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公开(公告)号：US07208438B2
公开(公告)日：2007-04-24
申请号：US10909954
申请日：2004-07-30
申请人： Hugo Gerard Eduard Ingelbrecht , Sabyasachi Mandal , Ashok Menon , Pradeep Nadkarni , Rupesh Pawar , Kuppuswamy Raghunathan , Gert-Jan Schoenmakers , Sahida Sharma
发明人： Hugo Gerard Eduard Ingelbrecht , Sabyasachi Mandal , Ashok Menon , Pradeep Nadkarni , Rupesh Pawar , Kuppuswamy Raghunathan , Gert-Jan Schoenmakers , Sahida Sharma
CPC分类号： B01J21/10 , B01J23/78 , B01J23/862 , B01J35/1019 , B01J35/1061 , B01J35/109 , B01J37/0018 , C07C37/16 , C07C2521/10 , C07C2523/745 , C07C39/07
摘要： A method of making a catalyst comprising mixing a metal oxide precursor and a pore former to form a metal oxide precursor mixture and calcining the metal oxide precursor mixture in the presence of a flowing gas having a flow rate to form the catalyst comprising metal oxide. The catalyst comprises a first distribution of pores having a median pore diameter of 10 to 50 angstroms and a second distribution of pores having a median pore diameter of 1 to 500 angstroms. The median pore diameter of the second distribution of pores is inversely related to the flow rate of the gas.
摘要翻译： 一种制备催化剂的方法，包括将金属氧化物前体和成孔剂混合以形成金属氧化物前体混合物，并在流动的气体存在下煅烧金属氧化物前体混合物以形成包含金属氧化物的催化剂。 该催化剂包括中值孔径为10至50埃的孔的第一分布和中等孔径为1至500埃的孔的第二分布。 孔的第二分布的中值孔径与气体的流量成反比。
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2.发明授权公开(公告)号：US07205377B2
公开(公告)日：2007-04-17
申请号：US10953723
申请日：2004-09-29
摘要： A method for preparing a poly(arylene ether) with a reduced level of powder fines is described. In one embodiment, the method comprises oxidatively coupling a monohydric phenol in the presence of a solvent and a complex metal catalyst, to produce a poly(arylene ether) resin; and then removing a portion of the solvent to produce a concentrated solution having a cloud point Tcloud. The concentrated solution is then combined with an anti-solvent to precipitate the poly(arylene ether) in the form of a precipitation mixture. The concentrated solution usually has a temperature of at least about (Tcloud−10° C.) immediately before it is combined with the anti-solvent. The precipitation mixture has a temperature of at least about (Tcloud−40° C.) after its formation. Related poly(arylene ether) copolymers are also described.
摘要翻译： 描述了一种制备具有降低粉末粉粒度的聚（亚芳基醚）的方法。 在一个实施方案中，该方法包括在溶剂和复合金属催化剂的存在下将一元酚氧化偶联以产生聚（亚芳基醚）树脂; 然后除去溶剂的一部分以产生具有浊点T云的浓缩溶液。 然后将浓缩溶液与抗溶剂组合以沉淀出沉淀混合物形式的聚（亚芳基醚）。 在与抗溶剂组合之前，浓缩溶液通常具有至少约（T N 10 -2℃）的温度。 沉淀混合物在其形成之后的温度至少约为（T -40℃）。 还描述了相关的聚（亚芳基醚）共聚物。
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公开(公告)号：US06469128B1
公开(公告)日：2002-10-22
申请号：US09682210
申请日：2001-08-07
IPC分类号： C08G6538
摘要： A process for producing a poly(arylene ether) resins includes oxidatively coupling a monohydric phenol in the presence of a solvent and a catalyst to form a soluble poly(arylene ether) and an insoluble poly(arylene ether), separating the soluble poly(arylene ether) and the insoluble poly(arylene ether), and recycling the soluble poly(arylene ether). The process is particularly useful for synthesizing poly(arylene ether) copolymers in which the monomer compositions of soluble and insoluble copolymers may vary.
摘要翻译： 一种制备聚（亚芳基醚）树脂的方法包括在溶剂和催化剂存在下使一元酚氧化偶合形成可溶性聚（亚芳基醚）和不溶性聚（亚芳基醚），将可溶性聚（亚芳基） 醚）和不溶性聚（亚芳基醚），并再循环可溶性聚（亚芳基醚）。 该方法对于合成其中可溶性和不溶性共聚物的单体组成可能变化的聚（亚芳基醚）共聚物特别有用。
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4.发明授权Method of preparing a poly(arylene ether), apparatus therefor, and poly(arylene ether) prepared thereby 有权制备聚（亚芳基醚）的方法及其制备方法和由此制备的聚（亚芳基醚）公开(公告)号：US07151158B2
公开(公告)日：2006-12-19
申请号：US10769043
申请日：2004-01-30
CPC分类号： C08J3/07 , C08J2371/02 , C08L71/10 , Y10S526/92
摘要： A method of precipitating a poly(arylene ether) includes combining a poly(arylene ether) solution with an antisolvent at a shear rate of greater than 50,000 sec−1. The high shear mixing conditions produce a poly(arylene ether) dispersion in which the poly(arylene ether) solid contains reduced amounts of undesirably fine particles.
摘要翻译： 沉淀聚（亚芳基醚）的方法包括在大于50,000sec -1的剪切速率下将聚（亚芳基醚）溶液与抗溶剂混合。 高剪切混合条件产生聚（亚芳基醚）分散体，其中聚（亚芳基醚）固体含有减少量的不期望的细颗粒。
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5.发明授权Method of preparing a poly(arylene ether), and a poly(arylene ether) prepared thereby 有权制备聚（亚芳基醚）的方法和由其制备的聚（亚芳基醚）公开(公告)号：US06407200B1
公开(公告)日：2002-06-18
申请号：US09681895
申请日：2001-06-21
IPC分类号： C08G6538
摘要： A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether), wherein the concentrated solution has a temperature of at least about (Tcloud−10° C.) immediately before it is combined with the anti-solvent. The method reduces the formation of undesirably fine particles in the product poly(arylene ether).
摘要翻译： 制备聚（亚芳基醚）的方法包括使溶液中的一元酚氧化聚合，通过除去溶剂的一部分浓缩溶液以形成具有浊点Tcloud的浓缩溶液，并将浓缩溶液与抗 - 溶剂以沉淀聚（亚芳基醚），其中浓缩溶液在其与抗溶剂组合之前具有至少约（Tcloud-10℃）的温度。 该方法减少了产物聚（亚芳基醚）中不期望的细颗粒的形成。
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公开(公告)号：US07459520B2
公开(公告)日：2008-12-02
申请号：US11565396
申请日：2006-11-30
CPC分类号： C08J3/07 , C08J2371/02 , C08L71/10 , Y10S526/92
摘要： A poly(arylene ether) produced by combining a poly(arylene ether) solution with an antisolvent at a shear rate of greater than 50,000 sec−1. The high shear mixing conditions produce a poly(arylene ether) dispersion in which the poly(arylene ether) solid contains reduced amounts of undesirably fine particles.
摘要翻译： 通过在大于50,000sec -1的剪切速率下将聚（亚芳基醚）溶液与抗溶剂结合而制备的聚（亚芳基醚）。 高剪切混合条件产生聚（亚芳基醚）分散体，其中聚（亚芳基醚）固体含有减少量的不期望的细颗粒。
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公开(公告)号：US07329708B2
公开(公告)日：2008-02-12
申请号：US10920744
申请日：2004-08-18
申请人： Joop Birsak , Herbert Shin-I Chao , Bryan Duffey , Amy Rene Freshour , Hugo Gerard Eduard Ingelbrecht , Qiwei Lu , Michael Joseph O'Brien , Prameela Susarla , Michael Vallance , Kenneth Paul Zarnoch
发明人： Joop Birsak , Herbert Shin-I Chao , Bryan Duffey , Amy Rene Freshour , Hugo Gerard Eduard Ingelbrecht , Qiwei Lu , Michael Joseph O'Brien , Prameela Susarla , Michael Vallance , Kenneth Paul Zarnoch
IPC分类号： C08L71/12
CPC分类号： C08G65/485 , C08F220/06 , C08F222/1006 , C08F283/06 , C08F283/08 , C08F290/061 , C08F290/062
摘要： A curable composition includes an olefinically unsaturated monomer and a poly(arylene ether) having two polymerizable groups and an intrinsic viscosity of about 0.05 to about 0.30 deciliters per gram. The composition exhibits an improved combination of high flow during molding and high post-cure stiffness and impact strength. The composition is particularly useful for fabricating plastic-packaged electronic devices.
摘要翻译： 可固化组合物包括烯属不饱和单体和具有两个可聚合基团的聚（亚芳基醚），特性粘度为约0.05至约0.30分升/克。 该组合物在模塑期间显示出高流动性和高后固化刚度和冲击强度的改进的组合。 该组合物特别适用于制造塑料封装的电子器件。
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8.发明授权Method of preparing a poly(arylene ether), and a poly(arylene ether) prepared thereby 有权制备聚（亚芳基醚）的方法和由其制备的聚（亚芳基醚）公开(公告)号：US06444779B1
公开(公告)日：2002-09-03
申请号：US09683806
申请日：2002-02-19
IPC分类号： C08G6538
摘要： A method of preparing a poly(arylene ether) includes oxidatively polymerizing a monohydric phenol in solution, concentrating the solution by removing a portion of the solvent to form a concentrated solution having a cloud point, Tcloud, adjusting the temperature of the concentrated solution to at least about (Tcloud−10° C.), and combining the concentrated solution with an anti-solvent to precipitate the poly (arylene ether). The method reduces the formation of undesirably fine particles in the product poly(arylene ether).
摘要翻译： 制备聚（亚芳基醚）的方法包括使溶液中的一元酚氧化聚合，通过除去一部分溶剂浓缩溶液，形成具有浊点的浓缩溶液Tcloud，将浓缩溶液的温度调节至 至少约（Tcloud-10℃），并将浓缩溶液与抗溶剂组合以沉淀聚（亚芳基醚）。 该方法减少了产物聚（亚芳基醚）中不期望的细颗粒的形成。
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9.发明授权Method of preparing a poly (arylene ether) and a poly (arylene ether) prepared thereby 有权制备由其制备的聚（亚芳基醚）和聚（亚芳基醚）的方法公开(公告)号：US06437084B1
公开(公告)日：2002-08-20
申请号：US09683037
申请日：2001-11-12
申请人： Joop Birsak , Hugo Gerard Eduard Ingelbrecht , David Parrillo , Mukund Parthasarathy , Probjot Singh
发明人： Joop Birsak , Hugo Gerard Eduard Ingelbrecht , David Parrillo , Mukund Parthasarathy , Probjot Singh
IPC分类号： C08G6538
CPC分类号： C08G65/44
摘要： A method of preparing a poly(arylene ether) includes oxidatively coupling a monohydric phenol in a reaction solution at a reaction temperature that exceeds the cloud point temperature of the reaction solution. The oxidative coupling occurs in the presence of a metal complex catalyst, and when the catalyst includes an amine ligand, the method facilitates incorporation of the amine ligand into the poly(arylene ether) resin. The amine-incorporated poly(arylene ether) resins prepared by the method are useful in the preparation of higher molecular weight poly(arylene ether) resins and compatibilized blends of poly(arylene ether) resins with other thermoplastics.
摘要翻译： 制备聚（亚芳基醚）的方法包括在超过反应溶液的浊点温度的反应温度下将反应溶液中的一元酚氧化偶联。 氧化偶联发生在金属络合物催化剂的存在下，当催化剂包括胺配体时，该方法便于将胺配体引入聚（亚芳基醚）树脂中。 通过该方法制备的加入胺的聚（亚芳基醚）树脂可用于制备高分子量聚（亚芳基醚）树脂和聚（亚芳基醚）树脂与其它热塑性塑料的相容混合物。
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