公开(公告)号：US5547654A

公开(公告)日：1996-08-20

申请号：US301038

申请日：1994-09-06

申请人： Isao Machida ,  Ryuji Fujiura ,  Takashi Kojima ,  Hitoshi Sakamoto

发明人： Isao Machida ,  Ryuji Fujiura ,  Takashi Kojima ,  Hitoshi Sakamoto

IPC分类号： C04B35/528 ,  C04B35/83 ,  C01B31/02

CPC分类号： C04B35/528 ,  C04B35/83

摘要： Self-adhesive carbonaceous grains for use in the production of high density carbon artifacts and high performance carbon-carbon composites are made by processes such as oxidation and heat treatment of specific mesophase pitches. The present carbonaceous grains exhibit excellent binding properties, shape stability when molded, and high density with higher carbonization yield, providing very high strength artifacts when their properties fall within the specific range of properties defined by their H/C and O/C values. High density carbon artifacts can be easily obtained by molding the grains and carbonizing or graphitizing the same.

摘要翻译： 用于生产高密度碳伪影和高性能碳 - 碳复合材料的自粘碳质颗粒通过诸如特定中间相沥青的氧化和热处理的方法制备。 本发明的碳质颗粒表现出优异的粘合性能，当模塑时的形状稳定性，以及高密度和较高的碳化收率，当它们的性能落在由其H / C和O / C值定义的特定特性范围内时，提供非常高的强度伪影。 高密度碳伪影可以通过模制成型并使其碳化或石墨化而容易地获得。

公开(公告)号：US5609800A

公开(公告)日：1997-03-11

申请号：US529439

申请日：1995-09-18

申请人： Isao Mochida ,  Ryuji Fujiura ,  Takashi Kojima ,  Hitoshi Sakamoto

发明人： Isao Mochida ,  Ryuji Fujiura ,  Takashi Kojima ,  Hitoshi Sakamoto

IPC分类号： C04B35/528 ,  C10C3/00 ,  C01B31/02

CPC分类号： C04B35/528 ,  C10C3/00

摘要： Self-adhesive carbonaceous grains for use in the manufacture of high-density and high-strength carbon artifacts containing 0.5-1.5 wt % of a quinoline-soluble but pyridine-insoluble component and at least 97 wt % of a quinoline-insoluble component and which are prepared by heat-treating in a nonoxidizing atmosphere a mesophase pitch that is obtained by polymerizing condensed polycyclic hydrocarbons or substances containing them in the presence of a superacid consisting of hydrogen fluoride and boron trifluoride. The carbonaceous grains are molded and the mold is baked at a sufficient temperature to achieve its carbonization, with the heating rate being not more than 20.degree. C./h in the temperature range from 400 .degree. to 600.degree. C. In this way, high-density and high-strength carbon artifacts showing a homogeneous fine mosaic texture of optical anisotropy can be efficiently manufactured in high carbon yield.

摘要翻译： 用于制造含有0.5-1.5重量％喹啉可溶但不溶于吡啶的组分和至少97重量％喹啉不溶组分的高密度和高强度碳伪影的自粘碳质颗粒，其中 通过在非氧化性气氛中通过在由氟化氢和三氟化硼组成的超强酸的存在下聚合冷凝的多环烃或含有它们的物质而获得的中间相沥青来制备。 碳质颗粒被模制，模具在足够的温度下烘烤以实现其碳化，加热速率在400℃至600℃的温度范围内不超过20℃/小时。这样高 可以高产率地有效地制造显示光学各向异性的均匀的细微马赛克纹理的密度和高强度碳伪影。

公开(公告)号：US5484520A

公开(公告)日：1996-01-16

申请号：US350679

申请日：1994-12-07

申请人： Isao Mochida ,  Ryuji Fujiura ,  Takashi Kojima ,  Hitoshi Sakamoto

发明人： Isao Mochida ,  Ryuji Fujiura ,  Takashi Kojima ,  Hitoshi Sakamoto

IPC分类号： C04B35/528 ,  C10C3/00 ,  C10G73/36

CPC分类号： C04B35/528 ,  C10C3/00

摘要： Self-adhesive carbonaceous grains for use in the manufacture of high-density and high-strength carbon artifacts containing 0.5-1.5 wt % of a quinoline-soluble but pyridine-insoluble component and at least 97 wt % of a quinoline-insoluble component and which are prepared by heat-treating in a nonoxidizing atmosphere a mesophase pitch that is obtained by polymerizing condensed polycyclic hydrocarbons or substances containing them in the presence of a superacid consisting of hydrogen fluoride and boron trifluoride. The carbonaceous grains are molded and the mold is baked at a sufficient temperature to achieve its carbonization, with the heating rate being not more than 20.degree. C./h in the temperature range from 400.degree. to 600.degree. C. In this way, high-density and high-strength carbon artifacts showing a homogeneous fine mosaic texture of optical anisotropy can be efficiently manufactured in high carbon yield.

摘要翻译： 用于制造含有0.5-1.5重量％喹啉可溶但不溶于吡啶的组分和至少97重量％喹啉不溶组分的高密度和高强度碳伪影的自粘碳质颗粒，其中 通过在非氧化性气氛中通过在由氟化氢和三氟化硼组成的超强酸的存在下聚合冷凝的多环烃或含有它们的物质而获得的中间相沥青来制备。 碳质颗粒被模制，模具在足够的温度下烘烤以实现其碳化，加热速率在400℃至600℃的温度范围内不超过20℃/小时。这样高 可以高产率地有效地制造显示光学各向异性的均匀的细微马赛克纹理的密度和高强度碳伪影。

公开(公告)号：US5106462A

公开(公告)日：1992-04-21

申请号：US432811

申请日：1989-11-07

申请人： Takamasa Kawakami ,  Rieko Nakano ,  Kazuhiro Ando ,  Ryuji Fujiura

发明人： Takamasa Kawakami ,  Rieko Nakano ,  Kazuhiro Ando ,  Ryuji Fujiura

IPC分类号： C23C18/08 ,  C25D5/56 ,  H05K3/10

CPC分类号： C23C18/08 ,  C25D5/56 ,  H05K3/105 ,  Y10S205/927

摘要： Process for producing a copper plated resin article by forming a uniform copper coating having excellent adhesive strength on a fiber-reinforced or unreinforced thermoplastic or thermosetting resin article having a heat deformation temperature higher than 165.degree. C. The resin article is heated along with a source of copper formate under a reduced pressure or in a non-oxidative atmosphere to a temperature in the range above 165.degree. C. but lower than the heat deformation temperature of the resin article. The process makes it possible to produce a resin article having formed thereon a copper layer having an excellent adhesive strength by a very simple manner, and the resin article thus obtained can be used in various industrial fields.

公开(公告)号：US5093510A

公开(公告)日：1992-03-03

申请号：US622681

申请日：1990-12-05

申请人： Takamasa Kawakami ,  Ryuji Fujiura ,  Kazuhiro Ando ,  Rieko Nakano

发明人： Takamasa Kawakami ,  Ryuji Fujiura ,  Kazuhiro Ando ,  Rieko Nakano

IPC分类号： C07C51/09 ,  C07C51/41 ,  C07C53/06

CPC分类号： C07C51/412

摘要： A process for producing copper formate, which comprises subjecting methyl formate to a liquid-phase hydrolysis reaction at a temperature from 60 to 85.degree. C. in the presence of copper carbonate.

公开(公告)号：US06689336B2

公开(公告)日：2004-02-10

申请号：US10052737

申请日：2002-01-23

申请人： Koichi Kanno ,  Hirotaka Tsuruya ,  Ryuji Fujiura ,  Takeshi Koshikawa ,  Fumitaka Watanabe

发明人： Koichi Kanno ,  Hirotaka Tsuruya ,  Ryuji Fujiura ,  Takeshi Koshikawa ,  Fumitaka Watanabe

IPC分类号： C01B3102

CPC分类号： C04B38/0022 ,  C04B35/524 ,  C04B38/0058 ,  C04B38/0067 ,  C04B38/0074 ,  C04B35/52 ,  C04B35/522

摘要： A carbon foam obtained by heat-treating a mesophase pitch whose softening point is 300° C. or less according to an elevated flow tester, whose ratio (Daromatic/Daliphatic) of the absorption intensity of an aromatic C—H stretching vibration, measured with FT-IR, to the absorption intensity of an aliphatic C—H stretching vibration, measured with FT-IR, is 4.0 or less and whose optically anisotropic content is at least 80%, a graphite foam obtained by heat-treating the carbon foam recited above at a temperature of 2,000° C. or higher and production processes of these.

摘要翻译： 根据升高的流动测试仪，通过用FT-测量仪测量芳族CH伸缩振动的吸收强度的比率（Daromatic / Daliphatic），将软化点为300℃以下的中间相沥青热处理得到的碳泡沫， IR与通过FT-IR测定的脂肪族CH伸缩振动的吸收强度为4.0以下，光学各向异性含量为80％以上的石墨泡沫体，以上述碳热发泡体的温度 为2000℃以上，这些的制造方法。

公开(公告)号：US5205888A

公开(公告)日：1993-04-27

申请号：US724892

申请日：1991-07-02

申请人： Isao Mochida ,  Ryuji Fujiura

发明人： Isao Mochida ,  Ryuji Fujiura

IPC分类号： C04B35/83

CPC分类号： C04B35/83

摘要： A process for making carbon fiber reinforced materials which not only have desirable qualities which include high strength, high heat resistance, chemical resistance, wear resistance and lightweightness but also which are produced in a short time and at low cost. The process includes the steps of impregnating a carbon fiber assembly with a melt of mesophase pitch or mixing short carbon fibers with the mesophase pitch, shaping the pitch-impregnated assembly or the pitch/short carbon fiber mixture, and firing the same. The process requires that the mesophase pitch used in the process be almost 100% of an optical anistropic phase as examined under a polarizing microscope; have a softening point of no higher than 350.degree. C. and be capable of being carbonized in a yield of at least 70% when gradually heated to a temperature of about 600.degree. C. in an inert gas atmosphere and then held at that temperature for two hours.

摘要翻译： 一种制造碳纤维增强材料的方法，其不仅具有包括高强度，高耐热性，耐化学性，耐磨性和轻质性，而且在短时间和低成本下生产的所需质量。 该方法包括以下步骤：用中间相沥青的熔体浸渍碳纤维组合物或将短碳纤维与中间相沥青混合，对沥青浸渍的组合物或沥青/短碳纤维混合物进行成型，并对其进行烧制。 该方法要求在该过程中使用的中间相沥青几乎是在偏光显微镜下检查的光学相位相的100％; 软化点不高于350℃，并且在惰性气体气氛中逐渐加热至约600℃的温度时能够以至少70％的产率碳化，然后在该温度下保持 两个小时

公开(公告)号：US07008526B2

公开(公告)日：2006-03-07

申请号：US09923373

申请日：2001-08-08

申请人： Koichi Kanno ,  Hirotaka Tsuruya ,  Ryuji Fujiura

发明人： Koichi Kanno ,  Hirotaka Tsuruya ,  Ryuji Fujiura

IPC分类号： C10C1/16 ,  C10C1/19 ,  C10C3/04 ,  C10C3/14

CPC分类号： C10B55/00 ,  C01B32/05 ,  C01B32/20 ,  C01P2002/60 ,  C01P2002/72 ,  C01P2004/61 ,  H01M4/587

摘要： When a pitch composition prepared by mixing 100 parts by weight of mesophase pitch with 10 to 1,000 parts by weight of coal tar pitch, is heat-treated at a temperature of 500° C. or higher, it is possible to produce a high-density coke at a high yield while avoiding the foaming of the mesophase pitch. In addition, when the coke is graphitized at a temperature of 2,000° C. or higher, it is possible to obtain an artificial graphite having a high graphitization degree. Further, when the coke is first pulverized and then graphitized at a temperature of 2,000° C. or higher, it is possible to obtain a high-crystallinity graphite powder which can be suitably used as a carbon material for a negative electrode of non-aqueous solvent type secondary battery having a high discharge capacity and a high charge-discharge efficiency.