公开(公告)号：US10017703B2

公开(公告)日：2018-07-10

申请号：US14313783

申请日：2014-06-24

申请人： Indian Oil Corporation Limited

发明人： Ganesh Vitthalrao Butley ,  Yamini Gupta ,  Mainak Sarkar ,  Arun Arangarasu ,  Madhusudan Sau ,  Brijesh Kumar ,  Santanam Rajagopal ,  Ravinder Kumar Malhotra

IPC分类号： C10G65/04

CPC分类号： C10G65/04 ,  C10G2300/202

摘要： A multi-stage hydrotreating process obtains ultra-low sulfur diesel boiling range hydrocarbon having less than 10 ppm sulfur with elimination of external hot high pressure separator and avoids the formation of recombinant mercaptans by removing excess hydrogen sulfide formed during hydroprocessing reaction. The process includes mixing a diesel boiling range hydrocarbon feedstock with hydrogen and sending to the first predominantly liquid phase hydroprocessing reaction stage. Effluent from the first hydroprocessing reaction stage is sent to first separator zone of open and empty space in the upper part of the second hydroprocessing reaction stage to flash off the dissolved reaction products hydrogen sulfide and ammonia. Liquid part of the effluent of first hydroprocessing reaction stage is passed to the second predominantly liquid phase hydroprocessing reaction stage. The process is repeated until the liquid product sulfur level of less than 10 ppm is attained and the liquid product is sent to further processing.

公开(公告)号：US11731094B2

公开(公告)日：2023-08-22

申请号：US17814929

申请日：2022-07-26

申请人： Indian Oil Corporation Limited

发明人： Yamini Gupta ,  Arun Arangarasu ,  Nepal Viswakarma ,  Ganesh Vitthalrao Butley ,  Sarvesh Kumar ,  Madhusudan Sau ,  Gurpreet Kapur Singh ,  Sankara Sri Venkata Ramakumar

IPC分类号： B01J8/00 ,  B01J8/02 ,  C10G45/22 ,  C10G45/72 ,  C10G47/10 ,  C10G65/12

CPC分类号： B01J8/0221 ,  C10G45/22 ,  C10G45/72 ,  C10G47/10 ,  C10G65/12 ,  B01J2208/00911 ,  C10G2300/1044 ,  C10G2300/1059 ,  C10G2300/1074 ,  C10G2300/202 ,  C10G2300/4006 ,  C10G2300/4012 ,  C10G2300/4018 ,  C10G2400/02 ,  C10G2400/04

摘要： The present invention provides a multistage single reactor system for hydroprocessing and a process of carrying out multistage hydroprocessing in the said reactor assembly consisting of, a fixed bed solid catalyst system, a feed injection system enabling axial flow of hydrogen saturated hydrocarbon feed, a hydrogen dispensing system inside the reactor enabling minimum required hydrogen flow in cross-flow pattern, also using multitudes of integrated separation and withdrawal limbs for continuous staging. The innovative reactor disclosed in the present invention enables continuous separation and withdrawal of gaseous products along the reactor length by means of combined horizontal reactor orientation and vertical separation limbs provided at the top of the horizontally oriented reactor. The advantage of the reactor assembly includes effective heat sink of exothermic reactions and lower severity of operation due to removal of inhibitory gaseous products.

公开(公告)号：US10655076B2

公开(公告)日：2020-05-19

申请号：US16294771

申请日：2019-03-06

申请人： INDIAN OIL CORPORATION LIMITED

发明人： Mainak Sarkar ,  Darshankumar Manubhai Dave ,  Ganesh Vitthalrao Butley ,  Ramesh Karumanchi ,  Arun Arangarasu ,  Sarvesh Kumar ,  Madhusudan Sau ,  Debasis Bhattacharyya ,  Sanjiv Kumar Mazumdar ,  Sankara Sri Venkata Ramakumar

IPC分类号： C10G65/04 ,  C10G67/02 ,  C10G65/16 ,  C10G65/00

摘要： The present invention relates to an assorted co-staging and counter stage hydro-treating process configuration scheme is disclosed for deep desulfurization and deep hydro-treating of diesel range hydrocarbons for obtaining diesel product having product sulfur less than 10 ppm and cetane number more than 51.

公开(公告)号：US10604708B2

公开(公告)日：2020-03-31

申请号：US15912212

申请日：2018-03-05

申请人： INDIAN OIL CORPORATION LIMITED

发明人： Ganesh Vitthalrao Butley ,  Yamini Gupta ,  Mainak Sarkar ,  Arun Arangarasu ,  Madhusudan Sau ,  Brijesh Kumar ,  Santanam Rajagopal ,  Ravinder Kumar Malhotra

IPC分类号： C10G65/04

摘要： A multi-stage hydrotreating process obtains ultra-low sulfur diesel boiling range hydrocarbon having less than 10 ppm sulfur with elimination of external hot high pressure separator and avoids the formation of recombinant mercaptans by removing excess hydrogen sulfide formed during hydroprocessing reaction. The process includes mixing a diesel boiling range hydrocarbon feedstock with hydrogen and sending to the first predominantly liquid phase hydroprocessing reaction stage. Effluent from the first hydroprocessing reaction stage is sent to first separator zone of open and empty space in the upper part of the second hydroprocessing reaction stage to flash off the dissolved reaction products hydrogen sulfide and ammonia. Liquid part of the effluent of first hydroprocessing reaction stage is passed to the second predominantly liquid phase hydroprocessing reaction stage. The process is repeated until the liquid product sulfur level of less than 10 ppm is attained and the liquid product is sent to further processing.