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公开(公告)号：US10899682B2
公开(公告)日：2021-01-26
申请号：US16330785
申请日：2017-09-06
IPC分类号： B01J29/06 , C07C1/24 , B01J29/65 , C01B39/02 , B01J21/08 , B01J35/02 , B01J37/00 , B01J29/40 , B01J35/00 , B01J37/12 , B01J29/70 , B01J37/14 , B01J37/30 , C07C5/27 , B01J29/08 , C07C11/09
摘要： Process for preparing a catalyst composition containing a modified crystalline aluminosilicate and a binder, wherein the catalyst composition comprises from 5 to 95% by weight of crystalline aluminosilicate as based on the total weight of the catalyst composition, the process being remarkable in that it comprises a step of steaming said crystalline aluminosilicate: at a temperature ranging from 100° C. to 380° C.; under a gas phase atmosphere containing from 5 wt % to 100 wt % of steam; at a pressure ranging from 2 to 200 bars; at a partial pressure of H2O ranging from 2 to 200 bars; and said steaming being performed during at least 30 min and up to 144 h; and in that the process also comprises a step of shaping, or of extruding, the crystalline aluminosilicate with a binder, wherein the binder is selected to comprise at least 85 wt % of silica as based on the total weight of the binder, and less than 1000 ppm by weight as based on the total weight of the binder of aluminium, gallium, boron, iron and/or chromium.
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公开(公告)号：US09902662B2
公开(公告)日：2018-02-27
申请号：US15038830
申请日：2014-10-08
发明人： Nicolas Aribert , Laure Brandhorst , Vincent Coupard , Sylvie Maury , Tom Vivien
IPC分类号： C07C1/24 , C07C29/149 , C07C67/08 , B01J21/04 , B01J35/10
CPC分类号： C07C1/24 , B01J21/04 , B01J35/1019 , B01J35/1061 , C07C29/149 , C07C67/08 , C07C2521/04 , Y02P20/52 , C07C11/04 , C07C11/06 , C07C69/24 , C07C31/08 , C07C31/10
摘要： The present invention relates to a process for the production of a mixture of ethylene and propylene from a mixture containing ethanol and n-propanol and having a water content comprised between 30 and 75% by weight with respect to the total weight of the mixture.
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3.发明授权公开(公告)号：US09079812B2
公开(公告)日：2015-07-14
申请号：US13646002
申请日：2012-10-05
发明人： Vincent Coupard , Natacha Touchais , Stephanie Fleurier , Helena Gonzalez Penas , Philip De Smedt , Walter Vermeiren , Cindy Adam , Delphine Minoux
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , C07C2529/40 , Y02P30/48 , C07C11/04
摘要： A process for dehydration of an ethanol feedstock into ethylene, comprising the vaporization of said dilute hydrated ethanol feedstock in an exchanger, with heat exchange with the effluent that is obtained from a last reactor, with said mixture being introduced into said vaporization stage at a pressure that is lower than the pressure of the effluent that is obtained from the last reactor, the compression of the mixture that is vaporized in a compressor, the introduction of the vaporized and compressed mixture, into at least one adiabatic reactor that contains at least one dehydration catalyst.
摘要翻译： 一种将乙醇原料脱水成乙烯的方法，包括在交换器中蒸发所述稀水合乙醇原料，与最后一个反应器获得的流出物进行热交换，所述混合物在压力下被引入所述蒸发阶段 低于从最后一个反应器获得的流出物的压力，在压缩机中蒸发的混合物的压缩，将蒸发和压缩的混合物引入到至少一个绝热反应器中，该绝热反应器含有至少一个脱水 催化剂。
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4.发明授权公开(公告)号：US11117844B2
公开(公告)日：2021-09-14
申请号：US16629620
申请日：2018-07-10
摘要： The invention relates to a process for dehydrating alcohols to olefins, comprising a reaction step and a catalyst selectivation step.
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公开(公告)号：US10773250B2
公开(公告)日：2020-09-15
申请号：US16680709
申请日：2019-11-12
发明人： Nikolai Nesterenko , Delphine Minoux , Nadiya Danilina , Jean-Pierre Dath , Vincent Coupard , Sylvie Maury
IPC分类号： B01J29/06 , B01J29/67 , B01J29/65 , B01J29/66 , B01J29/68 , B01J29/69 , B01J37/02 , C01B39/02 , C07C1/24 , B01J29/90 , B01J29/70 , C07C5/27 , B01J37/30 , C01B39/44 , B01J29/74
摘要： The present invention relates to a catalyst composition comprising a modified crystalline aluminosilicate of the Framework Type FER having Si/Al framework molar/ratio greater than 20 characterized in that in said modified crystalline aluminosilicate the ratio between the strong acid sites and the weak acid sites, S/W, is lower than 1.0 and having the extra framework aluminum (EFAL) content lowered to less than 10 wt % preferably 5 wt % even more preferably less than 2 wt % measured by 27Al MAS NMR. The present invention further relates to a process for producing olefins from alcohols in presence of said catalyst composition.
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公开(公告)号：US10604456B2
公开(公告)日：2020-03-31
申请号：US16134363
申请日：2018-09-18
发明人： Kirill Drobyshev , Vincent Coupard , Jean-Christophe Gabelle , Nikolai Nesterenko , Christophe Thille
摘要： This invention relates to a method for dehydration of alcohols into olefins comprising an improved step for recovery of unreacted alcohol.
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公开(公告)号：US10472300B2
公开(公告)日：2019-11-12
申请号：US15540327
申请日：2015-12-18
发明人： Delphine Minoux , Nikolai Nesterenko , Cindy Adam , Walter Vermeiren , Philip De Smedt , Jean-Pierre Dath , Vincent Coupard , Sylvie Maury , Nicolas Aribert
摘要： The present invention is a process for dehydrating an alcohol to prepare a corresponding olefin, comprising: (a) providing a composition (A) comprising at least an alcohol having at least 2 carbon atoms, optionally water, optionally an inert component, in a dehydration unit, (b) placing the composition (A) into contact with an acidic catalyst in a reaction zone of said dehydration unit at conditions effective to dehydrate at least a portion of the alcohol to make a corresponding olefin, (c) recovering from said dehydration unit an effluent (B) comprising: at least an olefin, water, undesired by-products including aldehydes and light products, optionally unconverted alcohol(s), optionally the inert component, wherein, said composition (A)—providing step (a) comprises adding an effective amount of one or more sulfur containing compound capable to reduce the undesired by-products by comparison with a non introduction of such sulfur containing compound. The component introduced at step (a) can be chosen from the group consisting of thiols, sulfides, disulfides.
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8.发明申请公开(公告)号：US20150291485A1
公开(公告)日：2015-10-15
申请号：US14647174
申请日：2013-11-18
发明人： Vincent Coupard , Natacha Touchais , Thomas Plennevaux , Emilie Kobel , Stephanie Fleurier , Walter Vermeiren , Delphine Minoux , Philip De Smedt , Cindy Adam , Nikolai Nesterenko
CPC分类号： C07C1/24 , C07C29/76 , C07C41/09 , C07C2527/173 , C07C2529/40 , C07C2529/85 , C07C11/04 , C07C43/06 , C07C31/08
摘要： The invention relates to a process for dehydration of an ethanol feedstock into ethylene comprising at least the stages: a) A stage for pretreatment of the ethanol feedstock on an acidic solid, b) A stage for evaporation of said pretreated ethanol feedstock in a heat exchanger, c) A stage for superheating said evaporated feedstock in such a way as to bring it to an inlet temperature that is compatible with the temperature of a dehydration reaction, d) A stage for dehydration of said feedstock that is obtained from stage c) in at least one adiabatic reactor that contains at least one dehydration catalyst.
摘要翻译： 本发明涉及一种将乙醇原料脱水成乙烯的方法，至少包括以下阶段：a）用于在酸性固体上预处理乙醇原料的阶段，b）在热交换器中蒸发所述预处理的乙醇原料的阶段 c）用于使所述蒸发的原料过热以使其达到与脱水反应的温度相适应的入口温度的阶段，d）用于脱水所述原料的阶段，其从阶段c） 至少一个含有至少一种脱水催化剂的绝热反应器。
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9.发明授权公开(公告)号：US11584698B2
公开(公告)日：2023-02-21
申请号：US17124631
申请日：2020-12-17
IPC分类号： C07C1/24 , B01J29/65 , C01B39/02 , B01J21/08 , B01J35/02 , B01J37/00 , B01J29/40 , B01J35/00 , B01J37/12 , B01J29/70 , B01J37/14 , B01J37/30 , C07C5/27 , B01J29/08 , C07C11/09
摘要： Process for preparing a catalyst composition containing a modified crystalline aluminosilicate and a binder, wherein the catalyst composition comprises from 5 to 95% by weight of crystalline aluminosilicate as based on the total weight of the catalyst composition, the process being remarkable in that it comprises a step of steaming said crystalline aluminosilicate: at a temperature ranging from 100° C. to 380° C.; under a gas phase atmosphere containing from 5 wt % to 100 wt % of steam; at a pressure ranging from 2 to 200 bars; at a partial pressure of H2O ranging from 2 to 200 bars; and said steaming being performed during at least 30 min and up to 144 h; and in that the process also comprises a step of shaping, or of extruding, the crystalline aluminosilicate with a binder, wherein the binder is selected to comprise at least 85 wt % of silica as based on the total weight of the binder, and less than 1000 ppm by weight as based on the total weight of the binder of aluminium, gallium, boron, iron and/or chromium.
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公开(公告)号：US11267771B2
公开(公告)日：2022-03-08
申请号：US16968186
申请日：2019-01-28
摘要： The present invention relates to a process for treating, by reactive distillation, an olefinic feedstock comprising linear olefins containing n carbon atoms, and branched olefins, the branched olefins comprising tertiary branched olefins, for example a mixture of n-butenes and of tertiary branched olefins comprising isobutene, so as to produce an olefinic effluent with a mass content of tertiary branched olefin of less than or equal to 3% by weight and a heavy hydrocarbon effluent, said process comprising the feeding of a reactive distillation section with said olefinic feedstock and with an alcohol feedstock comprising a primary alcohol, said reactive distillation section comprising a column composed at least of an upper reflux zone into which is introduced said alcohol feedstock, comprising, for example, ethanol, an intermediate reaction zone comprising at least 6 reactive doublets, and a lower fractionation zone at the level of which said section is fed with said olefinic feedstock, said reactive distillation section being operated at a relative pressure of between 0.3 and 0.5 MPa, a column head temperature of between 40° C. and 60° C., with a reflux ratio of between 1.8 and 2.2.
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