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公开(公告)号:US10287383B2
公开(公告)日:2019-05-14
申请号:US15355697
申请日:2016-11-18
IPC分类号: C08F251/02 , B01J20/24 , C08B3/08 , C08B15/00 , D21H27/00 , D21H11/16 , D21H11/20 , D21H17/37 , D01F11/02 , B01J20/26 , B01J20/28 , D01F2/00
摘要: Grafted, crosslinked cellulosic materials include cellulose fibers and polymer chains composed of at least one monoethylenically unsaturated acid group-containing monomer (such as acrylic acid) grafted thereto, in which one or more of said cellulose fibers and said polymer chains are crosslinked (such as by intra-fiber chain-to-chain crosslinks). Some of such materials are characterized by a wet bulk of about 10.0-17.0 cm3/g, an IPRP value of about 1000 to 7700 cm2/MPa·sec, and/or a MAP value of about 7.0 to 38 cm H2O. Methods for producing such materials may include grafting polymer chains from a cellulosic substrate, followed by treating the grafted material with a crosslinking agent adapted to effect crosslinking of one or more of the cellulosic substrate or the polymer chains. Example crosslinking mechanisms include esterfication reactions, ionic reactions, and radical reactions, and example crosslinking agents include pentaerythritol, homopolymers of the graft species monomer, and hyperbranched polymers.
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公开(公告)号:US20200087435A1
公开(公告)日:2020-03-19
申请号:US16549903
申请日:2019-08-23
IPC分类号: C08F251/02 , B01J20/28 , B01J20/26 , B01J20/24 , D01F11/02 , D21H17/37 , D21H11/20 , D21H11/16 , D21H27/00 , C08B15/00 , C08B3/08 , D21H21/22 , D21C9/00
摘要: Grafted, crosslinked cellulosic materials include cellulose fibers and polymer chains composed of at least one monoethylenically unsaturated acid group-containing monomer (such as acrylic acid) grafted thereto, in which one or more of said cellulose fibers and said polymer chains are crosslinked (such as by intra-fiber chain-to-chain crosslinks). Some of such materials are characterized by a wet bulk of about 10.0-17.0 cm3/g, an IPRP value of about 1000 to 7700 cm2/MPa·sec, and/or a MAP value of about 7.0 to 38 cm H2O. Methods for producing such materials may include grafting polymer chains from a cellulosic substrate, followed by treating the grafted material with a crosslinking agent adapted to effect crosslinking of one or more of the cellulosic substrate or the polymer chains. Example crosslinking mechanisms include esterfication reactions, ionic reactions, and radical reactions, and example crosslinking agents include pentaerythritol, homopolymers of the graft species monomer, and hyperbranched polymers.
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公开(公告)号:US20180087216A1
公开(公告)日:2018-03-29
申请号:US15829745
申请日:2017-12-01
发明人: Angel Stoyanov , Joerg Endres , Holger Beruda , Ludwig Busam
摘要: Bleached polyacrylic acid crosslinked cellulose fibers with reduced furfural content are disclosed. The reduced furfural content is accompanied by a strong reduction of malodor associated with crosslinked fibers. Methods of furfural reduction include treatment with hydrogen peroxide in the absence of alkaline or other bleaching agents subsequent to curing polyacrylic acid crosslinked cellulose fibers. Some embodiments of treated polyacrylic acid crosslinked cellulose fibers have a furfural content lower than 1.3 ppm. In some embodiments, the reduction of furfural content of the treated crosslinked fibers compared to untreated crosslinked fibers is at least 55%. In some embodiments, furfural content decreases with aging of the treated crosslinked fibers.
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公开(公告)号:US20230383461A1
公开(公告)日:2023-11-30
申请号:US18449233
申请日:2023-08-14
发明人: Angel Stoyanov , Joerg Endres , Holger Beruda , Ludwig Busam
摘要: Bleached polycrylic acid crosslinked cellulose fibers with reduced furfural content are disclosed. The reduced furfural content is accompanied by a strong reduction of malodor associated with crosslinked fibers. Methods of furfural reduction include treatment with hydrogen peroxide in the absence of alkaline or other bleaching agents subsequent to curing polyacrylic acid crosslinked cellulose fibers. Some embodiments of treated polycrylic acid crosslinked cellulose fibers have a furfural content lower than 1.3 ppm. In some embodiments, the reduction of furfural content of the treated crosslinked fibers compared to untreated crosslinked fibers is at least 55%. in some embodiments, furfural content decreases with aging of the treated crosslinked fibers.
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公开(公告)号:US11725339B2
公开(公告)日:2023-08-15
申请号:US16788165
申请日:2020-02-11
发明人: Angel Stoyanov , Joerg Endres , Holger Beruda , Ludwig Busam
摘要: Bleached polyacrylic acid crosslinked cellulose fibers with reduced furfural content are disclosed. The reduced furfural content is accompanied by a strong reduction of malodor associated with crosslinked fibers. Methods of furfural reduction include treatment with hydrogen peroxide in the absence of alkaline or other bleaching agents subsequent to curing polyacrylic acid crosslinked cellulose fibers. Some embodiments of treated polyacrylic acid crosslinked cellulose fibers have a furfural content lower than 1.3 ppm. In some embodiments, the reduction of furfural content of the treated crosslinked fibers compared to untreated crosslinked fibers is at least 55%. in some embodiments, furfural content decreases with aging of the treated crosslinked fibers.
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公开(公告)号:US20230212341A1
公开(公告)日:2023-07-06
申请号:US18174747
申请日:2023-02-27
IPC分类号: C08F251/02 , B01J20/24 , D21H17/37 , C08B15/00 , D21C9/00 , D01F11/02 , B01J20/26 , B01J20/28 , C08B3/08 , D21H11/20 , D21H21/22 , D21H27/00 , D21H11/16 , D01F2/00
CPC分类号: C08F251/02 , B01J20/24 , B01J20/265 , B01J20/267 , B01J20/28023 , C08B3/08 , C08B15/005 , D01F11/02 , D21C9/005 , D21H11/16 , D21H11/20 , D21H17/37 , D21H21/22 , D21H27/002 , D01F2/00
摘要: Grafted, crosslinked cellulosic materials include cellulose fibers and polymer chains composed of at least one monoethylenically unsaturated acid group-containing monomer (such as acrylic acid) grafted thereto, in which one or more of said cellulose fibers and said polymer chains are crosslinked (such as by intra-fiber chain-to-chain crosslinks). Some of such materials are characterized by a wet bulk of about 10.0-17.0 cm3/g, an IPRP value of about 1000 to 7700 cm2/MPa·sec, and/or a MAP value of about 7.0 to 38 cm H2O. Methods for producing such materials may include grafting polymer chains from a cellulosic substrate, followed by treating the grafted material with a crosslinking agent adapted to effect crosslinking of one or more of the cellulosic substrate or the polymer chains. Example crosslinking mechanisms include esterfication reactions, ionic reactions, and radical reactions, and example crosslinking agents include pentaerythritol, homopolymers of the graft species monomer, and hyperbranched polymers.
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公开(公告)号:US11591429B2
公开(公告)日:2023-02-28
申请号:US17241421
申请日:2021-04-27
IPC分类号: C08F251/02 , C08B3/08 , C08B15/00 , D21H27/00 , D21H11/16 , D21H11/20 , D21H17/37 , D01F11/02 , D21C9/00 , D21H21/22 , B01J20/24 , B01J20/26 , B01J20/28 , D01F2/00
摘要: Grafted, crosslinked cellulosic materials include cellulose fibers and polymer chains composed of at least one monoethylenically unsaturated acid group-containing monomer (such as acrylic acid) grafted thereto, in which one or more of said cellulose fibers and said polymer chains are crosslinked (such as by intra-fiber chain-to-chain crosslinks). Some of such materials are characterized by a wet bulk of about 10.0-17.0 cm3/g, an IPRP value of about 1000 to 7700 cm2/MPa·sec, and/or a MAP value of about 7.0 to 38 cm H2O. Methods for producing such materials may include grafting polymer chains from a cellulosic substrate, followed by treating the grafted material with a crosslinking agent adapted to effect crosslinking of one or more of the cellulosic substrate or the polymer chains. Example crosslinking mechanisms include esterfication reactions, ionic reactions, and radical reactions, and example crosslinking agents include pentaerythritol, homopolymers of the graft species monomer, and hyperbranched polymers.
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公开(公告)号:US20210246247A1
公开(公告)日:2021-08-12
申请号:US17241421
申请日:2021-04-27
IPC分类号: C08F251/02 , C08B3/08 , C08B15/00 , D21H27/00 , D21H11/16 , D21H11/20 , D21H17/37 , D01F11/02 , D21C9/00 , D21H21/22 , B01J20/24 , B01J20/26 , B01J20/28
摘要: Grafted, crosslinked cellulosic materials include cellulose fibers and polymer chains composed of at least one monoethylenically unsaturated acid group-containing monomer (such as acrylic acid) grafted thereto, in which one or more of said cellulose fibers and said polymer chains are crosslinked (such as by intra-fiber chain-to-chain crosslinks). Some of such materials are characterized by a wet bulk of about 10.0-17.0 cm3/g, an IPRP value of about 1000 to 7700 cm2/MPa·sec, and/or a MAP value of about 7.0 to 38 cm H2O. Methods for producing such materials may include grafting polymer chains from a cellulosic substrate, followed by treating the grafted material with a crosslinking agent adapted to effect crosslinking of one or more of the cellulosic substrate or the polymer chains. Example crosslinking mechanisms include esterfication reactions, ionic reactions, and radical reactions, and example crosslinking agents include pentaerythritol, homopolymers of the graft species monomer, and hyperbranched polymers.
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公开(公告)号:US20200181840A1
公开(公告)日:2020-06-11
申请号:US16788165
申请日:2020-02-11
发明人: Angel Stoyanov , Joerg Endres , Holger Beruda , Ludwig Busam
摘要: Bleached polycrylic acid crosslinked cellulose fibers with reduced furfural content are disclosed. The reduced furfural content is accompanied by a strong reduction of malodor associated with crosslinked fibers. Methods of furfural reduction include treatment with hydrogen peroxide in the absence of alkaline or other bleaching agents subsequent to curing polyacrylic acid crosslinked cellulose fibers. Some embodiments of treated polycrylic acid crosslinked cellulose fibers have a furfural content lower than 1.3 ppm. In some embodiments, the reduction of furfural content of the treated crosslinked fibers compared to untreated crosslinked fibers is at least 55%. in some embodiments, furfural content decreases with aging of the treated crosslinked fibers.
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