公开(公告)号：US10604708B2

公开(公告)日：2020-03-31

申请号：US15912212

申请日：2018-03-05

申请人： INDIAN OIL CORPORATION LIMITED

发明人： Ganesh Vitthalrao Butley ,  Yamini Gupta ,  Mainak Sarkar ,  Arun Arangarasu ,  Madhusudan Sau ,  Brijesh Kumar ,  Santanam Rajagopal ,  Ravinder Kumar Malhotra

IPC分类号： C10G65/04

摘要： A multi-stage hydrotreating process obtains ultra-low sulfur diesel boiling range hydrocarbon having less than 10 ppm sulfur with elimination of external hot high pressure separator and avoids the formation of recombinant mercaptans by removing excess hydrogen sulfide formed during hydroprocessing reaction. The process includes mixing a diesel boiling range hydrocarbon feedstock with hydrogen and sending to the first predominantly liquid phase hydroprocessing reaction stage. Effluent from the first hydroprocessing reaction stage is sent to first separator zone of open and empty space in the upper part of the second hydroprocessing reaction stage to flash off the dissolved reaction products hydrogen sulfide and ammonia. Liquid part of the effluent of first hydroprocessing reaction stage is passed to the second predominantly liquid phase hydroprocessing reaction stage. The process is repeated until the liquid product sulfur level of less than 10 ppm is attained and the liquid product is sent to further processing.

公开(公告)号：US10131589B2

公开(公告)日：2018-11-20

申请号：US14727307

申请日：2015-06-01

申请人： Indian Oil Corporation Limited

发明人： Saravanan Subramani ,  Reshmi Manna ,  Pushkar Varshney ,  Anju Chopra ,  Debasis Bhattacharyya ,  Brijesh Kumar ,  Biswapriya Das ,  Ravinder Kumar Malhotra

IPC分类号： C07C29/04 ,  C07C2/08 ,  C10L1/06 ,  C10L1/16 ,  C10L10/10 ,  C07C2/28 ,  C10G50/00 ,  C10L1/02 ,  B01J35/06 ,  B01J35/10

摘要： The present invention relates to a process for production of oligomer products from olefinic C4 feed stocks comprising isobutene, butenes, butanes, butadienes and mixture thereof. Particularly, the present invention relates to a process for the preparation of oligomers using olefinic C4 feed stock in presence of tertiary butyl alcohol (TBA) and iso propyl alcohol (IPA).

公开(公告)号：US09890229B2

公开(公告)日：2018-02-13

申请号：US14416611

申请日：2013-09-24

申请人： INDIAN OIL CORPORATION LIMITED

发明人： Gurmeet Singh ,  Bhasker Bantu ,  Sukhdeep Kaur ,  Naresh Kumar ,  Gurpreet Singh Kapur ,  Shashi Kant ,  Biswajit Basu ,  Ravinder Kumar Malhotra

IPC分类号： C08F110/06 ,  C07F3/02 ,  C07F7/00

CPC分类号： C08F110/06 ,  C07F3/02 ,  C07F7/003 ,  C08F4/6548 ,  C08F2500/12 ,  C08F4/6465 ,  C08F4/6545

摘要： The present invention provides a liquid organomagnesium precursor having formula {Mg(OR′)X}.a{MgX2}.b{Mg(OR′)2}.c{R′OH}, wherein R′ is selected from a hydrocarbon group, X is selected from a halide group, and a:b:c is in range of 0.1-99.8:0.1-99.8:0.1-99.8, and a process for preparing the same. The said process comprises contacting a magnesium source with an organohalide and alcohol in a solvent to form the liquid organomagnesium precursor. The present invention also provides a catalyst system using the organomagnesium precursor and its use thereof for polymerization of olefins. An illustrative example of the claimed process to make the organomagnesium precursor is: At 25° C., magnesium (powder or turnings) is added to organohalide, followed by alcohol in toluene. After heating to 90° C. and keeping there for 6 h the solution became viscous.

公开(公告)号：US09644050B2

公开(公告)日：2017-05-09

申请号：US14794148

申请日：2015-07-08

申请人： Indian Oil Corporation Limited

发明人： Sukhdeep Kaur ,  Bhasker Bantu ,  Gurmeet Singh ,  Naresh Kumar ,  Shashikant ,  Gurpreet Singh Kapur ,  Biswajit Basu ,  Ravinder Kumar Malhotra

IPC分类号： C08F110/06

CPC分类号： C08F110/06 ,  C08F4/6548 ,  C08F4/651 ,  C08F4/6465 ,  C08F2500/18 ,  C08F4/6545

摘要： The present invention describes a process for controlling particle size of a catalyst composition. The process comprising the steps of contacting an internal donor with an organomagnesium precursor solution to form an intermediate solution and treating the intermediate solution with a transition metal compound to form a catalyst composition, wherein particle size of the catalyst composition is controlled by controlling a contact time of the internal donor with the precursor solution during formation of the intermediate solution.

公开(公告)号：US20150158014A1

公开(公告)日：2015-06-11

申请号：US14415534

申请日：2013-08-17

申请人： Indian Oil Corporation Limited

发明人： Arumugam Velayutham Karthikeyani ,  Mohan Prabhu Kuvettu ,  Biswanath Sarkar ,  Gadari Saidulu ,  Shiba Prasad Choudhury ,  Sudhir Kumar Pande ,  Arvind Mahant ,  Brijesh Kumar ,  Santanam Rajagopal ,  Ravinder Kumar Malhotra ,  Velusamy Chidambaram

IPC分类号： B01J20/30 ,  B01J20/10 ,  B01J20/28 ,  B01J20/12

CPC分类号： B01J20/3064 ,  B01J20/10 ,  B01J20/103 ,  B01J20/12 ,  B01J20/28071 ,  B01J20/28078 ,  B01J20/28085 ,  B01J20/28092 ,  B01J20/3007 ,  B01J20/3085 ,  C10G11/18 ,  C10G25/03 ,  C10G55/06 ,  C10G2300/708

摘要： The present invention provides an adsorbent for removal of con-carbon and contaminant metals in feed, said adsorbent composition consisting of clay in the range of 30-70 wt. % and silica in the range of 70-30 wt. %, wherein the adsorbent has a pore volume in the range of 0.25-0.45 cc/gm; a pore size in the range of 20 to 2000 Å and a bi-modal pore size distribution characteristics, with a maximum of about 32% of the adsorbent having a pore size in the range of 20-200 Å and a minimum of about 68% of the adsorbent having a pore size in the range of 200-2000 Å. The present invention also provides a process for preparing the said adsorbent.

摘要翻译： 本发明提供一种用于去除进料中的碳和污染金属的吸附剂，所述吸附剂组合物由粘土组成，其范围为30-70wt。 ％和二氧化硅在70-30重量％的范围内。 ％，其中吸附剂的孔体积在0.25-0.45cc / gm范围内; 孔尺寸在20至2000埃范围内，并且具有双峰孔径分布特性，最大约32％的孔径在20-200埃范围内的吸附剂和最小约68％ 的孔径在200-2000范围内的吸附剂。 本发明还提供了制备所述吸附剂的方法。

公开(公告)号：US10960382B2

公开(公告)日：2021-03-30

申请号：US15035697

申请日：2014-01-06

申请人： Indian Oil Corporation Limited

发明人： Kuvettu Mohan Prabhu ,  Velusamy Chidambaram ,  Pankaj Kumar Kasliwal ,  Alex Cheru Pulikottil ,  Biswanath Sarkar ,  Brijesh Kumar ,  Santanam Rajagopal ,  Ravinder Kumar Malhotra

IPC分类号： B01J21/16 ,  B01J21/04 ,  B01J35/02 ,  B01J35/10 ,  B01J37/04 ,  B01J37/08 ,  C10G11/04 ,  C10G11/02 ,  B01J37/00 ,  B01J35/00 ,  B01J21/08 ,  B01J37/06

摘要： The present invention provides a catalyst product comprising of (a) porous acidic clay material and (b) binder and matrix to shape the catalyst to either microspheres, pellet, tablet, extrudate and ring and suitable for enhancing the crack-ability of heavy feed material derived from atmospheric and vacuum distillation bottoms; FCC bottoms, coker bottoms and hydrocracker bottoms. The invention particularly relates to a catalyst cum heat supply product suitable for thermal coking process either in a batch mode or continuous coking process.

公开(公告)号：US10100136B2

公开(公告)日：2018-10-16

申请号：US15371193

申请日：2016-12-06

申请人： INDIAN OIL CORPORATION LIMITED

发明人： Sukhdeep Kaur ,  Gurmeet Singh ,  Bhasker Bantu ,  Naresh Kumar ,  Gurpreet Singh Kapur ,  Shashi Kant ,  Biswajit Basu ,  Ravinder Kumar Malhotra

IPC分类号： C08F110/06 ,  C07F3/02 ,  C08F4/16 ,  C08F4/52

摘要： The present invention provides a solid organomagnesium precursor having formula {Mg(OR′)X}.a{MgX2}.b{Mg(OR′)2}.c{R′OH}, wherein R′ is selected from a hydrocarbon group, X is selected from a halide group, and a:b:c is in range of 0.01-0.5:0.01-0.5:0.01-5 and process for preparing the same, said process comprising contacting a magnesium source with a solvating agent, an organohalide and an alcohol to obtain the solid organomagnesium precursor. The present invention also provides a process for preparing a catalyst system using the organomagnesium precursor and its use thereof for polymerization of olefins.

公开(公告)号：US09944862B2

公开(公告)日：2018-04-17

申请号：US15036051

申请日：2014-01-06

申请人： INDIAN OIL CORPORATION LIMITED

发明人： Pankaj Kumar Kasliwal ,  Kuvettu Mohan Prabhu ,  Arumugam Velayutham Karthikeyani ,  Bandaru Venkata Hariprasadgupta ,  Balaiah Swamy ,  Biswanath Sarkar ,  Brijesh Kumar ,  Santanam Rajagopal ,  Ravinder Kumar Malhotra

IPC分类号： C10G9/32 ,  C10G9/00 ,  C10G9/26

CPC分类号： C10G9/005 ,  C10G9/26 ,  C10G9/32

摘要： The present invention provides a process and a system for coking and simultaneous upgrading of a heavy hydrocarbon feedstock. More particularly the present invention relates to a process of cracking heavy hydrocarbon feedstock employing high heat carrier, incorporated with weak acid sites for improving the liquid yield and reducing coke yield. The feedstock is vaporized and brought in contact with a heat carrier material to produce a product stream and separating the product stream from the particulate heat carrier, regeneration of the particulate heat carrier to the extent of 10-30% and collecting a gaseous and liquid product from the product stream.

公开(公告)号：US09593172B2

公开(公告)日：2017-03-14

申请号：US14414401

申请日：2013-07-12

申请人： INDIAN OIL CORPORATION LIMITED

发明人： Bhasker Bantu ,  Gurmeet Singh ,  Sukhdeep Kaur ,  Naresh Kumar ,  Gurpreet Singh Kapur ,  Shashi Kant ,  Ravinder Kumar Malhotra

IPC分类号： C08F4/649 ,  C08F10/00

CPC分类号： C08F4/6494 ,  C08F10/00 ,  C08F110/00 ,  C08F4/651

摘要： A catalyst composition for use as precursor for Ziegler-Natta catalyst system, said catalyst composition comprising a combination of magnesium moiety, titanium moiety and an internal donor containing at least one 1,2-phenylenedioate compound of structure (A). Also, the present invention provides a process for preparing the aforesaid catalyst composition. Further, the present invention provides a Ziegler-Natta catalyst system incorporating the aforesaid catalyst composition and a method for polymerizing and/or copolymerizing olefins using the Ziegler-Natta catalyst system.

摘要翻译： 一种用作齐格勒 - 纳塔催化剂体系的前体的催化剂组合物，所述催化剂组合物包含镁部分，钛部分和含有至少一种结构（A）的1,2-亚苯基二酸酯化合物的内给体的组合。 另外，本发明提供了制备上述催化剂组合物的方法。 此外，本发明提供了使用齐格勒 - 纳塔催化剂体系结合上述催化剂组合物的齐格勒 - 纳塔催化剂体系和使烯烃聚合和/或共聚的方法。

公开(公告)号：US10137438B2

公开(公告)日：2018-11-27

申请号：US14766287

申请日：2014-02-08

申请人： INDIAN OIL CORPORATION LIMITED

发明人： Mohan Prabhu Kuvettu ,  Kanthasamy Ramasubramanian ,  Alex Cheru Pulikottil ,  Kochappilly Ouseph Xavier ,  Mani Karthikeyan ,  Vinay Kumar Chaudhury ,  Brijesh Kumar ,  Santanam Rajagopal ,  Ravinder Kumar Malhotra

IPC分类号： B01J29/06 ,  B01J29/16 ,  B01J29/072 ,  B01J29/04 ,  B01J29/74 ,  B01J29/12 ,  B01J29/068 ,  B01J37/06 ,  B01J21/16 ,  B01J23/88 ,  B01J23/883 ,  B01J23/888 ,  B01J29/08 ,  B01J29/14 ,  B01J35/10 ,  B01J37/02 ,  B01J29/076 ,  B01J29/80

摘要： The present invention relates to a catalyst precursor composition comprising a first component having active sites, said first component being at least one of the surface modified clay and/or pore modified zeolite; and a second component being metal species comprising of at least one metal selected from Group VI B and at least one metal selected from VIII B and the second component is in intimate contact with the active sites of the first component. The present invention also provides a process for preparing the catalyst precursor composition. The present invention also relates to a catalyst composition and process of preparation thereof by using the catalyst precursor. More particularly, the present invention provides a catalyst composition suitable for converting hydrocarbon feeds to diesel range product.