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公开(公告)号：US20240010798A1
公开(公告)日：2024-01-11
申请号：US18252445
申请日：2021-12-21
Applicant: IDEMITSU KOSAN CO.,LTD.
Inventor： Yoshihito KOYAMA , Toshifumi MIYAGAWA
CPC classification number: C08H6/00 , C08L97/005 , C08K5/13 , C08L61/04 , C08K5/17 , C08L2203/30
Abstract: A lignin composition containing two or more compounds represented by the following formula (1), where the total content of the compounds is 0.06% by mass or more:
where in the formula, Ra is a hydrogen atom, a methyl group, an ethyl group, a furyl group, a hydroxymethylfuryl group, a hydroxyphenyl group, a hydroxymethoxyphenol group, or a hydroxydimethoxyphenol group; Rc1 and Rc2 are independently a hydroxyl group, an alkoxy group, an amino group, or a thiol group; R11 to R20 are independently a hydrogen atom, a hydroxyl group, a hydrocarbon group including 1 to 15 carbon atoms, a hydrocarbon ether group including 1 to 15 carbon atoms, or a group containing a carbonyl group.-
2.发明公开公开(公告)号：US20240239947A1
公开(公告)日：2024-07-18
申请号：US18563399
申请日：2022-05-23
Applicant: IDEMITSU KOSAN CO.,LTD.
Inventor： Toshifumi MIYAGAWA , Yoshihito KOYAMA
CPC classification number: C08G18/6492 , C08G18/12 , C08G18/14 , C08G18/3215 , C08G18/4845 , C08G2101/00 , C08G2110/0025
Abstract: A thermosetting composition comprising a lignin component comprising two or more kinds of compounds represented by the following formula (1) and a polyol, wherein the amount of the lignin component is 0.10% by mass or more, and the total content of the compound is 0.06% by mass or more, based on the total amount of the lignin component:
wherein in the formula, Ra is a hydrogen atom, a methyl group, an ethyl group, a furyl group, a hydroxymethylfuryl group, a hydroxyphenyl group, a hydroxymethoxyphenyl group or a hydroxydimethoxyphenyl group; Rc1 and Rc2 independently represent a hydroxyl group, an alkoxy group, an amino group or thiol group; R11 to R20 are independently a hydrogen atom, a hydroxyl group, a hydrocarbon group having 1 to 15 carbon atoms, a hydrocarbon ether group having 1 to 15 carbon atoms, or a group including a carbonyl group; each of R11 to R20 may be the same as or different from each other; provided that at least one of R11 to R15 is a hydrogen atom, and at least one of R16 to R20 is a hydrogen atom.-
公开(公告)号：US20220119575A1
公开(公告)日：2022-04-21
申请号：US17427313
申请日：2020-02-07
Applicant: IDEMITSU KOSAN CO.,LTD.
Inventor： Yoshihito KOYAMA , Hironori TASHIRO
Abstract: A method for producing a polyphenol derivative, including reacting a polyphenol-containing composition and an aromatic compound having an ortho-para directionality in a solvent, a polyphenol derivative produced by the method for producing a polyphenol derivative, and a polyphenol derivative-containing resin composition material containing the polyphenol derivative.
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公开(公告)号：US20220348725A1
公开(公告)日：2022-11-03
申请号：US17864134
申请日：2022-07-13
Applicant: IDEMITSU KOSAN CO., LTD
Inventor： Hironori TASHIRO , Yoshihito KOYAMA
Abstract: A method for producing a modified lignin, including reacting one or more kind of a second generation ethanol fermentation residue and a second generation ethanol saccharification residue, with a phenol compound, a modified lignin having a ratio ((2H+G)/S) of a total of twice of a relative existence ratio H (%) of an H-type skeleton and a relative existence ratio G (%) of a G-type skeleton with respect to a relative existence ratio S (%) of an S-type skeleton, obtained from integrated values measured by 31P-NMR, of 2.5 or more, and an existence ratio of an aliphatic hydroxy group obtained by the same method of less than 20%, and a modified lignin-containing resin composition material.
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5.发明申请公开(公告)号：US20200377672A1
公开(公告)日：2020-12-03
申请号：US16636600
申请日：2018-08-10
Applicant: IDEMITSU KOSAN CO., LTD.
Inventor： Hironori TASHIRO , Yoshihito KOYAMA
Abstract: A method for producing a modified lignin, including reacting one or more kind of a second generation ethanol fermentation residue and a second generation ethanol saccharification residue, with a phenol compound, a modified lignin having a ratio ((2H+G)/S) of a total of twice of a relative existence ratio H (%) of an H-type skeleton and a relative existence ratio G (%) of a G-type skeleton with respect to a relative existence ratio S (%) of an S-type skeleton, obtained from integrated values measured by 31P-NMR, of 2.5 or more, and an existence ratio of an aliphatic hydroxy group obtained by the same method of less than 20%, and a modified lignin-containing resin composition material.
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Patent Agency Ranking
6.发明申请公开(公告)号：US20190211207A1
公开(公告)日：2019-07-11
申请号：US16330842
申请日：2017-09-04
Applicant: IDEMITSU KOSAN CO., LTD.
Inventor： Yoshihito KOYAMA , Shinobu YAMAO , Masaki OKANO
CPC classification number: C08L97/005 , C08H6/00 , C08J5/00 , C08L61/06 , C08L97/00 , C08L101/00
Abstract: The method for producing a resin composition of the present invention includes a step of obtaining a lignin-containing solution that contains a solubilized lignin prepared through a treatment of separating lignin in a lignin-containing solution and a solvent, and a step of adding a resin to the lignin-containing solution to thereby obtain a lignin/resin-containing solution. Also, the method for producing a resin composition of the present invention includes a step of mixing the lignin/resin-containing solution with at least one solvent selected from water and a hydrocarbon having a dipole moment of 0.25 d or less. The lignin-containing resin molded article of the present invention uses the resin composition obtained according to the production method of the present invention.
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公开(公告)号：US20230025187A1
公开(公告)日：2023-01-26
申请号：US17951913
申请日：2022-09-23
Applicant: IDEMITSU KOSAN CO., LTD.
Inventor： Hironori TASHIRO , Yoshihito KOYAMA
Abstract: A modified lignin having a ratio ((2H+G)/S) of a total of twice of a relative existence ratio H (%) of an H-type skeleton and a relative existence ratio G (%) of a G-type skeleton with respect to a relative existence ratio S (%) of an S-type skeleton, obtained from integrated values measured by 31P-NMR, of 2.5 or more, and an existence ratio of an aliphatic hydroxy group obtained by the same method of less than 20%, a method for producing a modified polyphenol, and a modified lignin-containing resin composition material.
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8.发明申请公开(公告)号：US20200181410A1
公开(公告)日：2020-06-11
申请号：US16635394
申请日：2018-08-10
Applicant: IDEMITSU KOSAN CO., LTD.
Inventor： Hironori TASHIRO , Yoshihito KOYAMA
Abstract: A modified lignin having a ratio ((2H+G)/S) of a total of twice of a relative existence ratio H (%) of an H-type skeleton and a relative existence ratio G (%) of a G-type skeleton with respect to a relative existence ratio S (%) of an S-type skeleton, obtained from integrated values measured by 31P-NMR, of 2.5 or more, and an existence ratio of an aliphatic hydroxy group obtained by the same method of less than 20%, a method for producing a modified polyphenol, and a modified lignin-containing resin composition material.
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9.发明申请公开(公告)号：US20180215878A1
公开(公告)日：2018-08-02
申请号：US15762996
申请日：2016-09-23
Applicant: IDEMITSU KOSAN CO., LTD.
Inventor： Masaki OKANO , Yoshihito KOYAMA , Shinobu YAMAO
CPC classification number: C08H6/00 , C08G8/20 , C08H8/00 , C08L97/005 , C08L101/00
Abstract: Provided is a method of producing a purified lignin, including: treating a plant biomass in a first solvent mixture formed of water and a first organic solvent under specific conditions; subjecting a solid fraction insoluble in a first solution mixture and the first solution mixture to solid-liquid separation after the treatment; mixing the first solution mixture from which the insoluble solid fraction has been separated, and a second organic solvent excluding the first organic solvent and having a dipole moment of 0.25 d or less to provide a second solution mixture; and subjecting a solid fraction insoluble in the second solution mixture to solid-liquid separation to extract the purified lignin in a liquid phase of the second solution mixture.
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10.发明申请公开(公告)号：US20180171552A1
公开(公告)日：2018-06-21
申请号：US15579762
申请日：2016-06-10
Inventor： Yoshihito KOYAMA , Takao MASUDA , Teruoki TAGO
CPC classification number: D21C3/20 , C12P19/02 , C12P19/14 , C12P2201/00 , C13B5/00 , C13K1/02 , D21C3/006
Abstract: The method for producing a cellulose-containing solid material of the invention includes treating a botanical biomass in a mixed solvent of water and at least one alcohol selected from aliphatic alcohols having 4 to 8 carbon atoms, under condition A (the concentration of the raw material to be charged into the mixed solvent is 1% by mass or more and 50% by mass or less), condition B (the reaction temperature is 100° C. or higher and 350° C. or lower), and condition C (the reaction time is 0.1 hours or more and 10 hours or less), followed by solid-liquid separation after the treatment to give a cellulose-containing solid material. Accordingly, there are provided a method for producing a cellulose-containing solid material excellent in saccharification performance and a method for producing glucose from the cellulose-containing solid material.
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