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公开(公告)号：US06645705B2
公开(公告)日：2003-11-11
申请号：US10007359
申请日：2001-11-05
IPC分类号： G03C176
CPC分类号： G03C1/7614 , Y10S430/162
摘要： The present invention is a photographic element which includes a support, at least one silver-halide emulsion layer superposed on the support and a processing-solution-permeable overcoat overlying the silver-halide emulsion layer that becomes water-resistant in the final product, without requiring lamination or fusing. The presence, in the coating composition, of a compound comprising a blocked copolymer of ethylene oxide and propylene oxide has been found to improve wet durability, prevent the retention of iron, and improve the conversion of the overcoat to a water-resistant layer during processing. The present invention is also directed to a method of making a photographic print involving developing the photographic element.
摘要翻译： 本发明是一种照相元件，它包括一个载体，至少一个叠加在载体上的卤化银乳剂层和覆盖卤化银乳剂层的加工溶液渗透性外涂层，在最终产品中变得防水，不含 需要层压或熔合。 在涂料组合物中，已经发现包含环氧乙烷和环氧丙烷的封端共聚物的化合物的存在可以改善湿润耐久性，防止铁的保留，并且在加工过程中改善外涂层对耐水层的转化率 。 本发明还涉及一种制造涉及显影照相元件的照相印相的方法。
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公开(公告)号：US5952130A
公开(公告)日：1999-09-14
申请号：US136375
申请日：1998-08-19
摘要： The present invention is an imaged photographic element which includes a support, at least one light sensitive silver halide emulsion layer superposed on the support, and an overcoat layer overlying the light sensitive silver halide emulsion layer. The protective overcoat includes a first water insoluble polymer having a Tg less than 25.degree. C. and a second water insoluble polymer having a Tg greater than 25.degree. C. The first or second polymer is composed of a monomer at a weight percent of 20 to 100 having the following formula ##STR1## wherein: X is selected from the group consisting of --Cl, --F, and --CN, and Y is each independently selected from the group consisting of H, Cl, F, CN, CF.sub.3, CH.sub.3, C.sub.2 H.sub.5, n--C.sub.3 H.sub.7, iso--C.sub.3 H.sub.7, n--C.sub.4 H.sub.9, n--C.sub.5 H.sub.11, n--C.sub.6 H.sub.13, OCH.sub.3, OC.sub.2 H.sub.5, phenyl C.sub.6 F.sub.5, C.sub.6 Cl.sub.5, CH.sub.2 Cl, CH.sub.2 F, C.sub.2 F.sub.5, n--C.sub.3 F.sub.7, iso--C.sub.3 F.sub.7, OCF.sub.3, OC.sub.2 F.sub.5, OC.sub.3 F.sub.7, C(CF.sub.3).sub.3, CH.sub.2 (CF.sub.3), CH(CF.sub.3).sub.2, --COCF.sub.3, COC.sub.2 F.sub.5, COCH.sub.3, COC.sub.2 H.sub.5.
摘要翻译： 本发明是一种成像的照相元件，其包括载体，叠加在载体上的至少一种感光卤化银乳剂层和覆盖在感光卤化银乳剂层上的外涂层。 保护性外涂层包括Tg小于25℃的第一水不溶性聚合物和Tg大于25℃的第二水不溶性聚合物。第一或第二聚合物由重量百分比为20至 100，其中：X选自-Cl，-F和-CN，Y各自独立地选自H，Cl，F，CN，CF 3，CH 3，C 2 H 5， 正C 3 H 7，异-C 3 H 7，n-C 4 H 9，n -C 5 H 11，n-C 6 H 13，OCH 3，OC 2 H 5，苯基C 6 F 5，C 6 Cl 5，CH 2 Cl，CH 2 F，C 2 F 5，n -C 3 F 7，异-C 3 F 7，OCF 3，OC 2 F 5，OC 3 F 7，C （CF 3）3，CH 2（CF 3），CH（CF 3）2，-COCF 3，COC 2 F 5，COCH 3，COC 2 H 5。
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公开(公告)号：US6130014A
公开(公告)日：2000-10-10
申请号：US354055
申请日：1999-07-15
IPC分类号： B41M5/00 , B41M7/00 , C09D5/00 , C09D157/06 , G03C1/053 , G03C1/76 , G03C1/85 , G03C5/14 , G03C11/08
CPC分类号： G03C11/08 , B41M7/0036 , G03C1/76 , G03C1/053 , G03C1/85 , G03C5/14 , Y10S430/162
摘要： The present invention is a coating composition comprising at least one first water insoluble polymer having a Tg equal to or less than 30.degree. C. and at least one second water insoluble polymer having a Tg equal to or greater than 60.degree. C. wherein the first polymer comprises a monomer at a weight percent of 75 to 100 of the monomer represented by the following formula 1: ##STR1## wherein: X is selected from the group consisting of --Cl, --F, or --CN, and Y is each independently selected from the group consisting of H, Cl, F, CN, CF.sub.3, CH.sub.3, C.sub.2 H.sub.5, n-C.sub.3 H.sub.7, iso-C.sub.3 H.sub.7, n-C.sub.4 H.sub.9, n-C.sub.5 H.sub.11, n-C.sub.6 H.sub.13, OCH.sub.3, OC.sub.2 H.sub.5, phenyl, C.sub.6 F.sub.5, C.sub.6 Cl.sub.5, CH.sub.2 Cl, CH.sub.2 F, Cl, F, CN, CF.sub.3, C.sub.2 F.sub.5, n-C.sub.3 F.sub.7, iso-C.sub.3 F.sub.7, OCF.sub.3, OC.sub.2 F.sub.5, OC.sub.3 F.sub.7, C(CF.sub.3).sub.3, CH.sub.2 (CF.sub.3), CH(CF.sub.3).sub.2, COCF.sub.3, COC.sub.2 F.sub.5, COCH.sub.3, COC.sub.2 H.sub.5 ; and the second polymer is a microgel particle.
摘要翻译： 本发明是一种涂料组合物，其包含至少一种Tg等于或小于30℃的第一水不溶性聚合物和Tg等于或大于60℃的至少一种第二水不溶性聚合物。其中第一 聚合物包含以下式1表示的单体的重量百分比为75-100的单体：其中：X选自-Cl，-F或-CN，Y各自独立地选自 由H，Cl，F，CN，CF 3，CH 3，C 2 H 5，n-C 3 H 7，异-C 3 H 7，n-C 4 H 9，n -C 5 H 11，n-C 6 H 13，OCH 3，OC 2 H 5，苯基，C 6 F 5，C 6 Cl 5，CH 2 Cl， ，CF 3，CH 2（CF 3），CH（CF 3）2，COCF 3，COC 2 F 5，COCH 3，COC 2 H 5; C 1 -C 3烷基，C 1 -C 6烷基， 并且第二聚合物是微凝胶颗粒。
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公开(公告)号：US06221546B1
公开(公告)日：2001-04-24
申请号：US09354209
申请日：1999-07-15
IPC分类号： G03C1108
CPC分类号： C09D127/16 , B41M5/5254 , B41M7/0036 , G03C1/7614 , G03C7/38 , G03C2001/7448 , G03C2001/7621 , G03C2001/7635 , G03C2200/08 , G03C2200/36 , G03C2200/42 , G03C2200/51 , Y10S430/162
摘要： The present invention is a coating composition comprising a water insoluble polymer having a Tg less than 25° C. and comprising 75 to 100 weight percent of the monomer having the following formula: wherein: X is selected from the group consisting of —Cl, —F, or —CN, and Y is each independently selected from the group consisting of H, Cl, F, CN, CF3, CH3, C2H5, n—C3H7, iso—C3H7, n—C4H9, n—CH11, n—C6H,13, OCH3, OC2H5, phenyl, C6F5, C6Cl5, CH2Cl, CH2F, Cl, F, CN, CF3, C2F5, n—C3F7, iso— C3F7, OCF3, OC2F5, OC3F7, C(CF3)3, CH2(CF3), CH(CF3)2, —COCF3, COC2F5, COCH3, COC2H5.
摘要翻译： 本发明是一种涂料组合物，其包含Tg小于25℃的水不溶性聚合物，并且包含75至100重量％的具有下式的单体：其中：X选自-Cl， - F或-CN，并且Y各自独立地选自H，Cl，F，CN，CF 3，CH 3，C 2 H 5，n-C 3 H 7，异-C 3 H 7，n-C 4 H 9，n-CH 11，n-C 6 H ，13，OCH 3，OC 2 H 5，苯基，C 6 F 5，C 6 Cl 5，CH 2 Cl，CH 2 F，Cl，F，CN，CF 3，C 2 F 5，n -C 3 F 7，异-C 3 F 7，OCF 3，OC 2 F 5，OC 3 F 7，C（CF 3）3，CH 2 ），CH（CF 3）2，-COCF 3，COC 2 F 5，COCH 3，COC 2 H 5。
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公开(公告)号：US06214938B1
公开(公告)日：2001-04-10
申请号：US09567718
申请日：2000-05-10
IPC分类号： C08L3306
CPC分类号： G03C11/08 , B41M7/0036 , G03C1/053 , G03C1/76 , G03C1/85 , G03C5/14 , Y10S430/162
摘要： The present invention is a coating composition comprising at least one first water insoluble polymer having a Tg equal to or less than 30° C. and at least one second water insoluble polymer having a Tg equal to or greater than 60° C. wherein the first polymer comprises a monomer at a weight percent of 75 to 100 of the monomer represented by the following formula 1: wherein: X is selected from the group consisting of —Cl, —F, or —CN, and Y is each independently selected from the group consisting of H, Cl, F, CN, CF3, CH3, C2H5, n—C3H7, iso—C3H7, n—C4H9, n—C5H11, n—C6H13, OCH3, OC2H5, phenyl, C6F5, C6Cl5, CH2Cl, CH2F, Cl, F, CN, CF3, C2F5, n—C3F7, iso—C3F7, OCF3, OC2F5, OC3F7, C(CF3)3, CH2(CF3), CH(CF3)2, COCF3, COC2F5, COCH3, COC2H5; and the second polymer is a microgel particle.
摘要翻译： 本发明是包含Tg等于或小于30℃的至少一种第一水不溶性聚合物和Tg等于或大于60℃的至少一种第二水不溶性聚合物的涂料组合物，其中第一 聚合物包含以下式1表示的单体的重量百分比为75-100的单体：其中：X选自-Cl，-F或-CN，Y各自独立地选自 由H，Cl，F，CN，CF 3，CH 3，C 2 H 5，n-C 3 H 7，异-C 3 H 7，n-C 4 H 9，n -C 5 H 11，n-C 6 H 13，OCH 3，OC 2 H 5，苯基，C 6 F 5，C 6 Cl 5，CH 2 Cl， ，CF 3，CH 2（CF 3），CH（CF 3）2，COCF 3，COC 2 F 5，COCH 3，COC 2 H 5; C 1 -C 3烷基，C 1 -C 6烷基， 并且第二聚合物是微凝胶颗粒。
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公开(公告)号：US06869178B2
公开(公告)日：2005-03-22
申请号：US10289607
申请日：2002-11-07
申请人： Hwei-Ling Yau , David E. Decker , Xiaoru Wang , Wendy S. Krzemien
发明人： Hwei-Ling Yau , David E. Decker , Xiaoru Wang , Wendy S. Krzemien
CPC分类号： B41M5/52 , B41M5/5218 , B41M5/5227 , B41M7/0027
摘要： An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon a fusible, porous, image-receiving layer containing at least two types of hydrophobic polymer particles having different glass transition temperatures, the first type of hydrophobic polymer particles having a Tg higher than about 60° C. that is substantially monodisperse and the second type of hydrophobic polymer particles having a Tg lower than about 25° C.; C) loading the printer with an ink jet ink; and D) printing on the image-receiving layer using the ink jet ink in response to the digital data signals.
摘要翻译： 一种喷墨打印方法，具有以下步骤：A）提供响应于数字数据信号的喷墨打印机; B）使用具有支撑体的喷墨记录元件装载打印机，所述支撑体上具有包含至少两种具有不同玻璃化转变温度的疏水性聚合物颗粒的易熔，多孔的图像接收层，第一类型的疏水性聚合物颗粒具有Tg 高于约60℃，其基本上是单分散的，第二类型的疏水聚合物颗粒的Tg低于约25℃; C）用喷墨墨水装载打印机; 和D）响应于数字数据信号，使用喷墨墨在图像接收层上进行打印。
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公开(公告)号：US07449501B2
公开(公告)日：2008-11-11
申请号：US10984302
申请日：2004-11-09
申请人： David S. Uerz , Hwei-Ling Yau , Wendy S. Krzemien , James A. Reczek , Xiaoru Wang , David E. Decker
发明人： David S. Uerz , Hwei-Ling Yau , Wendy S. Krzemien , James A. Reczek , Xiaoru Wang , David E. Decker
IPC分类号： C09D11/00
CPC分类号： C09D11/40
摘要： This invention relates to an ink jet ink composition comprising an aqueous medium and microgel particles, said particles comprising a crosslinked copolymer prepared from a monomer mixture comprising at least a crosslinking monomer, a polymerizable carboxylic acid monomer, and one or more polymerizable water insoluble vinyl type monomers. The ink composition may be a colorless ink or it may contain a colorant.
摘要翻译： 本发明涉及包含水介质和微凝胶颗粒的喷墨油墨组合物，所述颗粒包含由至少包含交联单体，可聚合羧酸单体和一种或多种可聚合的水不溶性乙烯基类型的单体混合物制备的交联共聚物 单体。 油墨组合物可以是无色油墨，也可以含有着色剂。
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公开(公告)号：US06861114B2
公开(公告)日：2005-03-01
申请号：US10289862
申请日：2002-11-07
申请人： Hwei-Ling Yau , David E. Decker , Xiaoru Wang , Wendy S. Krzemien
发明人： Hwei-Ling Yau , David E. Decker , Xiaoru Wang , Wendy S. Krzemien
CPC分类号： B41M5/52 , B41M5/508 , B41M5/5227
摘要： An ink jet recording element having a support having thereon a fusible, porous, image-receiving layer of at least two types of hydrophobic polymer particles having different glass transition temperatures, the first type of hydrophobic polymer particles having a Tg higher than about 60° C. that is substantially monodisperse and the second type of hydrophobic polymer particles having a Tg lower than about 25° C.
摘要翻译： 一种喷墨记录元件，其具有在其上具有至少两种具有不同玻璃化转变温度的疏水性聚合物颗粒的可熔化，多孔的图像接收层的载体，第一类型的疏水性聚合物颗粒的Tg高于约60℃ ，其基本上是单分散的，第二类型的Tg低于约25℃的疏水聚合物颗粒。
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公开(公告)号：US6147139A
公开(公告)日：2000-11-14
申请号：US144031
申请日：1998-08-31
IPC分类号： B41J2/01 , B41M5/00 , C09D11/00 , C09D11/02 , C09D11/10 , B32B27/10 , C08L33/02 , C08L33/08 , C08L33/10
CPC分类号： C09D11/30 , C09D11/03 , Y10T428/31895
摘要： An ink jet ink comprising a carrier medium, a colorant, and thermoplastic polymeric particles; wherein said polymeric particles have a glass transition temperature between 30.degree. and 200.degree. C., and an average diameter between 10 and 1000 nm.
摘要翻译： 一种喷墨油墨，其包含载体介质，着色剂和热塑性聚合物颗粒; 其中所述聚合物颗粒的玻璃化转变温度为30至200℃，平均直径为10至1000nm。
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公开(公告)号：US4530445A
公开(公告)日：1985-07-23
申请号：US425228
申请日：1982-09-28
申请人： David E. Decker
发明人： David E. Decker
CPC分类号： B43M99/009
摘要： A holder for a multiplicity of paper clips is arranged in an aligned stack disclosed herein having an elongated, hollow housing closed at a dispensing end with a stop defining a partial opening for passing the uppermost clip of the stack. The housing dispensing end includes an outwardly projecting bill or lip adapted to present the uppermost clip in a preparatory position for manual removal from the housing. A spring biasing mechanism is incorporated into the housing closing the end thereof opposite to its clip dispensing end which includes a guide rod projecting through aligned openings in the stack of clips and a slidable foot carrying the clip stack. An expansion spring is disposed on the rod between the foot and a base which is snap-locked with the housing to close the housing storage cavity.
摘要翻译： 用于多个回形针的保持器布置在本文公开的对准的堆叠中，其具有在分配端处封闭的细长的中空壳体，其具有限定用于通过堆叠的最上部的夹子的部分开口的止挡件。 壳体分配端包括向外突出的纸币或唇缘，其适于将最上面的夹子呈现在用于从壳体手动移除的准备位置。 弹簧偏置机构被结合到壳体中，其闭合其与夹子分配端相对的端部，该夹子分配端部包括通过夹子堆叠中的对准开口突出的导杆和承载夹子叠层的可滑动脚。 膨胀弹簧设置在杆之间的杆和基座之间，其与壳体卡扣锁定以关闭壳体储存腔。
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