摘要:
Disclosed is a non-aqueous electrolyte secondary battery having an excellent preservation characteristic at a high temperature and charging/discharging cycle characteristic.A rolled body in which a strip-shape positive electrode and negative electrode are rolled with a separator in-between is provided inside a battery can. The positive electrode contains LixMn2−yMayO4 (where, Ma is at least one element selected from the group consisting of metal elements other than Mn, and B) and LiNi1−zMbzO2 (where, Mb is at least one element selected from the group consisting of metal elements other than Ni, and B). By replacing part of Mn and Ni with other elements, the crystal structure can be stabilized. Thereby, the capacity retention ratio after preservation at a high temperature, and a heavy load discharging power under a high electric potential cutoff can be improved. The mean particle size of particles of the above-mentioned oxides are preferable to be 30 μm and below so that an excellent charging/discharging cycle characteristic can be obtained.
摘要翻译:公开了一种在高温和充放电循环特性方面具有优异的保存特性的非水电解质二次电池。 在电池壳内部设置有带状正极和负极在其间分离的卷状卷绕体。 正极含有Li x Mn 2 O y O y O 4(其中,Ma是至少一个 选自除Mn以外的金属元素的元素,以及B)和LiNi 1-z Mb z O 2 N(其中,Mb 是选自Ni之外的金属元素和B)中的至少一种元素。 通过用其他元素代替Mn和Ni的一部分,可以稳定晶体结构。 由此,能够提高高电位保存后的容量保持率和高电位切断下的重负荷放电功率。 上述氧化物的粒子的平均粒径优选为30μm以下,因此可以得到良好的充放电循环特性。
摘要:
Disclosed is a non-aqueous electrolyte secondary battery having an excellent preservation characteristic at a high temperature and charging/discharging cycle characteristic. A rolled body in which a strip-shape positive electrode and negative electrode are rolled with a separator in-between is provided inside a battery can. The positive electrode contains LixMn2-yMayO4 (where, Ma is at least one element selected from the group consisting of metal elements other than Mn, and B) and LiNi1-zMbzO2 (where, Mb is at least one element selected from the group consisting of metal elements other than Ni, and B). By replacing part of Mn and Ni with other elements, the crystal structure can be stabilized. Thereby, the capacity retention ratio after preservation at a high temperature, and a heavy load discharging power under a high electric potential cutoff can be improved. The mean particle size of particles of the above-mentioned oxides are preferable to be 30 μm and below so that an excellent charging/discharging cycle characteristic can be obtained.
摘要翻译:公开了一种在高温和充放电循环特性方面具有优异的保存特性的非水电解质二次电池。 在电池壳内部设置有带状正极和负极在其间分离的卷状卷绕体。 正极含有Li x Mn 2 O y O y O 4(其中,Ma是至少一个 选自除Mn以外的金属元素的元素,以及B)和LiNi 1-z Mb z O 2 N(其中,Mb 是选自Ni之外的金属元素和B)中的至少一种元素。 通过用其他元素代替Mn和Ni的一部分,可以稳定晶体结构。 由此,能够提高高电位保存后的容量保持率和高电位切断下的重负荷放电功率。 上述氧化物的粒子的平均粒径优选为30μm以下,因此可以得到良好的充放电循环特性。
摘要:
Disclosed is a non-aqueous electrolyte secondary battery having an excellent preservation characteristic at a high temperature and charging/discharging cycle characteristic. A rolled body in which a strip-shape positive electrode and negative electrode are rolled with a separator in-between is provided inside a battery can. The positive electrode contains LixMn2-yMayO4 (where, Ma is at least one element selected from the group consisting of metal elements other than Mn, and B) and LiNi1-zMbzO2 (where, Mb is at least one element selected from the group consisting of metal elements other than Ni, and B). By replacing part of Mn and Ni with other elements, the crystal structure can be stabilized. Thereby, the capacity retention ratio after preservation at a high temperature, and a heavy load discharging power under a high electric potential cutoff can be improved. The mean particle size of particles of the above-mentioned oxides are preferable to be 30 μm and below so that an excellent charging/discharging cycle characteristic can be obtained.
摘要:
A method of manufacturing a negative material and a secondary battery in which a belt-shaped positive electrode and a belt-shaped negative electrode are wound together with a separator in between them to form a wound electrode body. The wound electrode battery is then inserted inside a battery can. Preferably, the negative electrode is produced with crushed silicon or a silicon compound in an oxygen partial pressure atmosphere within a value from higher than 10 Pa to lower than an oxygen partial pressure of air.
摘要:
The present invention provides a non-aqueous electrolyte secondary cell including: a lithium-nickel composite oxide as a cathode active material and a material having a specific surface in the range from 0.05 m2/g to 2 m2/g as an anode active material. When A is assumed to be the weight of the lithium-nickel composite oxide and B is assumed to be the weight of the cathode active material other than the lithium-nickel composite oxide, the mixture ratio R expressed A/(A+B) is in the range from 0.2 to 1. This combination of the cathode active material and the anode active material enables to obtain an improved anti-over discharge characteristic even when an anode current collector contains Cu.
摘要:
The present invention relates to a nonaqueous electrolyte secondary battery comprising an anode (3), a cathode (2) and a nonaqueous electrolyte. The anode forming this battery includes composite particles having a carbon material included in a metallic material. As the metallic material, metal capable of electrochemically reacting with lithium in a nonaqueous electrolyte is included.
摘要:
Provided is a battery with a higher capacity and superior charge-discharge cycle characteristics. A cathode contained in a package can and an anode contained in a package cup are laminated with a separator in between. The separator is impregnated with an electrolyte solution formed by dissolving lithium salt in a solvent. The anode comprises a tin-containing material including metallic tin and an intermetallic compound including tin in the same particle. A higher capacity and superior charge-discharge cycles can be obtained by the tin-containing material.
摘要:
A nonaqueous electrolyte secondary battery is provided with a positive electrode including a positive-electrode active material, a negative electrode including a negative-electrode active material, and a nonaqueous electrolyte solution. The negative electrode further includes carbon fibers and carbon flakes. The synergistic effects of the improved retention of the electrolyte solution by the carbon fibers and the improved conductivity between the active material particles by the carbon flakes facilitate doping/undoping of lithium in a high-load current mode and increase the capacity of the battery in the high-load current mode.
摘要:
A nonaqueous electrolyte secondary battery is provided with a positive electrode including a positive-electrode active material, a negative electrode including a negative-electrode active material, and a nonaqueous electrolyte solution. The negative electrode further includes carbon fibers and carbon flakes. The synergistic effects of the improved retention of the electrolyte solution by the carbon fibers and the improved conductivity between the active material particles by the carbon flakes facilitate doping/undoping of lithium in a high-load current mode and increase the capacity of the battery in the high-load current mode.
摘要:
In a non-aqueous electrolyte secondary battery including an anode and a cathode consisting of material capable of doping/undoping of lithium, and non-aqueous electrolytic solution in which electrolyte is dissolved in a non-aqueous solvent, flaky graphite having high crystallinity and high electron conductivity is added as conductive agent into the anode and the cathode. Further, granulated carbon and carbon black having specific material property is added as conductive agent in addition to the flaky graphite. Thus, non-aqueous electrolyte secondary battery having long cycle life time and high reliability can be obtained.