公开(公告)号：US08431289B2

公开(公告)日：2013-04-30

申请号：US12825867

申请日：2010-06-29

申请人： Hiroyuki Otaki ,  Toshio Yoshihara ,  Yoshihito Maeno

发明人： Hiroyuki Otaki ,  Toshio Yoshihara ,  Yoshihito Maeno

IPC分类号： G03C1/02

CPC分类号： G03F7/038 ,  G03F7/001 ,  G03F7/0046 ,  G03F7/027 ,  G03H1/02 ,  G03H1/0248 ,  G03H1/0252 ,  G03H2250/10 ,  G03H2260/12

摘要： The volume hologram recording photosensitive composition provided by the present invention contains at least a fluorine-contained photoreactive compound represented by the following formula (1): R1—R3—(CF2)n-R4—R2 wherein R1 and R2 are photoreactive groups which can be bonded to each other by photoreaction, and each of R3 and R4 is independently a single bond or a bivalent hydrocarbon group having 1 to 5 carbon atoms, and n is an integer of 1 or more. This volume hologram recording photosensitive composition is used to form a recording section of a recording medium, and then the section is exposed to light, whereby a bright volume hologram can be obtained.

摘要翻译： 由本发明提供的体积全息记录光敏组合物至少含有由下式（1）表示的含氟光反应性化合物：R1-R3-（CF2）n-R4-R2，其中R1和R2是可以 通过光反应彼此键合，R3和R4各自独立地为单键或碳原子数为1〜5的二价烃基，n为1以上的整数。 该体积全息记录光敏组合物用于形成记录介质的记录部分，然后将该部分曝光，由此可以获得明亮的体积全息图。

公开(公告)号：US07629086B2

公开(公告)日：2009-12-08

申请号：US12056062

申请日：2008-03-26

申请人： Hiroyuki Otaki ,  Toshio Yoshihara

发明人： Hiroyuki Otaki ,  Toshio Yoshihara

IPC分类号： G03H1/02

CPC分类号： G03F7/027 ,  G03F7/001 ,  G03F7/0757 ,  G03F7/0758 ,  G03H1/02 ,  G03H2260/12

摘要： A photosensitive composition and A photosensitive medium for volume hologram recording comprises a photopolymerization reactive compound (a monomer) and any one of the following binder: (a) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 1 “R1m M1 (OR2)n” and an ethylenic monomer and/or its hydrolyzed polycondensate; (b) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 3 “R4m Si(OR5)n” and an ethylenic monomer and/or its hydrolyzed polycondensate; and (c) a binder resin bonded to a metal or a combination use of a binder resin containing a hydroxyl group and/or carboxyl group and a metal chelate compound.

摘要翻译： 用于体积全息记录的光敏组合物和A感光性介质包括光聚合反应性化合物（单体）和以下粘合剂中的任一种：（a）有机 - 无机杂化聚合物，其可通过使式1的有机金属化合物“R1m M1 （OR2）n“和烯属单体和/或其水解缩聚物; （b）通过使式3“R4m Si（OR5）n”的有机金属化合物与乙烯性单体和/或其水解缩聚物共聚得到的有机 - 无机杂化聚合物; 和（c）粘合到金属上的粘合剂树脂或包含羟基和/或羧基的粘合剂树脂和金属螯合物的组合使用。

公开(公告)号：US07550234B2

公开(公告)日：2009-06-23

申请号：US11985803

申请日：2007-11-16

申请人： Hiroyuki Otaki ,  Toshio Yoshihara

发明人： Hiroyuki Otaki ,  Toshio Yoshihara

IPC分类号： G03H1/02 ,  G03C1/73 ,  G03F7/027

CPC分类号： G03F7/027 ,  G03F7/001 ,  G03F7/0757 ,  G03F7/0758 ,  G03H1/02 ,  G03H2260/12

摘要： A photosensitive composition and A photosensitive medium for volume hologram recording comprises a photopolymerization reactive compound (a monomer) and any one of the following binder: (a) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 1 “R1m M1(OR2)n” and an ethylenic monomer and/or its hydrolyzed polycondensate; (b) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 3 “R4m Si(OR5)n” and an ethylenic monomer and/or its hydrolyzed polycondensate; and (c) a binder resin bonded to a metal or a combination use of a binder resin containing a hydroxyl group and/or carboxyl group and a metal chelate compound.

摘要翻译： 用于体积全息记录的光敏组合物和A感光性介质包括光聚合反应性化合物（单体）和以下粘合剂中的任一种：（a）有机 - 无机杂化聚合物，其可通过使式1的有机金属化合物“R1m M1 （OR2）n“和烯属单体和/或其水解缩聚物; （b）通过使式3“R4m Si（OR5）n”的有机金属化合物与乙烯性单体和/或其水解缩聚物共聚得到的有机 - 无机杂化聚合物; 和（c）粘合到金属上的粘合剂树脂或包含羟基和/或羧基的粘合剂树脂和金属螯合物的组合使用。

公开(公告)号：US07323275B2

公开(公告)日：2008-01-29

申请号：US10072201

申请日：2002-02-07

申请人： Hiroyuki Otaki ,  Toshio Yoshihara

发明人： Hiroyuki Otaki ,  Toshio Yoshihara

IPC分类号： G03H1/02

CPC分类号： G03F7/027 ,  G03F7/001 ,  G03F7/0757 ,  G03F7/0758 ,  G03H1/02 ,  G03H2260/12

摘要： A photosensitive composition and A photosensitive medium for volume hologram recording comprises a photopolymerization reactive compound (a monomer) and any one of the following binder: (a) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 1 “R1m M1 (OR2)” and an ethylenic monomer and/or its hydrolyzed polycondensate; (b) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 3 “R4m Si (OR5)n” and an ethylenic monomer and/or its hydrolyzed polycondensate; and (c) a binder resin bonded to a metal or a combination use of a binder resin containing a hydroxyl group and/or carboxyl group and a metal chelate compound.

摘要翻译： 用于体积全息记录的光敏组合物和A感光性介质包括光聚合反应性化合物（单体）和以下粘合剂中的任一种：（a）有机 - 无机杂化聚合物，其通过使式1的有机金属化合物“ （OR 2）和烯属单体和/或其水解缩聚物;和/或其水解缩聚物; （b）有机 - 无机杂化聚合物，其通过使式3“R”4 Si（OR 5）n“的有机金属化合物与烯属单体和/ 或其水解缩聚物; 和（c）粘合到金属上的粘合剂树脂或包含羟基和/或羧基的粘合剂树脂和金属螯合物的组合使用。

公开(公告)号：US07521155B2

公开(公告)日：2009-04-21

申请号：US10458563

申请日：2003-06-10

申请人： Hiroyuki Otaki ,  Toshio Yoshihara ,  Tetsuya Toshine

发明人： Hiroyuki Otaki ,  Toshio Yoshihara ,  Tetsuya Toshine

IPC分类号： G03H1/02

CPC分类号： G03H1/0248 ,  G03H1/0252 ,  G03H2240/50 ,  G03H2250/10 ,  G03H2250/42 ,  G03H2260/12

摘要： It is a main object of the present invention to provide a volume hologram layer with good foil cutting property which is used for a volume hologram transfer foil and the like. The present invention provides a volume hologram layer wherein when the layer thickness thereof is 20 μm, breaking strength is in a range from 10 MPa to 30 MPa and breaking strain is in a range from 0.1% to 3% at 25° C., and breaking strength is in a range from 0.1 MPa to 1 MPa and breaking strain is in a range from 0.1% to 5% at 130° C., to thereby solve the above problem.

摘要翻译： 本发明的主要目的是提供一种用于体积全息图转印箔等的具有良好箔切割性能的体积全息图层。 本发明提供一种体积全息图层，其中当其厚度为20μm时，断裂强度在10MPa至30MPa的范围内，断裂应变在25℃为0.1％至3％的范围内，并且 断裂强度在0.1MPa〜1MPa的范围内，断裂应变在130℃为0.1％〜5％的范围，从而解决了上述问题。

公开(公告)号：US20080248402A1

公开(公告)日：2008-10-09

申请号：US12056062

申请日：2008-03-26

申请人： Hiroyuki Otaki ,  Toshio Yoshihara

发明人： Hiroyuki Otaki ,  Toshio Yoshihara

IPC分类号： G03F7/004

CPC分类号： G03F7/027 ,  G03F7/001 ,  G03F7/0757 ,  G03F7/0758 ,  G03H1/02 ,  G03H2260/12

摘要： A photosensitive composition and A photosensitive medium for volume hologram recording comprises a photopolymerization reactive compound (a monomer) and any one of the following binder: (a) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 1 “R1mM1(OR2)n” and an ethylenic monomer and/or its hydrolyzed polycondensate; (b) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 3 “R4mSi(OR5)n” and an ethylenic monomer and/or its hydrolyzed polycondensate; and (c) a binder resin bonded to a metal or a combination use of a binder resin containing a hydroxyl group and/or carboxyl group and a metal chelate compound.

摘要翻译： 用于体积全息记录的光敏组合物和A感光性介质包括光聚合反应性化合物（单体）和以下粘合剂中的任一种：（a）有机 - 无机杂化聚合物，其通过使式1的有机金属化合物“ （OR 2）n“和烯属单体和/或其水解缩聚物;和/或其水解缩聚物; （b）有机 - 无机杂化聚合物，其通过使式3“R”4 Si（OR 5）n“的有机金属化合物与烯属单体和/或 其水解缩聚物; 和（c）粘合到金属上的粘合剂树脂或包含羟基和/或羧基的粘合剂树脂和金属螯合物的组合使用。

公开(公告)号：US20080131786A1

公开(公告)日：2008-06-05

申请号：US11985803

申请日：2007-11-16

申请人： Hiroyuki Otaki ,  Toshio Yoshihara

发明人： Hiroyuki Otaki ,  Toshio Yoshihara

IPC分类号： G03F7/004

CPC分类号： G03F7/027 ,  G03F7/001 ,  G03F7/0757 ,  G03F7/0758 ,  G03H1/02 ,  G03H2260/12

摘要： A photosensitive composition and A photosensitive medium for volume hologram recording comprises a photopolymerization reactive compound (a monomer) and any one of the following binder: (a) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 1 “R1mM1(OR2)n” and an ethylenic monomer and/or its hydrolyzed polycondensate; (b) an organic-inorganic hybrid polymer obtainable by copolymerizing an organometallic compound of the formula 3 “R4mSi(OR5)n” and an ethylenic monomer and/or its hydrolyzed polycondensate; and (c) a binder resin bonded to a metal or a combination use of a binder resin containing a hydroxyl group and/or carboxyl group and a metal chelate compound.

摘要翻译： 用于体积全息记录的光敏组合物和A感光性介质包括光聚合反应性化合物（单体）和以下粘合剂中的任一种：（a）有机 - 无机杂化聚合物，其通过使式1的有机金属化合物“ （OR 2）n“和烯属单体和/或其水解缩聚物;和/或其水解缩聚物; （b）有机 - 无机杂化聚合物，其通过使式3“R”4 Si（OR 5）n“的有机金属化合物与烯属单体和/或 其水解缩聚物; 和（c）粘合到金属上的粘合剂树脂或包含羟基和/或羧基的粘合剂树脂和金属螯合物的组合使用。

公开(公告)号：US07824822B2

公开(公告)日：2010-11-02

申请号：US10615041

申请日：2003-07-08

申请人： Hiroyuki Otaki ,  Toshio Yoshihara ,  Yoshihito Maeno

发明人： Hiroyuki Otaki ,  Toshio Yoshihara ,  Yoshihito Maeno

IPC分类号： G03H1/02

CPC分类号： G03F7/038 ,  G03F7/001 ,  G03F7/0046 ,  G03F7/027 ,  G03H1/02 ,  G03H1/0248 ,  G03H1/0252 ,  G03H2250/10 ,  G03H2260/12

摘要： The volume hologram recording photosensitive composition provided by the present invention contains at least a fluorine-contained photoreactive compound represented by the following formula (1): R1—R3—(CF2)n-R4—R2 wherein R1 and R2 are photoreactive groups which can be bonded to each other by photoreaction, and each of R3 and R4 is independently a single bond or a bivalent hydrocarbon group having 1 to 5 carbon atoms, and n is an integer of 1 or more. This volume hologram recording photosensitive composition is used to form a recording section of a recording medium, and then the section is exposed to light, whereby a bright volume hologram can be obtained.

摘要翻译： 由本发明提供的体积全息记录光敏组合物至少含有由下式（1）表示的含氟光反应性化合物：R1-R3-（CF2）n-R4-R2，其中R1和R2是可以 通过光反应彼此键合，R3和R4各自独立地为单键或碳原子数为1〜5的二价烃基，n为1以上的整数。 该体积全息记录光敏组合物用于形成记录介质的记录部分，然后将该部分曝光，由此可以获得明亮的体积全息图。

公开(公告)号：US07018744B2

公开(公告)日：2006-03-28

申请号：US10228676

申请日：2002-08-27

申请人： Hiroyuki Otaki ,  Toshio Yoshihara

发明人： Hiroyuki Otaki ,  Toshio Yoshihara

IPC分类号： G03H1/04

CPC分类号： G03H1/0248 ,  G03F7/001 ,  G03F7/027 ,  G03F7/033 ,  G03H2001/0264 ,  G03H2260/12 ,  G11B7/24044 ,  G11B7/245

摘要： The present invention provides a volume type hologram recording photosensitive composition. A type (i) composition comprises one or more photopolymerizable compounds, a heat-curable compound and a heat-curing crosslinking agent, wherein the heat-curing crosslinking agent is a latent heat-curing crosslinking agent which is not reacted in an interference exposure process, is not reacted at the heating temperature used in a refractive index-modulation promoting process and becomes active at the heating temperature used in a heat-curing process. A type (ii) composition further comprises a binder resin beside the type (i) volume type composition.

公开(公告)号：US06849149B2

公开(公告)日：2005-02-01

申请号：US10254934

申请日：2002-09-26

申请人： Hiroyuki Otaki ,  Kenji Ueda ,  Fumiko Noujima

发明人： Hiroyuki Otaki ,  Kenji Ueda ,  Fumiko Noujima

IPC分类号： G03H1/04 ,  G03H1/18 ,  B32B31/00 ,  G03H1/00

CPC分类号： G03H1/041 ,  G03H1/0011 ,  G03H1/0236 ,  G03H1/0248 ,  G03H1/18 ,  G03H2001/187 ,  G03H2240/50 ,  G03H2250/10 ,  G03H2250/12 ,  G03H2250/32 ,  G03H2250/35 ,  G03H2250/40 ,  G03H2270/54 ,  Y10T156/1051 ,  Y10T428/14 ,  Y10T428/1405 ,  Y10T428/1476 ,  Y10T428/1481 ,  Y10T428/1486 ,  Y10T428/149 ,  Y10T428/1495 ,  Y10T428/15 ,  Y10T428/24802 ,  Y10T428/24851 ,  Y10T428/2486 ,  Y10T428/24868 ,  Y10T428/24942

摘要： There are provided a hologram laminate and a hologram label which do not involve any problem in the production process per se of forging preventive labels using a volume hologram, can provide a reliable process of the attainment of forgery preventive effect, and can make difficult to notice the signs of the forgery preventive processing. In applying a protective film 108 onto a hologram 107 through a second pressure-sensitive adhesive 109, the adhesive strength is partially varied. By virtue of this construction, upon separation of the protective film 108, the second pressure-sensitive adhesive 109 is partially left on the hologram 107, so that the fact of the separation can be found out.

摘要翻译： 提供了全息图层压板和全息图标签，其在生产过程中本身使用体积全息图的锻造预防标签不会产生任何问题，可提供达到防伪效果的可靠过程，并且可能难以注意 防伪加工的迹象。 在通过第二压敏粘合剂109将保护膜108施加到全息图107上时，粘合强度部分变化。 由于这种结构，在隔离保护膜108时，第二压敏粘合剂109部分地残留在全息图107上，从而可以发现分离的事实。