摘要:
A membrane-electrode assembly 1 having an anode catalyst layer 20 and a cathode catalyst layer 30 which are mutually opposing and a polymer electrolyte membrane 10 formed between the anode catalyst layer 20 and cathode catalyst layer 30, wherein the anode catalyst layer 20 has a plurality of polymer layers 20a, 20b containing a polymer in which a repeating unit (a) with an ion-exchange group and a repeating unit (b) with no ion-exchange group are arranged in a random or block fashion, and the polymer in the polymer layer 20a in closest proximity to the polymer electrolyte membrane 10 is the polymer with the lowest block character of the repeating units (a) and (b).
摘要:
A membrane-electrode assembly 1 having an anode catalyst layer 20 and cathode catalyst layer 30 that are mutually opposing and a polymer electrolyte membrane 10 formed between the anode catalyst layer 20 and cathode catalyst layer 30, wherein the anode catalyst layer 20 is composed of a plurality of ion-exchange layers 20a and 20b with different layer ion-exchange capacities, and of the plurality of ion-exchange layers 20a and 20b, ion-exchange layer A (20a) having the smallest layer ion-exchange capacity is situated more toward the polymer electrolyte membrane 10 side than ion-exchange layer B (20b) having the largest layer ion-exchange capacity, and the ratio of the layer ion-exchange capacity of the ion-exchange layer B (20b) with respect to the layer ion-exchange capacity of the ion-exchange layer A (20a) is 1.7 or greater.
摘要:
A membrane-electrode assembly (MEA) comprising an anode catalyst layer and cathode catalyst layer placed opposite each other, and a polymer electrolyte membrane formed between the anode catalyst layer and cathode catalyst layer, as well as a fuel cell comprising the same. Either or both the anode catalyst layer and cathode catalyst layer comprise: a catalyst-supported material, having at least one catalyst substance selected from among platinum and platinum-containing alloys and a support on which the catalyst substance is supported; and a hydrocarbon-based polymer electrolyte. The catalyst-supporting ratio of the catalyst-supported material is 60 wt % or greater.
摘要:
A membrane-electrode assembly comprising an anode catalyst layer and cathode catalyst layer placed each other, and a polymer electrolyte membrane formed between the anode catalyst layer and cathode catalyst layer. The polymer electrolyte membrane comprises: a hydrocarbon-based polymer electrolyte, and the anode catalyst layer and cathode catalyst layer both comprise a catalyst-supported material, having at least one catalyst substance selected from among platinum and platinum-containing alloys and a support on which the catalyst substance is supported; and a polymer electrolyte. Either or both the anode catalyst layer and cathode catalyst layer have a catalyst-supporting ratio of 60 wt % or greater in the catalyst-supported material.
摘要:
A membrane-electrode assembly for a solid polymer fuel cell, which comprises a mutually opposing anode catalyst layer and cathode catalyst layer with a polymer electrolyte membrane formed between the anode catalyst layer and cathode catalyst layer, wherein the anode catalyst layer and cathode catalyst layer each contain a catalyst and a hydrocarbon-based polymer electrolyte with an ion-exchange group. If the ion-exchange group density of the anode catalyst layer is represented as α [μeq/cm2] and the ion-exchange group density of the cathode catalyst layer is represented as β [μeq/cm2], then α and β satisfy the following relational expressions (1), (2) and (3). β/α>1.0 (1) α
摘要:
A membrane-electrode assembly, containing an electrode catalyst containing a base metal complex, in which exchange current density i0 obtained from a Tafel plot, which is related to current density and voltage, is 5.0×10−4 Acm−2 or more, and in which a Tafel slope obtained from the Tafel plot is 450 mV/decade or less; anda membrane-electrode assembly, containing catalyst layers each containing an electrode catalyst on both sides of an electrolyte membrane, in which at least one of the catalyst layers comprises a non-noble metal-based electrode catalyst, and in which the electrolyte membrane is a hydrocarbon-based electrolyte membrane.
摘要:
A polymer electrolyte membrane having excellent mechanical natures is provided. The polymer electrolyte membrane has an elastic modulus at 23° C. and a relative humidity of 50% of 400 MPa to 900 MPa and comprises at least one polymer, all of which have an aromatic ring on their main chain, at least one of which has an aliphatic chain on its main chain and at least one of which is a polymer electrolyte.
摘要:
An electromagnetic wave propagation device includes multiple planar propagation media each formed by laminating at least one planar conductor and at least one planar dielectric, multiple transceivers for transmitting and receiving information among electronic apparatuses, and a first interface for transmitting and receiving the electromagnetic wave between the transceivers and the planar propagation media. Planar dielectric spacers are provided for isolating the multiple planar propagation media from one another. The planar propagation medium is disposed to have an overlapped part with at least the other of the planar propagation media so that an obverse face of the medium and a reverse face of the other medium are at least partially overlapped with each other. The planar conductor is provided with an electromagnetic wave linking unit at the overlapped part that transmits and receives the electromagnetic wave between the planar propagation media.
摘要:
In a millimeter waveband transceiver using an antenna and a waveguide for a connection line, it is necessary to perform transmission mode line conversion between TEM waves of a microstrip line and VTE01 mode waves of the waveguide. There is a limit to reducing the conversion loss using only a matching box for connecting the microstrip line with the waveguide. In a transmission mode line transducer for converting between the TEM waves of the microstrip line and the VTE01 mode waves of the waveguide, if the cross-sections are substantially the same size, in the case of a 50Ω microstrip line when the characteristic impedance of the waveguide is about 80%, i.e., 40Ω, the line conversion loss can be optimized. Therefore, the microstrip line is connected with the waveguide using a λ/4 matching box via a ridged waveguide having a low impedance and a length of λ/16 or less.
摘要:
In a millimeter waveband transceiver using an antenna and a waveguide for a connection line, it is necessary to perform transmission mode line conversion between TEM waves of a microstrip line and VTE01 mode waves of the waveguide. There is a limit to reducing the conversion loss using only a matching box for connecting the microstrip line with the waveguide. In a transmission mode line transducer for converting between the TEM waves of the microstrip line and the VTE01 mode waves of the waveguide, if the cross-sections are substantially the same size, in the case of a 50Ω microstrip line when the characteristic impedance of the waveguide is about 80%, i.e., 40Ω, the line conversion loss can be optimized. Therefore, the microstrip line is connected with the waveguide using a λ/4 matching box via a ridged waveguide having a low impedance and a length of λ/16 or less.