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公开(公告)号：US4900707A
公开(公告)日：1990-02-13
申请号：US283658
申请日：1988-12-13
摘要： An improved wax isomerization catalyst is described which is a hydrogenation metal on halogenated refractory metal oxide support catalyst characterized in that the catalyst is prepared by depositing the hydrogenation metal on the refractory metal oxide support followed by fluoriding using a low pH fluorine source such as aqueous HF. Thereafter the catalyst is crushed to expose inner surfaces, the crushed catalyst being sieved to remove fines, the catalyst charge having an average particle diameter of 1/32 inch and smaller across the longest continuous cross sectional dimension, preferably between 1/64 to 1/32". Alternatively, the catalyst is made by depositing a hydrogenation metal on a refractory metal support, crushing the material to a particle size of 1/32 inch and smaller across the longest continuous cross-sectional dimension and fluoriding said material using acidic fluorine source such as HF. Following sizing the sized catalyst is activated by heating in a hydrogen atmosphere.Isomerization using this "sized" catalyst is marked by the production of an isomerized dewaxed oil product having unexpectedly high VI and superior levels of selective conversion of wax to liquid isomerized product.
摘要翻译： 描述了一种改进的蜡异构化催化剂，其是卤化难熔金属氧化物载体催化剂上的氢化金属，其特征在于通过将氢化金属沉积在难熔金属氧化物载体上然后使用低pH氟源如HF水溶液进行氟化而制备催化剂 。 此后，将催化剂粉碎以暴露内表面，将破碎的催化剂筛分以除去细粒，催化剂装料的平均粒径为最大连续横截面尺寸为1/32英寸且较小，优选为1/64至1 / 32“。 或者，催化剂通过在难熔金属载体上沉积氢化金属制成，通过最长的连续横截面尺寸将材料粉碎至1/32英寸或更小的粒度，并使用酸性氟源如HF氟化所述材料 。 在定尺寸之后，通过在氢气氛中加热来活化大小的催化剂。 使用这种“大小”催化剂的异构化的特征在于生产具有出人意料的高VI的异构化脱蜡油产物和优异的蜡向液体异构化产物的选择性转化。
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公开(公告)号：US4449991A
公开(公告)日：1984-05-22
申请号：US451102
申请日：1982-12-20
IPC分类号： B01D53/04
CPC分类号： B01D53/04 , B01D2253/104 , B01D2257/30 , B01D2259/402 , B01D2259/41
摘要： A process utilizing a sorbent in a manner which provides a greater and more efficient utilization of the sorbent for the removal of sulfur, or sulfur-containing compounds, from a process streamwherein a sulfur-containing process stream is passed through a fixed-bed of sorbent from one side of the bed to the opposite side, sulfur removed, and passage of the sulfur-containing process stream through said fixed-bed of sorbent continued to breakthrough of sulfur from the exit side of the bed. Then the direction of flow of the sulfur-containing process stream is reversed without desorption of the sulfur from the sorbent, and passage of the sulfur-containing process stream in said reverse direction through the bed again continued until breakthrough of sulfur from the side of the sorbent bed opposite the former entry side. In a preferred embodiment, two or more of the fixed-beds of sorbent are staged, or placed in series.
摘要翻译： 一种利用吸附剂的方法，其提供了更大和更有效地利用吸附剂从工艺流中除去硫或含硫化合物，其中含硫工艺物流通过固定床 吸附剂从床的一侧到相对侧，除去硫，并且含硫工艺流通过所述固定床吸附剂的继续从床的出口侧穿过硫。 然后，含硫工艺流的流动方向相反，而硫从吸附剂中解吸，并且含硫工艺物流沿所述相反方向再次通过床，继续直到硫从侧面通过 吸附剂床与前进入口相对。 在优选的实施方案中，两个或更多个固定床的吸附剂分级或串联放置。
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3.发明授权公开(公告)号：US06221240B1
公开(公告)日：2001-04-24
申请号：US09326827
申请日：1999-06-07
申请人： Darryl P. Klein , Michele S. Touvelle , Edward S. Ellis , Carl W. Hudson , Sylvain Hantzer , Jingguang Chen , David E. W. Vaughan , Michel Daage , James J. Schorfheide , William C. Baird, Jr. , Gary B. McVicker
发明人： Darryl P. Klein , Michele S. Touvelle , Edward S. Ellis , Carl W. Hudson , Sylvain Hantzer , Jingguang Chen , David E. W. Vaughan , Michel Daage , James J. Schorfheide , William C. Baird, Jr. , Gary B. McVicker
IPC分类号： C10G4500
CPC分类号： C10G25/003 , C10G45/10
摘要： A process for the hydrodesulfurization (HDS) of multiple condensed ring heterocyclic organosulfur compounds present in petroleum and petrochemical streams and the saturation of aromatics over noble metal-containing catalysts under relatively mild conditions. The noble metal is selected from Pt, Pd, Ir, Rh and polymetallics thereof. The catalyst system also contains a hydrogen sulfide sorbent material.
摘要翻译： 存在于石油和石油化学物流中的多种稠环杂环有机硫化合物的加氢脱硫（HDS）和在相对温和的条件下含贵金属的催化剂的芳族化合物的饱和过程。 贵金属选自Pt，Pd，Ir，Rh及其多金属。 催化剂体系还含有硫化氢吸附剂材料。
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公开(公告)号：US6103106A
公开(公告)日：2000-08-15
申请号：US326843
申请日：1999-06-07
申请人： Gary B. McVicker , James J. Schorfheide , William C. Baird Jr. , Michele S. Touvelle , Michel Daage , Darryl P. Klein , Edward S. Ellis , David E.W. Vaughan , Jingguang Chen , Sylvain S. Hantzer
发明人： Gary B. McVicker , James J. Schorfheide , William C. Baird Jr. , Michele S. Touvelle , Michel Daage , Darryl P. Klein , Edward S. Ellis , David E.W. Vaughan , Jingguang Chen , Sylvain S. Hantzer
CPC分类号： C10G67/06 , C10G45/10 , C10G65/04 , C10G65/043 , C10G65/08
摘要： A process for the hydrodesulfurization (HDS) of the multiple condensed ring heterocyclic organosulfur compounds and the ring opening of ring compounds present in petroleum and petrochemical streams. The process is conducted in the presence of hydrogen, one or more noble metal catalysts, and a hydrogen sulfide sorbent material.
摘要翻译： 多重稠环杂环有机硫化合物的加氢脱硫（HDS）和存在于石油和石油化工流中的环化合物的开环方法。 该方法在氢气，一种或多种贵金属催化剂和硫化氢吸附剂材料的存在下进行。
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公开(公告)号：US6007787A
公开(公告)日：1999-12-28
申请号：US702334
申请日：1996-08-23
CPC分类号： B01D3/16 , B01J8/0453 , B01J8/0492 , C10G49/002
摘要： A reaction vessel for processing liquid petroleum or chemical streams wherein the stream flows countercurrent to the flow of a treat gas, such as a hydrogen-containing gas, in at least one interaction zone. The reaction vessel contains vapor, and optionally liquid, passageways to bypass one or more packed beds, preferably catalyst beds. This permits more stable and efficient vessel operation.
摘要翻译： 一种用于处理液体石油或化学物流的反应容器，其中所述流在至少一个相互作用区域中与处理气体（例如含氢气体）的流动逆流流动。 反应容器含有蒸气和任选的液体，以绕过一个或多个填充床，优选催化剂床。 这允许更稳定和高效的船只操作。
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公开(公告)号：US5985131A
公开(公告)日：1999-11-16
申请号：US701925
申请日：1996-08-23
IPC分类号： B01J8/02 , B01J8/04 , B01J29/064 , C10G45/04 , C10G45/44 , C10G47/02 , C10G49/00 , C10G65/00 , C10G65/02 , C10G65/04 , C10G65/08 , C10G65/12 , C10G45/00 , C10G41/00
CPC分类号： B01J8/0278 , B01J29/064 , B01J8/0453 , B01J8/0492 , C10G49/002 , C10G65/02 , C10G65/12
摘要： A process for upgrading a liquid petroleum or chemical stream wherein said stream flows countercurrent to the flow of a treat gas, such as a hydrogen-containing gas, in at least one reaction zone. The reaction vessel used in the practice of the present invention contains vapor and optionally liquid passageway means to bypass one or more catalyst beds. This permits more stable and efficient reaction vessel operation.
摘要翻译： 一种用于升级液体石油或化学物流的方法，其中所述流与至少一个反应区中的处理气体（例如含氢气体）的流动逆流流动。 在本发明的实践中使用的反应容器包含蒸汽和任选的液体通道装置来绕过一个或多个催化剂床。 这允许更稳定和有效的反应容器操作。
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公开(公告)号：US08518244B2
公开(公告)日：2013-08-27
申请号：US11795547
申请日：2006-01-23
IPC分类号： C10G45/02
CPC分类号： C10G45/04
摘要： This invention relates to an improved hydrotreating process for removing sulfur from naphtha and distillate feedstreams. This improved process utilizes a hydrotreating zone, an acid gas removal zone, and a pressure swing adsorption zone having a total cycle time of less than about 30 seconds for increasing the concentration of hydrogen utilized in the process.
摘要翻译： 本发明涉及用于从石脑油和馏出物进料流中除去硫的改进的加氢处理方法。 该改进的方法利用加氢处理区，酸性气体去除区和总循环时间小于约30秒的变压吸附区，以增加在该方法中使用的氢的浓度。
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8.发明授权公开(公告)号：US06495029B1
公开(公告)日：2002-12-17
申请号：US09385644
申请日：1999-08-27
IPC分类号： C10G4500
CPC分类号： C10G25/003 , C10G45/10 , C10G65/04 , C10G67/06
摘要： A process for the hydrodesulfurization (HDS) of the multiple condensed ring heterocyclic organosulfur compounds present in petroleum and chemical streams. The stream is passed through at least one reaction zone countercurrent to the flow of a hydrogen-containing treat gas, and through at least one sorbent zone. The reaction zone contains a bed of Group VIII metal-containing hydrodesulfurization catalyst and the sorbent zone contains a bed of hydrogen sulfide sorbent material.
摘要翻译： 石油和化学物流中存在的多重稠环杂环有机硫化合物的加氢脱硫（HDS）的方法。 该物流通过与含氢处理气体的流动逆流的至少一个反应区，并通过至少一个吸附区。 反应区含有含Ⅷ族金属的加氢脱硫催化剂床，吸附剂区含有硫化氢吸附剂材料床。
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9.发明授权Combination cocurrent and countercurrent staged hydroprocessing with a vapor stage 失效组合并流和逆流分级加氢处理与蒸气阶段
公开(公告)号：US6153086A
公开(公告)日：2000-11-28
申请号：US73414
申请日：1998-05-06
CPC分类号： C10G65/12 , C10G65/00 , C10G69/04 , C10G69/06 , C10G2300/202 , C10G2300/207
摘要： A hydroprocessing process includes a cocurrent flow liquid reaction stage, a countercurrent flow liquid reaction stage and a vapor reaction stage in which feed components are catalytically hydroprocessed by reacting with hydrogen. Both liquid stages both produce a liquid and a vapor effluent, with the cocurrent stage liquid effluent the feed for the countercurrent stage and the countercurrent stage liquid effluent the hydroprocessed product liquid. Both liquid stage vapor effluents are combined and catalytically reacted with hydrogen in a vapor reaction stage, to form a hydroprocessed vapor. This vapor is cooled to condense and recover a portion of the hydroprocessed hydrocarbonaceous vapor components as additional product liquid. The uncondensed vapor is rich in hydrogen and is cleaned up if necessary, to remove contaminants, and then recycled back into the cocurrent stage as hydrogen-containing treat gas. Fresh hydrogen is introduced into the countercurrent stage and the countercurrent stage effluent contains sufficient, and preferably all of the hydrogen for the vapor stage reaction.
摘要翻译： 加氢处理方法包括并流流动液体反应阶段，逆流流动反应阶段和蒸气反应阶段，其中进料组分通过与氢反应进行催化加氢处理。 两个液相都产生液体和蒸汽流出物，并流阶段液体流出物是逆流阶段的进料和逆流阶段液体流出加氢产物液体。 两个液相蒸气流出物在蒸气反应阶段中与氢组合并催化反应，形成加氢处理的蒸汽。 将该蒸气冷却以冷凝并回收一部分加氢处理的含烃蒸汽组分作为另外的产物液体。 未冷凝的蒸汽富含氢气，如果需要，将其清除，以除去污染物，然后再循环回到并流阶段作为含氢处理气体。 将新鲜氢气引入逆流阶段，逆流阶段流出物含有足够的，优选全部用于蒸气阶段反应的氢气。
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10.发明授权
公开(公告)号：US5925239A
公开(公告)日：1999-07-20
申请号：US918639
申请日：1997-08-22
申请人： Darryl P. Klein , Michele S. Touvelle , Edward S. Ellis , Carl W. Hudson , Sylvain Hantzer , Jingguang G. Chen , David E. W. Vaughan , Michel Daage , James J. Schorfheide , William C. Baird, Jr. , Gary B. McVicker
发明人： Darryl P. Klein , Michele S. Touvelle , Edward S. Ellis , Carl W. Hudson , Sylvain Hantzer , Jingguang G. Chen , David E. W. Vaughan , Michel Daage , James J. Schorfheide , William C. Baird, Jr. , Gary B. McVicker
CPC分类号： C10G25/003 , C10G45/10
摘要： A process for the hydrodesulfurization (HDS) of multiple condensed ring heterocyclic organosulfur compounds present in petroleum and petrochemical streams and the saturation of aromatics over noble metal-containing catalysts under relatively mild conditions. The noble metal is selected from Pt, Pd, Ir, Rh and polymetallics thereof. The catalyst system also contains a hydrogen sulfide sorbent material.
摘要翻译： 存在于石油和石油化学物流中的多种稠环杂环有机硫化合物的加氢脱硫（HDS）和在相对温和的条件下含贵金属的催化剂的芳族化合物的饱和过程。 贵金属选自Pt，Pd，Ir，Rh及其多金属。 催化剂体系还含有硫化氢吸附剂材料。
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