公开(公告)号：US20140030520A1

公开(公告)日：2014-01-30

申请号：US13949181

申请日：2013-07-23

申请人： Hitachi Metals, Ltd.

发明人： YOSHIAKI NAKAMURA ,  Motoharu Kajiyama ,  Kentaro Segawa ,  Kenichiro Fujimoto ,  Hitoshi Kimura

IPC分类号： H01B3/30

CPC分类号： H01B3/308 ,  C08K3/04 ,  C08K3/22 ,  C08K2003/2224 ,  C08L23/0815 ,  C08L23/0853 ,  C08L51/06 ,  C08L2201/02 ,  C08L2203/202 ,  H01B3/441 ,  H01B3/448 ,  H01B7/295 ,  Y10T428/292

摘要： A halogen free flame-retardant polymer composition includes flame retardancy and excellent oil resistance/fuel resistance, low-temperature characteristics, and injury resistance, and an insulated electric wire and a cable include the composition. The halogen-free flame-retardant polymer composition includes a base polymer including 60 to 70% by mass of LLDPE, 10% by mass or more of EVA having a melt flow rate (MFR) of 100 or more, and 10 to 20% by mass of maleic acid-modified polyolefin, a metal hydroxide added at a ratio of 150 to 220 parts by mass relative to 100 parts by mass of the base polymer, and carbon black. The addition ratio (metal hydroxide/carbon black) between the metal hydroxide and the carbon black is 15:1 to 100:1.

摘要翻译： 无卤阻燃聚合物组合物包括阻燃性和优异的耐油性/耐燃料性，低温特性和耐损伤性，绝缘电线和电缆包括组合物。 无卤阻燃聚合物组合物包括：包含60〜70质量％的LLDPE，10质量％以上的熔体流动速率（MFR）为100以上的EVA和10〜20质量％ 马来酸改性聚烯烃的质量，相对于100质量份的基础聚合物以150〜220质量份的比例添加的金属氢氧化物和炭黑。 金属氢氧化物与炭黑的添加比（金属氢氧化物/碳黑）为15:1〜100:1。

公开(公告)号：US09530536B2

公开(公告)日：2016-12-27

申请号：US14059142

申请日：2013-10-21

申请人： Hitachi Metals, Ltd.

发明人： Kenichiro Fujimoto ,  Mitsuru Hashimoto ,  Hiroshi Nakashima

IPC分类号： H01B7/00 ,  H01B3/30 ,  H01B3/44 ,  H01B7/295 ,  H01B3/42

CPC分类号： H01B3/421 ,  H01B3/441

摘要： A non-halogen multilayer insulated wire includes a conductor, an inner layer covering the conductor, and an outer layer formed on the external surface of the inner layer. The inner layer includes a polyolefin resin composition including 60 to 95 parts by mass of a high density polyethylene, 5 to 40 parts by mass of an ethylene copolymer, and 0.1 to 1 part by mass of a metal damage inhibitor. The outer layer includes a polyester resin composition that includes a base polymer mainly including a polyester resin, and further includes, relative to 100 parts by mass of the base polymer, 50 to 150 parts by mass of a polyester block copolymer, 0.5 to 5 parts by mass of a hydrolysis inhibitor, 0.5 to 5 parts by mass of an inorganic porous filler, and 10 to 30 parts by mass of magnesium hydroxide.

摘要翻译： 非卤素多层绝缘线包括导体，覆盖导体的内层和形成在内层的外表面上的外层。 内层包括聚烯烃树脂组合物，其包含60至95质量份的高密度聚乙烯，5至40质量份的乙烯共聚物和0.1至1质量份的金属损伤抑制剂。 外层包括聚酯树脂组合物，其包含主要包含聚酯树脂的基础聚合物，并且相对于100质量份的基础聚合物，还包含50〜150质量份的聚酯嵌段共聚物，0.5〜5份 的水解抑制剂，0.5〜5质量份的无机多孔质填料和10〜30质量份的氢氧化镁。

公开(公告)号：US20160125973A1

公开(公告)日：2016-05-05

申请号：US14871773

申请日：2015-09-30

申请人： Hitachi Metals, Ltd.

发明人： Makoto Iwasaki ,  Motoharu Kajiyama ,  Yoshiaki Nakamura ,  Hiroshi Okikawa ,  Mitsuru Hashimoto ,  Kenichiro Fujimoto ,  Akinari Nakayama

IPC分类号： H01B3/44

摘要： A cable includes a conductor, an insulation coating layer on the conductor, and an outer coating layer on the insulation coating layer. The insulation coating layer is made of a composition containing 100 parts by mass of a base polymer (A) and 100 to 250 parts by mass of a non-halogen flame retardant. The polymer (A) contains 70% to 99% by mass of an ethylene-vinyl acetate copolymer (a1) containing an ethylene-vinyl acetate copolymer having a melting point of 70° C. or higher, and 1% to 30% by mass of an acid-modified polyolefin resin (a2) having a glass transition point of −55° C. or lower. The polymer (A) contains 25% to 50% by mass of a vinyl acetate component derived from the copolymer (a1). The outer coating layer is made of a composition containing 100 parts by mass of a base polymer (B) and 150 to 220 parts by mass of a non-halogen flame retardant. The polymer (B) contains 60% to 70% by mass of a linear low-density polyethylene (b1), 10% by mass or more of an ethylene-vinyl acetate copolymer (b2) having a melt flow rate of 100 g/10 min or more, and 10% to 20% by mass of a maleic acid-modified polyolefin (b3).

摘要翻译： 电缆包括导体，导体上的绝缘涂层和绝缘涂层上的外涂层。 绝缘被覆层由含有100质量份基础聚合物（A）和100〜250质量份无卤阻燃剂的组合物构成。 聚合物（A）含有70质量％〜99质量％的含有熔点为70℃以上的乙烯 - 乙酸乙烯酯共聚物和1质量％〜30质量％的乙烯 - 乙酸乙烯酯共聚物（a1） 的具有-55℃以下的玻璃化转变温度的酸改性聚烯烃树脂（a2）。 聚合物（A）含有25质量％至50质量％的由共聚物（a1）衍生的乙酸乙烯酯组分。 外涂层由含有100质量份基础聚合物（B）和150〜220质量份非卤素阻燃剂的组合物构成。 聚合物（B）含有60质量％〜70质量％的线性低密度聚乙烯（b1），10质量％以上的熔体流动速率为100g / 10的乙烯 - 乙酸乙烯酯共聚物（b2） min以上，10质量％〜20质量％的马来酸改性聚烯烃（b3）。

公开(公告)号：US20150060107A1

公开(公告)日：2015-03-05

申请号：US14472082

申请日：2014-08-28

申请人： Hitachi Metals, Ltd.

发明人： Makoto Iwasaki ,  Kenichiro Fujimoto

IPC分类号： H01B3/42 ,  C08K5/5419 ,  H01B7/295 ,  C08K3/22

CPC分类号： H01B3/427 ,  C08K3/22 ,  C08K2003/2224 ,  C08K2003/2241 ,  C08L67/02 ,  C08L83/04 ,  C09D171/12 ,  H01B3/423 ,  H01B7/295 ,  C08L71/12

摘要： A halogen-free resin composition includes an engineering plastic as a main component including an aromatic ring. A thermal weight-change rate measured by a thermogravimetry (under conditions that a dry air as a purge gas is introduced and that heating is conducted from 40° C. at a temperature rise rate of 10° C./min) is not less than −60% when it is 430° C.

摘要翻译： 无卤素树脂组合物包括工程塑料作为主要成分的芳环。 通过热重分析测定的热重量变化率（在引入干燥空气作为吹扫气体的条件下，以40℃，10℃/分钟的升温速度进行加热）不小于 -60％，当它是430°C

公开(公告)号：US20170062092A1

公开(公告)日：2017-03-02

申请号：US15254810

申请日：2016-09-01

申请人： Hitachi Metals, Ltd.

发明人： Makoto Iwasaki ,  Mitsuru Hashimoto ,  Kenichiro Fujimoto

IPC分类号： H01B3/44 ,  H01B7/295 ,  H01B7/29

CPC分类号： H01B3/441 ,  C08K3/22 ,  C08K2003/2224 ,  C08L23/0853 ,  C08L2203/202 ,  C08L2312/06 ,  H01B3/448 ,  H01B7/292 ,  H01B7/295 ,  Y02A30/14 ,  C08L51/06 ,  C08K9/06 ,  C08K9/04

摘要： An insulated electric wire of the present disclosure includes a conductor and an insulation layer provided on an outer circumference of the conductor. The insulation layer includes a base polymer comprising ethylene-vinyl acetate copolymer and a metal hydroxide. The base polymer has a vinyl acetate content of 25% by mass or more and less than 50% by mass, and the metal hydroxide includes magnesium hydroxide.

摘要翻译： 本公开的绝缘电线包括导体和设置在导体的外周上的绝缘层。 绝缘层包括含有乙烯 - 乙酸乙烯酯共聚物和金属氢氧化物的基础聚合物。 基础聚合物的乙酸乙烯酯含量为25质量％以上且小于50质量％，金属氢氧化物包括氢氧化镁。

公开(公告)号：US20140138119A1

公开(公告)日：2014-05-22

申请号：US14059142

申请日：2013-10-21

申请人： Hitachi Metals, Ltd.

发明人： Kenichiro Fujimoto ,  Mitsuru Hashimoto ,  Hiroshi Nakashima

IPC分类号： H01B3/42 ,  H01B13/06

CPC分类号： H01B3/421 ,  H01B3/441

摘要： A non-halogen multilayer insulated wire includes a conductor, an inner layer covering the conductor, and an outer layer formed on the external surface of the inner layer. The inner layer includes a polyolefin resin composition including 60 to 95 parts by mass of a high density polyethylene, 5 to 40 parts by mass of an ethylene copolymer, and 0.1 to 1 part by mass of a metal damage inhibitor. The outer layer includes a polyester resin composition that includes a base polymer mainly including a polyester resin, and further includes, relative to 100 parts by mass of the base polymer, 50 to 150 parts by mass of a polyester block copolymer, 0.5 to 5 parts by mass of a hydrolysis inhibitor, 0.5 to 5 parts by mass of an inorganic porous filler, and 10 to 30 parts by mass of magnesium hydroxide.

摘要翻译： 非卤素多层绝缘线包括导体，覆盖导体的内层和形成在内层的外表面上的外层。 内层包括聚烯烃树脂组合物，其包含60至95质量份的高密度聚乙烯，5至40质量份的乙烯共聚物和0.1至1质量份的金属损伤抑制剂。 外层包括聚酯树脂组合物，其包含主要包含聚酯树脂的基础聚合物，并且相对于100质量份的基础聚合物，还包含50〜150质量份的聚酯嵌段共聚物，0.5〜5份 的水解抑制剂，0.5〜5质量份的无机多孔质填料和10〜30质量份的氢氧化镁。

公开(公告)号：US20140138118A1

公开(公告)日：2014-05-22

申请号：US14038487

申请日：2013-09-26

申请人： Hitachi Metals, Ltd.

发明人： Kenichiro Fujimoto ,  Hitoshi Kimura ,  Kentaro Segawa

IPC分类号： H01B3/42 ,  H01B13/06

CPC分类号： H01B3/421 ,  H01B3/441 ,  H01B3/447 ,  H01B3/448

摘要： A non-halogen multilayer insulated wire includes a conductor, an inner layer covering the conductor, and an outer layer on the inner layer. The inner layer includes a polyolefin resin composition including a high density polyethylene and a copolymer in a mass ratio on the range of 50:50 to 90:10, and the copolymer includes one of an ethylene-ethyl acrylate copolymer including 9% to 35% by mass of ethyl acrylate and an ethylene-vinyl acetate copolymer including 15% to 45% by mass of vinyl acetate. The outer layer is made of a polyester resin composition that includes a base polymer mainly including a polyester resin and further includes, relative to 100 parts by mass of the base polymer, 50 to 150 parts by mass of a polyester block copolymer, 0.5 to 5 parts by mass of a hydrolysis inhibitor, and 0.5 to 5 parts by mass of an inorganic porous filler.

摘要翻译： 非卤素多层绝缘线包括导体，覆盖导体的内层和内层上的外层。 内层包括质量比在50:50至90:10范围内的高密度聚乙烯和共聚物的聚烯烃树脂组合物，共聚物包括乙烯 - 丙烯酸乙酯共聚物之一，其包含9％至35％ 的丙烯酸乙酯和含有15〜45质量％乙酸乙烯酯的乙烯 - 乙酸乙烯酯共聚物。 外层由聚酯树脂组合物制成，该聚酯树脂组合物包含主要包含聚酯树脂的基础聚合物，相对于100质量份的基础聚合物，还包括50〜150质量份的聚酯嵌段共聚物，0.5〜5 质量份的水解抑制剂和0.5〜5质量份的无机多孔质填料。