Additive for nonaqueous electrolyte and secondary battery using the same
    1.
    发明授权
    Additive for nonaqueous electrolyte and secondary battery using the same 有权
    用于非水电解质和使用其的二次电池的添加剂

    公开(公告)号:US07910249B2

    公开(公告)日:2011-03-22

    申请号:US11479305

    申请日:2006-06-30

    IPC分类号: H01M10/056

    摘要: Disclosed is an electrolyte for a battery, which comprises: (a) an electrolyte salt; (b) a solvent for electrolyte; and (c) a compound represented by the following formula 1: wherein R is a halogen atom, or a halogen-substituted or non-substituted C1˜C10 alkyl group or alkenyl group. An electrode comprising a passivation layer partially or totally formed on a surface thereof, wherein the passivation layer comprises a compound represented by the following Formula 1 or a chemical reaction product thereof, and a secondary battery using the electrolyte and/or the electrode are also disclosed. The compound can improve the initial charge/discharge efficiency and cycle life characteristics of a secondary battery, and can inhibit a battery from swelling under high-temperature storage conditions.

    摘要翻译: 公开了一种电池用电解质,其包括:(a)电解质盐; (b)电解质溶剂; 和(c)由下式1表示的化合物:其中R是卤素原子,或卤素取代或未取代的C1〜C10烷基或烯基。 一种电极,包括部分或全部形成在其表面上的钝化层,其中钝化层包括由下式1表示的化合物或其化学反应产物,并且还公开了使用电解质和/或电极的二次电池 。 该化合物可以提高二次电池的初始充电/放电效率和循环寿命特性,并且可以抑制电池在高温储存条件下膨胀。

    Additives for non-aqueous electrolytes and electrochemical device using the same
    2.
    发明授权
    Additives for non-aqueous electrolytes and electrochemical device using the same 有权
    非水电解质添加剂和使用其的电化学装置

    公开(公告)号:US07824578B2

    公开(公告)日:2010-11-02

    申请号:US11521780

    申请日:2006-09-15

    摘要: Disclosed is an electrolyte for batteries, which comprises: (a) an electrolyte salt; (b) an electrolyte solvent; and (c) a sulfonate-based compound containing at least one electron withdrawing group (EWG) selected from the group consisting of a cyano group (—CN), an isocyanate group (—NCO), a thiocyanate group (—SCN) and an isothiocyanate group (—NCS). An electrode comprising the sulfonate-based compound or a chemical reaction product thereof, partially or totally formed on the surface thereof, and an electrochemical device comprising the electrolyte and/or the electrode are also disclosed. The electrochemical device using the sulfonate-based compound containing a cyano group, an isocyanate group, a thiocyanate group and/or an isothiocyanate group as an additive for electrolytes can provide significantly improved high-temperature lifespan characteristics.

    摘要翻译: 公开了一种电池用电解质,其包括:(a)电解质盐; (b)电解质溶剂; 和(c)含有至少一个选自氰基(-CN),异氰酸酯基(-NCO),硫氰酸酯基(-SCN)和 - 氰基)的吸电子基团(EWG)的磺酸酯基化合物和 异硫氰酸酯基团(-NCS)。 还公开了包含部分或全部形成在其表面上的磺酸盐基化合物或其化学反应产物的电极和包含电解质和/或电极的电化学装置。 使用含有氰基,异氰酸酯基,硫氰酸酯基和/或异硫氰酸酯基作为电解质添加剂的磺酸基类化合物的电化学装置可以显着提高高温寿命特性。

    Nonaqueous electrolyte for improving performance and lithium secondary battery comprising the same
    3.
    发明授权
    Nonaqueous electrolyte for improving performance and lithium secondary battery comprising the same 有权
    用于改善性能的非水电解质和包含其的锂二次电池

    公开(公告)号:US08119292B2

    公开(公告)日:2012-02-21

    申请号:US11521892

    申请日:2006-09-15

    IPC分类号: H01M10/40

    摘要: Disclosed is a lithium secondary battery comprising a cathode, an anode, an electrolyte and a separator, wherein the anode comprises an anode active material having a specific surface area of 3 m2/g or less, and the electrolyte comprises 0.1˜6 parts by weight of a propane sultone-based compound based on 100 parts by weight of the electrolyte. The lithium secondary battery solves the problem of performance degradation caused by the use of an increased amount of a propane sultone-based compound required to form a SEI film on the surface of an anode upon the first charge cycle. Also, the lithium secondary battery can provide improved cycle characteristics and high-temperature storage characteristics.

    摘要翻译: 公开了包含阴极,阳极,电解质和隔膜的锂二次电池,其中所述阳极包括比表面积为3m 2 / g以下的负极活性物质,所述电解质包含0.1〜6重量份 的基于100重量份电解质的丙烷磺内酯基化合物。 锂二次电池解决了在第一次充电循环时在阳极表面上使用增加量的形成SEI膜所需的丙烷磺内酯类化合物引起的性能下降的问题。 此外,锂二次电池可以提供改进的循环特性和高温存储特性。

    Additives for non-aqueous electrolyte and lithium secondary battery using the same
    4.
    发明授权
    Additives for non-aqueous electrolyte and lithium secondary battery using the same 有权
    非水电解质和锂二次电池用添加剂

    公开(公告)号:US07927747B2

    公开(公告)日:2011-04-19

    申请号:US11623845

    申请日:2007-01-17

    IPC分类号: H01M6/16 H01M6/04

    摘要: Disclosed is an electrolyte for batteries, comprising: (a) an electrolyte salt; (b) an organic solvent; (c) a first compound having an oxidation initiation voltage (vs. Li/Li+) higher than the operating voltage of a cathode; and (d) a second reversible compound having an oxidation initiation voltage higher than the operating voltage of the cathode, but lower than the oxidation initiation voltage of the first compound. Also disclosed is a lithium secondary battery comprising said electrolyte. In the lithium secondary battery, two compounds having different safety improvement actions at a voltage higher than the operating voltage of the cathode are used in combination as electrolyte components. Thus, the safety of the secondary battery in an overcharged state can be ensured, and at the same time, the deterioration of the battery can be prevented from occurring when it is repeatedly cycled, continuously charged and stored at high temperature for a long time.

    摘要翻译: 公开了一种用于电池的电解质,其包括:(a)电解质盐; (b)有机溶剂; (c)具有高于阴极的工作电压的氧化起始电压(相对于Li / Li +)的第一化合物; 和(d)具有高于阴极的工作电压但低于第一化合物的氧化起始电压的氧化起始电压的第二可逆化合物。 还公开了包含所述电解质的锂二次电池。 在锂二次电池中,作为电解质成分组合使用具有比阴极的工作电压高的电压具有不同安全性改善作用的两种化合物。 因此,可以确保二次电池处于过充电状态的安全性,并且同时可以防止在重复循环,连续充电并长时间在高温下储存时发生电池的劣化。

    Lithium secondary battery with improved energy density
    5.
    发明授权
    Lithium secondary battery with improved energy density 有权
    具有提高能量密度的锂二次电池

    公开(公告)号:US08703340B2

    公开(公告)日:2014-04-22

    申请号:US13201385

    申请日:2010-02-16

    IPC分类号: H01M4/88 H01M4/13 H01M4/58

    摘要: Provided is a lithium secondary battery with enhanced energy density including a cathode using a cathode active material containing lithium mixed transition metal oxide absorbing and discharging lithium ions, wherein a final discharge voltage is in the range of about 1.5 V to about 2.75 V. A final discharge voltage can be reduced to 1.5 V to 2.75 V from 3.0 V by using various lithium mixed transition metal oxides as a cathode active material, or by using the various lithium mixed transition metal oxides with the LCO-based cathode material mixed. Compared to typical LCO-based cathode materials of which capacity and energy density do not change even if a final discharge voltage is decreased, a cathode material of the present invention results in further improving capacity by 10-20% as the final discharge voltage is decreased.

    摘要翻译: 提供了具有增强的能量密度的锂二次电池,包括使用吸收和放出​​锂离子的锂混合过渡金属氧化物的阴极活性材料的阴极,其中最终放电电压在约1.5V至约2.75V的范围内。最终 通过使用各种锂混合过渡金属氧化物作为正极活性物质,或通过混合各种锂混合过渡金属氧化物与LCO-阴极材料混合,放电电压可以从3.0V降低至1.5V至2.75V。 与其最终放电电压降低时容量和能量密度也不变化的典型的LCO阴极材料相比,本发明的阴极材料随着最终放电电压的降低而进一步提高10-20%的容量 。

    Cathode for secondary battery
    8.
    发明授权
    Cathode for secondary battery 有权
    二次电池阴极

    公开(公告)号:US08673171B2

    公开(公告)日:2014-03-18

    申请号:US13546023

    申请日:2012-07-11

    IPC分类号: H01M4/88

    摘要: Disclosed is a cathode for secondary batteries comprising a compound having a transition metal layer containing lithium as at least one compound selected from the following formula 1: (1−x)Li(LiyM1-y-zMaz)O2-bAb*xLi3PO4 (1) wherein M is an element stable for a six-coordination structure, which is at least one selected from transition metals that belong to first and second period elements; Ma is a metal or non-metal element stable for a six-coordination structure; A is at least one selected from the group consisting of halogen, sulfur, chalcogenide compounds and nitrogen; 0

    摘要翻译: 公开了一种二次电池用阴极,其包含具有过渡金属层的化合物,该过渡金属层含有作为选自下述式1中的至少一种化合物的锂:(1-x)Li(LiyM1-y-zMaz)O2-bAb * xLi3PO4(1) 其中M是对于六配位结构稳定的元素,其是选自属于第一和第二周期元素的过渡金属中的至少一种; Ma是六配位结构稳定的金属或非金属元素; A是选自卤素,硫,硫族化合物和氮的至少一种; 0

    LITHIUM SECONDARY BATTERY WITH IMPROVED ENERGY DENSITY
    10.
    发明申请
    LITHIUM SECONDARY BATTERY WITH IMPROVED ENERGY DENSITY 有权
    锂二次电池具有改善的能量密度

    公开(公告)号:US20120028134A1

    公开(公告)日:2012-02-02

    申请号:US13201385

    申请日:2010-02-16

    摘要: Provided is a lithium secondary battery with enhanced energy density including a cathode using a cathode active material containing lithium mixed transition metal oxide absorbing and discharging lithium ions, wherein a final discharge voltage is in the range of about 1.5 V to about 2.75 V. A final discharge voltage can be reduced to 1.5 V to 2.75 V from 3.0 V by using various lithium mixed transition metal oxides as a cathode active material, or by using the various lithium mixed transition metal oxides with the LCO-based cathode material mixed. Compared to typical LCO-based cathode materials of which capacity and energy density do not change even if a final discharge voltage is decreased, a cathode material of the present invention results in further improving capacity by 10-20% as the final discharge voltage is decreased.

    摘要翻译: 提供了具有增强的能量密度的锂二次电池,包括使用吸收和放出​​锂离子的锂混合过渡金属氧化物的阴极活性材料的阴极,其中最终放电电压在约1.5V至约2.75V的范围内。最终 通过使用各种锂混合过渡金属氧化物作为正极活性物质,或通过混合各种锂混合过渡金属氧化物与LCO-阴极材料混合,放电电压可以从3.0V降低至1.5V至2.75V。 与其最终放电电压降低时容量和能量密度也不变化的典型的LCO阴极材料相比,本发明的阴极材料随着最终放电电压的降低而进一步提高10-20%的容量 。