公开(公告)号：US11071971B2

公开(公告)日：2021-07-27

申请号：US16471403

申请日：2017-12-21

申请人： IFP Energies nouvelles ,  TOTAL RAFFINAGE CHIMIE

发明人： Arnold Lambert ,  Catherine Laroche ,  Delphine Marti ,  Elodie Comte

IPC分类号： B01J29/89 ,  B01J23/00 ,  B01J23/72 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/08 ,  F23C10/01 ,  F23C13/08

摘要： The invention relates to an oxygen carrier solid, its preparation and its use in a method of combustion of a hydrocarbon feedstock by active mass chemical-looping oxidation-reduction, i.e. chemical-looping combustion (CLC). The solid, which is in the form of particles, comprises an oxidation-reduction active mass composed of metal oxide(s) dispersed in a ceramic matrix comprising at least at least one feldspar or feldspathoid with a melting point higher than 1500° C., such as celsian, and has, initially, a specific macroporous texture. The oxygen carrier solid is prepared from a precursor of the ceramic matrix, obtained from a macroporous zeolitic material with zeolite crystals of a specific size, and a precursor of the oxidation-reduction active mass.

公开(公告)号：US11717811B2

公开(公告)日：2023-08-08

申请号：US16471499

申请日：2017-12-21

申请人： IFP Energies nouvelles ,  TOTAL RAFFINAGE CHIMIE

发明人： Arnold Lambert ,  Mathieu Michau ,  Delphine Marti ,  Elodie Comte

IPC分类号： B01J23/72 ,  B01J21/04 ,  B01J21/12 ,  B01J35/10 ,  B01J35/02 ,  B01J37/03 ,  B01J37/08 ,  B01J37/00 ,  F23C10/01 ,  F23C10/04 ,  F23C13/08 ,  B01J37/02

CPC分类号： B01J23/72 ,  B01J21/04 ,  B01J21/12 ,  B01J35/023 ,  B01J35/026 ,  B01J35/108 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1076 ,  B01J37/0018 ,  B01J37/0203 ,  B01J37/0207 ,  B01J37/0236 ,  B01J37/038 ,  B01J37/08 ,  F23C10/01 ,  F23C10/04 ,  F23C13/08

摘要： The invention relates to an oxygen carrier solid, its preparation and its use in a method of combustion of a hydrocarbon feedstock by active mass chemical-looping oxidation-reduction, i.e. chemical-looping combustion (CLC). The solid, which is in the form of particles, comprises an oxidation-reduction active mass composed of metal oxide(s) dispersed in a ceramic matrix comprising at least one oxide with a melting point higher than 1500° C., such as alumina, and has, initially, a specific macroporous texture. The oxygen carrier solid is prepared from an aqueous suspension containing precursor oxide grains for the ceramic matrix that have a specific size, by a spray-drying technique.