摘要:
This invention provides a method for synthesizing semi-crystalline polylactides (PLA) even from a lactide mixture including meso-LA and rac-LA. According to the invention, when a mixture of racemic lactide and meso-lactide ispolymerized using a catalyst capable of iso-selectively polymerizing L-lactide and D-lactide, an amorphous poly (meso-lactide) block is formed from meso-lactide and a semi-crystalline poly (racemic lactide) block is formed from racemic lactide by separately polymerizing racemic lactide and meso-lactide by taking advantage of a difference in physicochemical properties between racemic lactide and meso-lactide, whereby polylactide which is semi-crystalline as a whole is produced.
摘要:
This invention provides a method for synthesizing semi-crystalline polylactides (PLA) even from a lactide mixture including meso-LA and rac-LA. According to the invention, when a mixture of racemic lactide and meso-lactide ispolymerized using a catalyst capable of iso-selectively polymerizing L-lactide and D-lactide, an amorphous poly (meso-lactide) block is formed from meso-lactide and a semi-crystalline poly (racemic lactide) block is formed from racemic lactide by separately polymerizing racemic lactide and meso-lactide by taking advantage of a difference in physicochemical properties between racemic lactide and meso-lactide, whereby polylactide which is semi-crystalline as a whole is produced.
摘要:
To provide a method capable of producing stereocomplex polylactic acid, the method being capable of using carbon neutral materials that are not competitive from foods, such as saccharides, without the use of a method for designing optical resolution, which requires complicated operations and high cost and is difficult to perform mass production. The production method of the present invention comprises: a step of reacting glycerin with sodium hydroxide in high-temperature and high-pressure water to produce a racemic sodium lactate aqueous solution; a step of separating sodium from the racemic sodium lactate aqueous solution to recover racemic lactic acid; a step of dimerizing the racemic lactic acid to produce a lactide mixture containing meso lactide and racemic lactide; a step of separating meso lactide from the mixture to recover racemic lactide; and a step of polymerizing the racemic lactide with a salen-metal complex as a catalyst to produce stereocomplex polylactic acid.
摘要:
To provide a method capable of producing stereocomplex polylactic acid, the method being capable of using carbon neutral materials that are not competitive from foods, such as saccharides, without the use of a method for designing optical resolution, which requires complicated operations and high cost and is difficult to perform mass production. The production method of the present invention comprises: a step of reacting glycerin with sodium hydroxide in high-temperature and high-pressure water to produce a racemic sodium lactate aqueous solution; a step of separating sodium from the racemic sodium lactate aqueous solution to recover racemic lactic acid; a step of dimerizing the racemic lactic acid to produce a lactide mixture containing meso lactide and racemic lactide; a step of separating meso lactide from the mixture to recover racemic lactide; and a step of polymerizing the racemic lactide with a salen-metal complex as a catalyst to produce stereocomplex polylactic acid.
摘要:
A transmission system having a first transmission terminal and a second transmission terminal includes a first communications connector to connect first data communications between the first transmission terminal specified by first identification information and the second transmission terminal specified by second identification information, an identification information creating part to create fourth identification information of the second transmission terminal when receiving a request for connecting second data communications between the first transmission terminal and the second transmission terminal, and a second communications connector to acquire third identification information in association with the first identification information by referring to registration information registering the third identification information in association with the first identification information of the first transmission terminal, and connect the second data communications between the first transmission terminal specified by the third identification information and the second transmission terminal specified by the fourth identification information.
摘要:
A management apparatus is configured to, when a connection request specifying, as a communication partner, a communication apparatus or an information processing apparatus has been received from a partner apparatus, transmit a connection request to a communication apparatus. The communication apparatus is configured to transmit a reception notification message to the management apparatus, when the connection request has been received. The management apparatus is configured to, when the reception notification message has been received from the communication apparatus, identify the information processing apparatus that is in cooperation with the communication apparatus that is a transmission source of the received reception notification message, and transmit the reception notification message to the identified information processing apparatus. The information processing apparatus is configured to receive an approval operation for approval of reception or a denial operation for denial of reception, when the reception notification message has been received.
摘要:
A device for taking up a fire-fighting hose, allowing the user to quickly and reliably take up the hose with a small force in an upright posture and capable of accurately taking up the hose both in a single layer and in double layers. Wheels (2) are rotatably supported at the lower part of a frame body (1), and a handle (5) is provided to the upper part of the frame body (1). The frame body (1) can be moved by rotating the wheels (2) by pushing or pulling the handle (5). A rotatable reel (3) on which hose (H) is wound is provided to the frame body (1), a power transmitting circulation member (4) is passed over the rotating shaft (33) of the reel (3) and the rotation support shaft (21) of the wheels (2) to enable the reel (3) to rotate in association with the rotation of the wheels (2). A core member (3A) for a single-layer winding and a core member (3B) for double-layer winding, which are interchangeable, are provided to the reel (3), and either the core member (3A) for a single-layer winding or the core member (3B) for double-layer winding can be removably affixed to a rotating shaft section (30a) of a base plate (30) of the reel (3).
摘要:
A portable electronic apparatus provided with a biaxial hinge mechanism that connects a first body and a second body to be openable and closable and rotatable via a hinge portion that allows for a reduction in thickness in a thickness direction and a size of a set of the bodies in a closed state, while securing sufficient strength in the biaxial hinge mechanism.
摘要:
A maintenance management system creating inspection plans for an inspection region wherein, a required cost for an inspection of an inspection object included within each management region from among the combinations of deadlines for the inspection of the inspection object included within each management region, and a required cost for inspection of an inspection object including an inspection object which exceeds the deadline for inspection in combinations of the deadlines of each inspection from among the objects for inspection that are included in an inspection cost for the inspection region is compared and one combination from the combinations of deadlines for inspection is output on the basis of the comparison result.
摘要:
Disclosed herein is a character input apparatus including: a display section having a screen capable of displaying at least characters; an operation section configured to allow a user to input at least the characters; a first character input processing section configured to perform a first character input process of causing a character string to be displayed on the screen in accordance with a predetermined notation rule; a second character input processing section configured to perform a second character input process of causing a character string to be displayed on the screen not in accordance with the predetermined notation rule; a scene determination section configured to determine a character input scene; and an input process switch control section configured to switch between the first character input process and the second character input process in accordance with the character input scene.