摘要:
Disclosed is an electrolyte for a battery, which comprises: (a) an electrolyte salt; (b) a solvent for electrolyte; and (c) a compound represented by the following formula 1: wherein R is a halogen atom, or a halogen-substituted or non-substituted C1˜C10 alkyl group or alkenyl group. An electrode comprising a passivation layer partially or totally formed on a surface thereof, wherein the passivation layer comprises a compound represented by the following Formula 1 or a chemical reaction product thereof, and a secondary battery using the electrolyte and/or the electrode are also disclosed. The compound can improve the initial charge/discharge efficiency and cycle life characteristics of a secondary battery, and can inhibit a battery from swelling under high-temperature storage conditions.
摘要:
Disclosed is an electrolyte for batteries, which comprises: (a) an electrolyte salt; (b) an electrolyte solvent; and (c) a sulfonate-based compound containing at least one electron withdrawing group (EWG) selected from the group consisting of a cyano group (—CN), an isocyanate group (—NCO), a thiocyanate group (—SCN) and an isothiocyanate group (—NCS). An electrode comprising the sulfonate-based compound or a chemical reaction product thereof, partially or totally formed on the surface thereof, and an electrochemical device comprising the electrolyte and/or the electrode are also disclosed. The electrochemical device using the sulfonate-based compound containing a cyano group, an isocyanate group, a thiocyanate group and/or an isothiocyanate group as an additive for electrolytes can provide significantly improved high-temperature lifespan characteristics.
摘要:
Disclosed is a lithium secondary battery comprising a cathode, an anode, an electrolyte and a separator, wherein the anode comprises an anode active material having a specific surface area of 3 m2/g or less, and the electrolyte comprises 0.1˜6 parts by weight of a propane sultone-based compound based on 100 parts by weight of the electrolyte. The lithium secondary battery solves the problem of performance degradation caused by the use of an increased amount of a propane sultone-based compound required to form a SEI film on the surface of an anode upon the first charge cycle. Also, the lithium secondary battery can provide improved cycle characteristics and high-temperature storage characteristics.
摘要:
Disclosed is an electrolyte for batteries, comprising: (a) an electrolyte salt; (b) an organic solvent; (c) a first compound having an oxidation initiation voltage (vs. Li/Li+) higher than the operating voltage of a cathode; and (d) a second reversible compound having an oxidation initiation voltage higher than the operating voltage of the cathode, but lower than the oxidation initiation voltage of the first compound. Also disclosed is a lithium secondary battery comprising said electrolyte. In the lithium secondary battery, two compounds having different safety improvement actions at a voltage higher than the operating voltage of the cathode are used in combination as electrolyte components. Thus, the safety of the secondary battery in an overcharged state can be ensured, and at the same time, the deterioration of the battery can be prevented from occurring when it is repeatedly cycled, continuously charged and stored at high temperature for a long time.
摘要翻译:公开了一种用于电池的电解质,其包括:(a)电解质盐; (b)有机溶剂; (c)具有高于阴极的工作电压的氧化起始电压(相对于Li / Li +)的第一化合物; 和(d)具有高于阴极的工作电压但低于第一化合物的氧化起始电压的氧化起始电压的第二可逆化合物。 还公开了包含所述电解质的锂二次电池。 在锂二次电池中,作为电解质成分组合使用具有比阴极的工作电压高的电压具有不同安全性改善作用的两种化合物。 因此,可以确保二次电池处于过充电状态的安全性,并且同时可以防止在重复循环,连续充电并长时间在高温下储存时发生电池的劣化。
摘要:
Provided is a lithium secondary battery with enhanced energy density including a cathode using a cathode active material containing lithium mixed transition metal oxide absorbing and discharging lithium ions, wherein a final discharge voltage is in the range of about 1.5 V to about 2.75 V. A final discharge voltage can be reduced to 1.5 V to 2.75 V from 3.0 V by using various lithium mixed transition metal oxides as a cathode active material, or by using the various lithium mixed transition metal oxides with the LCO-based cathode material mixed. Compared to typical LCO-based cathode materials of which capacity and energy density do not change even if a final discharge voltage is decreased, a cathode material of the present invention results in further improving capacity by 10-20% as the final discharge voltage is decreased.
摘要:
Disclosed is lithium iron phosphate having an olivine crystal structure, wherein the length in the direction [001] is greater than the length in the direction [010] when the Li+ diffusion direction is the direction [010] in the lattice structure of the crystal.
摘要:
Disclosed is a cathode for secondary batteries comprising a compound having a transition metal layer containing lithium as at least one compound selected from the following formula 1: (1−x)Li(LiyM1-y-zMaz)O2-bAb*xLi3PO4 (1) wherein M is an element stable for a six-coordination structure, which is at least one selected from transition metals that belong to first and second period elements; Ma is a metal or non-metal element stable for a six-coordination structure; A is at least one selected from the group consisting of halogen, sulfur, chalcogenide compounds and nitrogen; 0
摘要:
Provided is a lithium secondary battery with enhanced energy density including a cathode using a cathode active material containing lithium mixed transition metal oxide absorbing and discharging lithium ions, wherein a final discharge voltage is in the range of about 1.5 V to about 2.75 V. A final discharge voltage can be reduced to 1.5 V to 2.75 V from 3.0 V by using various lithium mixed transition metal oxides as a cathode active material, or by using the various lithium mixed transition metal oxides with the LCO-based cathode material mixed. Compared to typical LCO-based cathode materials of which capacity and energy density do not change even if a final discharge voltage is decreased, a cathode material of the present invention results in further improving capacity by 10-20% as the final discharge voltage is decreased.