摘要:
Method for impregnating a Group VIII metal on a molecular sieve—binder extrudate wherein the binder comprises a low acidity refractory oxide binder material, which is essentially free of alumina, by a) contacting the molecular sieve—binder extrudate with an aqueous solution of a corresponding Group VIII metal nitrate salt having a pH of below 8, wherein the molar ratio between the Group VIII metal cations in the solution and the number of sorption sites present in the extrudate is equal to or larger than 1, and b) drying the molecular sieve—binder extrudate obtained from step a).
摘要:
A method for removing nitrogen oxides from exhaust gases containing oxygen and moisture, which comprises bringing the exhaust gas into contact with hydrogenated zeolite catalysts or hydrogenated zeolite catalysts impregnated with one or more kinds of metals selected from the group consisting of copper, zinc, vanadium, chromium, manganese, iron, cobalt, nickel, rhodium, palladium, platinum, and molybdenum, in the presence of organic compounds. The zeolite should be a zeolite having a silica/alumina ratio of 5 or above. The zeolite may be any one of zeolite of Y type, zeolite of L type, zeolite of offretite-erionite mixed crystal type, zeolite of ferrierite type, zeolite of mordenite type, zeolite of clinoptilolite type, and zeolite of ZSM-5 type.
摘要:
Provided herein is a catalytic article including a catalytic coating disposed on a substrate, wherein the catalytic coating comprises a bottom coating on the substrate and a top coating layer on the bottom coating layer, one such coating layer containing a platinum group metal on a refractory metal oxide support and the other such coating layer containing a ceria-containing molecular sieve. Such catalytic articles are effective toward treating exhaust gas streams of internal combustion engines and exhibit outstanding resistance to sulfur.
摘要:
The honeycomb catalyst body is equipped with a honeycomb structure body having partition walls that define a plurality of cells extending from a first end face as one of the end faces to a second end face as the other end face and serving as through channels of a fluid. The partition walls each have a base layer containing from 50 to 90 mass % of zeolite and a coat layer with which the surface of the base layer 11 is coated with a thickness of from 1 to 50 μm. The coat layer is either a coat layer (A) containing from 1 to 5 mass % vanadia and titania or a coat layer (B) containing from 1 to 5 mass % vanadia and a composite oxide of titania and tungsten oxide.
摘要:
The present invention concerns a catalyst comprising at least one crystalline material comprising silicon with a hierarchical and organized porosity and at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and/or group VIII of the periodic table of the elements. Said crystalline material comprising silicon with a hierarchical and organized porosity is constituted by at least two spherical elementary particles, each of said particles comprising a matrix based on oxide of silicon, which is mesostructured, with a mesopore diameter in the range 1.5 to 30 nm and having microporous and crystalline walls with a thickness in the range 1.5 to 60 nm, said elementary spherical particles having a maximum diameter of 200 microns. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
摘要:
This invention relates to a process in which a linear olefin is converted under isomerizing conditions to its corresponding methyl branched isoolefin by contact at a temperature of from 200.degree. C. to 650.degree. C. with an isomerizing catalyst comprising (i) at least one zeolite having only in one dimension a pore structure having a pore size small enough to retard by-product dimerization and coke formation and large enough to permit entry of the linear olefin and allow formation of the methyl branched isoolefin, (ii) an alumina binder and (iii) up to about 15% by weight of coke oxidation-promoting metal. After a period of operation, when sufficient coke has deposited on the catalyst in an amount to significantly reduce the activity of the catalyst, the catalyst is stripped of hydrocarbon and then contacted at elevated temperature with an oxygen-containing gas for a sufficient time to burn off the coke, i.e., to regenerate the catalyst at a temperature of less than about 565.degree. C. After regeneration, the isomerization process is continued. The use of palladium and/or platinum as the coke oxidation-promoting metal is particularly desirable.
摘要:
A hydrogenolysis bimetallic supported catalyst comprising a first metal, a second metal, and a zeolitic support; wherein the first metal and the second metal are different; and wherein the first metal and the second metal can each independently be selected from the group consisting of iridium (Ir), platinum (Pt), rhodium (Rh), ruthenium (Ru), palladium (Pd), molybdenum (Mo), tungsten (W), nickel (Ni), and cobalt (Co).
摘要:
Cluster-supporting catalyst having an improved heat resistivity, and method for producing the same are provided. The cluster-supporting catalyst includes boron-substitute zeolite particles, and catalyst metal clusters supported within the pores of the boron-substitute zeolite particles. The method for producing a cluster-supporting catalyst, includes the following steps: providing a dispersion liquid containing a dispersion medium and boron-substitute zeolite particles dispersed in the dispersion medium; and in the dispersion liquid, forming catalyst metal clusters having a positive charge, and supporting the catalyst metal clusters on the acid sites within the pores of the boron-substitute zeolite particles through an electrostatic interaction.
摘要:
A process is disclosed for decreasing the emission of airborne pollutants from an oil refinery and for upgrading a paraffinic feedstream to olefins and/or aromatics. Flue gas from a fluid catalytic cracking process catalyst regenerator is cooled to supply the endothermic heat of reaction for a paraffin upgrading reaction, eliminating the need for an additional process furnace. The process further decreases airborne pollutant emissions by upgrading paraffinic fractions which would otherwise be burned as fuel.
摘要:
A Process is disclosed for the preparation of zeolite ferrierite of high purity by hydrothermal crystallization from a starting mixture containing at least one compound selected from piperidine and alkyl-substituted piperidines.