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公开(公告)号：US20190119585A1
公开(公告)日：2019-04-25
申请号：US16169341
申请日：2018-10-24
摘要： Method for starting up a method for producing kerosene and diesel fuel from hydrocarbon compounds produced by Fischer-Tropsch synthesis.The start-up method employs catalytic reaction of Fischer-Tropsch synthesis with a synthesis gas for producing a heavy hydrocarbon fraction and a light hydrocarbon fraction, a reduction (RE) reducing a hydrotreatment catalyst by ensuring contact with a gas comprising hydrogen, bringing the heavy hydrocarbon fraction into contact with the hydrotreatment catalyst (DM). During the step for ensuring contact, the temperature (TEMP) of the catalyst is increased to a temperature of between 260° C. and 360° C. Then, (TR) bringing a mixture comprising the heavy hydrocarbon fraction and the light hydrocarbon fraction into contact with the hydrotreatment catalyst is carried out.
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公开(公告)号：US20200024529A1
公开(公告)日：2020-01-23
申请号：US16512995
申请日：2019-07-16
摘要： Process for the production of middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis comprising at least one light fraction, known as condensate, and a heavy fraction, known as waxes, in which: the said light fraction is stored in a vessel (B) maintained under an inert atmosphere and in which the temperature inside the vessel is maintained at a value of less than 20° C.; the said heavy fraction is stored in a vessel (C) maintained under an inert atmosphere and in which the temperature inside the vessel is maintained at a value of between 80 and 230° C.
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3.发明申请PRODUCTION OF MIDDLE DISTILLATES FROM AN EFFLUENT ORIGINATING FROM FISCHER-TROPSCH SYNTHESIS COMPRISING A STEP OF REDUCING THE CONTENT OF OXYGENATED COMPOUNDS 有权从包含减少含氧化合物含量的步骤的FISCHER-TROPSCH合成处理的液体中产生中间馏分公开(公告)号：US20130270153A1
公开(公告)日：2013-10-17
申请号：US13859789
申请日：2013-04-10
申请人： ENI S.P.A. , IFP ENERGIES NOUVELLES
IPC分类号： C10G65/12
CPC分类号： C10G65/12 , B01J21/12 , B01J23/462 , B01J23/464 , B01J23/755 , B01J23/882 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J35/0026 , B01J35/0066 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J37/0009 , B01J37/0201 , C07C1/0465 , C07C1/12 , C07C5/02 , C07C9/04
摘要： Production of middle distillates from a feedstock produced by Fischer-Tropsch synthesis and containing oxygenated compounds: a) catalytic hydrotreating; b) hydroisomerization/hydrocracking at least a part of liquid and gaseous effluent originating from a); c) gas/liquid separation of the stream from b) into a gaseous fraction comprising predominantly hydrogen, a hydroisomerized/hydrocracked organic liquid fraction and an aqueous fraction; d) fractionation of the organic liquid fraction in c) to obtain at least one fraction of middle distillates; and e) catalytic methanation of CO and CO2 on at least a part of said gaseous fraction in c) before hydrotreating a), and/or on at least a part of the liquid and gaseous effluent originating from a) in which the hydrogen in a) is obtained at least partly from the gaseous fraction separated in c).
摘要翻译： 由费 - 托合成生产含有氧化合物的原料生产中间馏分：a）催化加氢处理; b）加氢异构化/加氢裂化来自a）的至少一部分液体和气态流出物; c）将气流/液体从b）分离成主要包含氢气，加氢异构化/加氢裂化的有机液体馏分和水性馏分的气体馏分; d）有机液体馏分的分馏，c）得到至少一部分中间馏分; 和e）在加氢处理a）之前和/或在至少一部分源自a）的液体和气态流出物中，在c）中的至少一部分所述气态馏分中CO和CO 2的催化甲烷化，其中a） ）至少部分地由在c）中分离的气态馏分获得。
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公开(公告)号：US20200024530A1
公开(公告)日：2020-01-23
申请号：US16513819
申请日：2019-07-17
摘要： A process is described for producing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis and divided into a light fraction (cold condensate) and a heavy fraction (waxes). The process involves fractionation of the waxes to obtain a light fraction, the final boiling point of which is between 350° C. and 400° C., and a heavy fraction which boils above the light fraction. The light fraction is mixed with at least one portion of the cold condensate. The resultant mixture is hydrotreated in the presence of a hydrotreatment catalyst of at least one portion of the resultant effluent is hydroisomerized in the presence of a catalyst comprising at least one noble metal from Group VIII and at least one zeolite IZM-2. At least one portion of the heavy fraction is subjected to hydrocracking and hydroisomerization in the presence of a hydrocracking catalyst. The resultant effluents are fractionated to obtain at least one middle distillates fraction.
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公开(公告)号：US20200024528A1
公开(公告)日：2020-01-23
申请号：US16513106
申请日：2019-07-16
摘要： Process for the production of olefins and of middle distillates from a paraffinic feedstock, in which: a) a paraffinic feedstock resulting from a Fischer-Tropsch unit is recovered, the said feedstock containing a light fraction and a heavy fraction; b) the light fraction is sent to a catalytic cracking unit; c) the effluent resulting from the catalytic cracking unit is separated in a fractionation unit in order to obtain a fraction of light hydrocarbons, an olefinic fraction and a residual liquid fraction; d) the heavy fraction is sent to a hydrocracking/hydroisomerization unit; e) the effluent resulting from the hydrocracking/hydroisomerization unit is separated in a fractionation unit in order to obtain a middle distillates fraction, a naphtha cut having a maximum boiling point of less than 180° C. and an unconverted heavy fraction; f) a part of the naphtha cut resulting from the fractionation unit is sent to the catalytic cracking unit.
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公开(公告)号：US20180369776A1
公开(公告)日：2018-12-27
申请号：US16060117
申请日：2016-11-08
发明人： Regis DESGRANGES , Jean-Philippe HERAUD , Jean-Christophe VIGUIE , Sebastien BOUCHER , Chiara DELLA TORRE , Elsa MIGNONE
摘要： A method for charging a catalyst into a reactor (40) comprising a separation loop (21), comprising the following steps: a) filling the reactor (40) with a solvent S1; b) filling the separation loop (21) with said solvent S1; c) causing said solvent S1 to move in the synthesis reactor (40) and the separation loop (21); d) heating the reactor (40) to a temperature of 100° C. or less; e) injecting an inert gas into the bottom of the reactor (40); f) mixing said catalyst with a solvent S2 in a vessel (30) in order to obtain a liquid/solid mixture; g) increasing the pressure in the vessel (30) then sending the liquid/solid mixture to the reactor (40); h) withdrawing said solvent S1 and/or S2.
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