product, of a finely divided platinum group metal powder in the sintered product of the reference oxygen partial pressure-providing means.

摘要翻译： 氧传感元件的低温可操作性，其包括由烧结材料构成的固体电解质构件和用于提供参考氧分压的装置，其由细碎的金属或金属 - 金属氧化物混合物粉末的烧结产物组成， 完全嵌入在固体电解质构件内，通过在参考氧分压的烧结产物中加入基于烧结产品的总重量的0.5至10重量％的细碎的铂族金属粉末来改善 提供手段。

公开(公告)号：US4265930A

公开(公告)日：1981-05-05

申请号：US50057

申请日：1979-06-19

申请人： Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto ,  Toshinobu Furutani ,  Hiroshi Wakizaka

发明人： Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto ,  Toshinobu Furutani ,  Hiroshi Wakizaka

IPC分类号： G01N27/409 ,  B05D1/10 ,  C23C4/04 ,  G01N27/407 ,  H01M8/12 ,  B05D1/08 ,  B05D5/12

CPC分类号： G01N27/4077 ,  H01M4/9058

摘要： A protective layer of a refractory material deposited on a metal electrode layer of an oxygen sensing element is improved by a process comprising forming the protective layer onto the surface of the metal electrode layer by plasma spray coating the surface of the metal electrode layer, first with a refractory material powder at a position of a prescribed distance from a plasma spray coating device and at a prescribed electric power, and second, with a refractory material powder having the same particle size and composition as said refractory material powder used in the first plasma spray coating at a position of a distance greater than said prescribed distance and/or at an electric power lower than said prescribed electric power.

摘要翻译： 沉积在氧气感测元件的金属电极层上的耐火材料的保护层通过包括通过等离子体喷涂金属电极层的表面而形成保护层到金属电极层的表面上的方法得到改进，首先用 在与等离子体喷涂装置规定距离的位置和规定的电力下的耐火材料粉末，其次是与第一等离子体喷涂中使用的与所述耐火材料粉末相同的粒度和组成的耐火材料粉末 在大于所述规定距离的距离处和/或低于所述规定电力的电力下进行涂覆。

公开(公告)号：US4299627A

公开(公告)日：1981-11-10

申请号：US72822

申请日：1979-09-06

申请人： Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto ,  Toshinobu Furutani ,  Hiroshi Wakizaka

发明人： Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto ,  Toshinobu Furutani ,  Hiroshi Wakizaka

IPC分类号： G01N27/409 ,  B22F7/02 ,  B22F7/06 ,  G01N27/407 ,  B22F3/00 ,  B22F7/00

CPC分类号： G01N27/4073 ,  B22F7/06 ,  G01N27/4076 ,  Y10T428/1209

摘要： An oxygen sensing element capable of measuring partial pressures of oxygen in sample gases, which element has a solid electrolyte member having totally embedded therein a means for providing a reference partial pressure of oxygen composed of a sintered product of a finely divided metal or metal-metal oxide mixture and having a lead-out wire connected thereto is prepared by a method wherein: p1 (a) a part of the finely divided solid electrolyte material is compression-molded to form a provisional solid electrolyte member having a hole;(b) a provisional product of the reference oxygen partial pressure-providing means is formed in the hole of the provisional solid electrolyte member from the finely divided metal or metal-metal oxide mixture;(c) the remaining part of the finely divided solid electrolyte material is piled up on the provisional reference oxygen partial pressure-providing means product, followed by compression molding the piled up solid electrolyte material to form an integrated structure comprising the solid electrolyte member having totally embedded therein the provisional reference oxygen partial pressure-providing means;(d) the integrated structure is sintered in a non-oxidizing atmosphere at approximately 1,350.degree. to 1,500.degree. C.; and,(e) a layer or layers of an external conductive metal electrode or electrodes is formed on at least a part of the exterior surface of the sintered product.

摘要翻译： 一种氧气感测元件，其能够测量样品气体中的氧分压，该元件具有完全嵌入其中的固体电解质构件，用于提供由细碎金属或金属金属的烧结产物构成的参考分压 氧化物混合物并且具有连接到其上的引出线通过以下方法制备：其中：p1（a）一部分细分散的固体电解质材料被压缩模制以形成具有孔的临时固体电解质构件; （b）参考氧分压提供装置的临时产品由微细金属或金属 - 金属氧化物混合物形成在临时固体电解质构件的孔中; （c）将细碎的固体电解质材料的剩余部分堆积在临时参考氧分压提供装置产品上，然后将堆积的固体电解质材料压缩成型，形成整体结构，该结构包括固体电解质构件， 嵌入临时参考氧分压提供装置; （d）一体化结构在非氧化性气氛中烧结约1350〜1500℃。 和（e）在烧结产品的外表面的至少一部分上形成一层或多层外部导电金属电极或电极。

公开(公告)号：US4209377A

公开(公告)日：1980-06-24

申请号：US27832

申请日：1979-04-06

申请人： Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto ,  Toshinobu Furutani ,  Hiroshi Wakizaka

发明人： Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto ,  Toshinobu Furutani ,  Hiroshi Wakizaka

IPC分类号： G01N27/409 ,  G01N27/407 ,  G01N27/413 ,  H01M8/12 ,  H01M12/06 ,  G01N27/58

CPC分类号： G01N27/4076 ,  H01M12/06 ,  H01M8/12

摘要： The high temperature durability of an oxygen sensing element, which comprises a solid electrolyte member composed of sintered material, and a means for providing a reference oxygen partial pressure, composed of a sintered product of a finely divided metal or metal-metal oxide mixture powder and being completely embedded within the solid electrolyte member, is improved by incorporating in the finely divided metal or metal-metal oxide mixture powder an antisintering material and a pore-forming material capable of subliming or being decomposed, thereby to generate gas upon sintering. The amounts of the antisintering material and the pore-forming material are from 5 to 70% by weight and from 20 to 80% by weight, respectively, based on the total weight of these additives-incorporated metal or metal-metal oxide mixture. The low temperature operation capability of the oxygen sensing element is improved by further incorporating therein a minor amount of a platinum group metal.

摘要翻译： 包含由烧结材料构成的固体电解质构件的氧传感元件的高温耐久性和用于提供参考氧分压的装置，其由细碎金属或金属 - 金属氧化物混合物粉末的烧结产物和 通过在细分金属或金属 - 金属氧化物混合物粉末中掺入防结晶材料和能够升华或分解的成孔材料，从而在烧结时产生气体，从而改善了固体电解质成分的完全嵌入。 基于这些掺入添加剂的金属或金属 - 金属氧化物混合物的总重量，抗结晶材料和造孔材料的量分别为5-70重量％和20-80重量％。 氧传感元件的低温操作能力通过进一步掺入少量的铂族金属来提高。

公开(公告)号：US4284486A

公开(公告)日：1981-08-18

申请号：US132415

申请日：1980-03-21

申请人： Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Hideo Kamiya ,  Hiroshi Wakizaka ,  Toshinobu Furutani

发明人： Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Hideo Kamiya ,  Hiroshi Wakizaka ,  Toshinobu Furutani

IPC分类号： G01N27/409 ,  G01N27/407 ,  G01N27/413 ,  G01N27/58

CPC分类号： G01N27/4073 ,  G01N27/4075 ,  Y10T29/49002

摘要： A solid pole oxygen sensor wherein an oxygen sensor element is composed of a solid pole with one end of a lead wire buried therein; an internal electrode formed on the outside surface of the solid pole; a solid electrolyte enclosing the electrode to constitute a solid pole assembly as a column with a projection at its top; and a platinum electrode separated from the lead wire. The oxygen sensor element is so secured to an almost cylindrical ceramic insulator by means of adhesive or the like that the upper top side of the oxygen sensor element having the projection is matched to a recess at the tip of the cylindrical ceramic insulator and a pair of electroconductive zones provided on the side wall of the cylindrical ceramic insulator are electrically connected with the platinum electrode and the lead wire. A process of manufacturing a solid oxygen sensor is also disclosed.

摘要翻译： 固体氧传感器，其中氧传感器元件由固体极组成，其中埋入其中的引线的一端; 形成在固体极的外表面上的内部电极; 封闭电极的固体电解质构成固体极组件作为其顶部具有突起的柱; 以及与引线分离的铂电极。 氧传感器元件通过粘合剂等固定到几乎圆柱形的陶瓷绝缘体上，使得具有突起的氧传感器元件的上顶侧与圆柱形陶瓷绝缘体的尖端处的凹部匹配， 设置在圆筒形陶瓷绝缘体的侧壁上的导电区域与铂电极和引线电连接。 还公开了制备固体氧传感器的方法。

公开(公告)号：US4304651A

公开(公告)日：1981-12-08

申请号：US103472

申请日：1979-12-14

申请人： Hiroshi Wakizaka ,  Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto

发明人： Hiroshi Wakizaka ,  Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto

IPC分类号： G01N27/409 ,  G01N27/407 ,  G01N27/413 ,  G01N27/58

CPC分类号： G01N27/4073 ,  G01N27/4075

摘要： A solid pole oxygen sensor having a solid pole, in which one end of a lead wire of platinum or platinum rhodium is buried, tightly covered by a solid electrolyte and pressure-molded into a circular plate, which is dried and then fired in a reducing atmosphere. The surface of a sintered mass thus obtained is plated or baked to form a platinum electrode, and the oxygen sensor element thus obtained is secured by a bonding agent to the tip of a cylindrical ceramic insulator having electroconductive zones to be connected to the platinum electrode in such a manner that the circular face of the circular plate-shaped oxygen sensor element is in contact with the tip surface of the cylindrical ceramic insulator.

摘要翻译： 具有固体极的固体极氧传感器，其中埋有铂或铂铑的引线的一端，被固体电解质密封并压制成圆形板，其被干燥，然后以还原 大气层。 将由此获得的烧结体的表面进行电镀或烘烤以形成铂电极，并将由此获得的氧传感器元件通过粘合剂固定到具有导电区域的圆柱形陶瓷绝缘体的尖端，以连接到铂电极 圆板状氧传感器元件的圆形面与筒状陶瓷绝缘体的前端面接触的方式。

公开(公告)号：US4292157A

公开(公告)日：1981-09-29

申请号：US91883

申请日：1979-11-07

申请人： Hiroshi Wakizaka ,  Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto

发明人： Hiroshi Wakizaka ,  Hiroshi Shinohara ,  Yasuhiro Otsuka ,  Shinichi Matsumoto

IPC分类号： G01N27/409 ,  G01N27/407 ,  G01N27/413 ,  G01N27/58

CPC分类号： G01N27/4073 ,  G01N27/4075 ,  Y10T29/49002

摘要： A solid pole oxygen sensor in which one end of a lead wire of platinum or platinum/rhodium is buried in a solid pole and the surfaces of the solid pole and the lead wire are coated with an electroconductive paste. The solid pole is wrapped or encased in a solid electrolyte, pressure-molded into a pellet, which is dried and then fired in a reducing atmosphere. The surface of the sintered mass thus obtained is then plated or baked to form a platinum electrode, and the oxygen sensor element thus obtained is fitted or secured to the tip of an approximately cylindrical ceramic insulator equipped with electroconductive zones to be connected to the platinum electrode.

摘要翻译： 一种固体极氧传感器，其中铂或铂/铑的引线的一端被埋在固体极中，并且固体极和引线的表面涂覆有导电浆料。 固体极被包裹或封装在固体电解质中，压制成颗粒，将其干燥，然后在还原气氛中烧制。 然后将如此获得的烧结体的表面进行电镀或烘烤以形成铂电极，并将由此获得的氧传感器元件装配或固定到装有导电区域的近似圆柱形的陶瓷绝缘体的尖端以连接到铂电极 。

公开(公告)号：US5447624A

公开(公告)日：1995-09-05

申请号：US223696

申请日：1994-04-06

申请人： Takanobu Kawai ,  Hiroshi Wakizaka ,  Hiroyuki Moriyama ,  Katsuo Komiya ,  Hiroshi Ichikawa ,  Akira Yokoyama

发明人： Takanobu Kawai ,  Hiroshi Wakizaka ,  Hiroyuki Moriyama ,  Katsuo Komiya ,  Hiroshi Ichikawa ,  Akira Yokoyama

IPC分类号： B01J20/281 ,  G01N30/52 ,  G01N30/88 ,  B01D15/08

CPC分类号： G01N30/482 ,  G01N30/52 ,  B01J2220/54 ,  G01N2030/524

摘要： A microspherical packing for liquid chromatography, which comprises a porous silicon carbide having numerous through-pores, and a process for producing said microspherical packing.

摘要翻译： 一种用于液相色谱的微球形填料，其包含具有多个通孔的多孔碳化硅，以及用于制备所述微球形填料的方法。