公开(公告)号：US3642935A

公开(公告)日：1972-02-15

申请号：US3642935D

申请日：1968-08-22

申请人： ICI LTD

发明人： DUNNING ROBERT WILLIAM ,  TAYLOR KEITH ANDREW ,  WALKER JOHN

IPC分类号： B01J31/00 ,  B01J31/24 ,  B01J31/26 ,  C07B61/00 ,  C07C1/00 ,  C07C2/32 ,  C07C2/36 ,  C07C11/02 ,  C07C67/00 ,  C08F4/70 ,  C07C3/10

CPC分类号： B01J31/143 ,  B01J31/1865 ,  B01J31/1875 ,  B01J31/26 ,  B01J2231/20 ,  B01J2531/847 ,  C07C2/32 ,  C07C2/36 ,  C07C2527/126 ,  C07C2527/128 ,  C07C2531/04 ,  C07C2531/14 ,  C07C2531/22 ,  C07C2531/24 ,  C07C2531/30

摘要： PROCESS FOR THE OLIGOMERISATION OF MONOALKENES IN WHICH THE MONOALKENE IS CONTACTED WITH A CATALYST COMPRISING A NICKEL COMPOUND, A SUBSTITUTED ORGANIC HALOPHOSPHINE AND A LEWIS ACID. PREFERABLY THE CATALYST COMPRISES A PREFORMED NICKEL COMPLEX CONTAINING AN APPROPRIATE HALOPHOSPHINE LIGAND OR LIGANDS AND A LEWIS ACID. IN EITHER CASE, THE NICKEL COMPOUND OR COMPLEX IS PREFERABLY CONTACTED WITH AN OLEFIN BEFORE ADDITION OF THE LEWIS ACID.

公开(公告)号：US3436383A

公开(公告)日：1969-04-01

申请号：US3436383D

申请日：1966-05-25

申请人： ICI LTD

发明人： O'BRIEN STEPHEN ,  JANES WILLIAM HENRY ,  TAYLOR KEITH ANDREW ,  TODD PETER FRANK

IPC分类号： C07F7/28 ,  C07F17/00 ,  C08F2/00 ,  C08F4/12 ,  C08F20/44 ,  C08F1/30 ,  C07F11/00

CPC分类号： C08F4/12 ,  C07F7/28 ,  C07F17/00 ,  C08F2/36 ,  C08F20/44

摘要： Polymers of substituted alkenes are made by contacting the alkene with an organo-metallic compound of a metal of Group IVa to VIa of the Mendeleeff Periodic Table of Elements which contains at least one p -allylic ligand. Suitable compounds are tris-(p -allyl) chromium, tris-(p -methallyl) chromium, tris-(p -crotyl) chromium, titanium-(p -methallyl), dimolybdenum tetra-(p -allyl) and bis-(p -allyl) (acetylacetonato) chromium. The organo-metallic compound may be formed in situ. The polymerization may be effected in bulk or the substituted alkene may be dissolved in an organic solvent, e.g. a hydrocarbon or ester. Specified monomers are methyl methacrylate, chloroprene, and acrylonitrile and mixtures thereof with ethylene, propylene, butene-1, or butadiene. Exemplified monomers are methyl methacrylate, chloroprene and acrylonitrile. Stereostructures are given in examples.ALSO:The preparations of organo-metallic compounds of metals of Group IVA to VIA of the Mendeleeff Periodic Table of Elements which contain at least one p -allylic ligand are described. In particular: (1) tris-(p -allyl) chromium by reacting anhydrous CrCl3 with allyl magnesium chloride; (2) dimolybdenum tetra-(p -allyl) by reacting MoCl5 with allyl magnesium chloride; (3) tetrakis-(p -methallyl) titanium by reacting TiCl4 with methallyl magnesium chloride; (4) tris-(p -methallyl) chromium by reacting CrCl3 and methallyl magnesium chloride; and (5) bis-(p -allyl) (acetylacetonate) chromium by reacting tris-(p -allyl) chromium and tris-(acetylacetonate) chromium.

公开(公告)号：US3511891A

公开(公告)日：1970-05-12

申请号：US63965967

申请日：1967-05-19

申请人： ICI LTD

发明人： TAYLOR KEITH ANDREW ,  LEONARD JOHN ALEX

IPC分类号： B01J31/14 ,  B01J31/16 ,  B01J31/24 ,  C07C2/32 ,  C07C2/36 ,  C08F4/70 ,  C07C3/10 ,  C07C11/02

CPC分类号： C07C2/36 ,  B01J31/143 ,  B01J31/24 ,  B01J31/2404 ,  B01J2231/20 ,  B01J2531/847 ,  C07C2/32 ,  C07C2531/14 ,  C07C2531/16

公开(公告)号：US3428661A

公开(公告)日：1969-02-18

申请号：US3428661D

申请日：1966-04-21

申请人： ICI LTD

发明人： TAYLOR KEITH ANDREW

IPC分类号： B01J3/04 ,  B01J19/00 ,  B01J31/16 ,  B01J31/18 ,  B01J31/20 ,  B01J31/22 ,  B01J31/24 ,  C07C5/03 ,  C07C5/08 ,  C08G69/04 ,  C08G69/28 ,  C07F3/10 ,  C07C5/02 ,  C07F9/66

CPC分类号： C07C5/08 ,  B01J3/04 ,  B01J19/0013 ,  B01J31/1895 ,  B01J31/20 ,  B01J31/226 ,  B01J31/2409 ,  B01J2219/00078 ,  B01J2219/00094 ,  B01J2231/645 ,  B01J2531/827 ,  C07C5/03 ,  C07C2531/22 ,  C08G69/04 ,  C08G69/28 ,  Y10S585/906