公开(公告)号：US07138445B2

公开(公告)日：2006-11-21

申请号：US10731757

申请日：2003-12-08

申请人： Jae Ho Yang ,  Sang Hyun Hong ,  Gyu Chul Lee ,  Bok Nam Jang ,  Young Gil Jang ,  Sung Hee Ahn ,  Su Hak Bae ,  Jong-Cheol Lim ,  Kyung-Hoon Seo ,  Sam-Joo Yang

发明人： Jae Ho Yang ,  Sang Hyun Hong ,  Gyu Chul Lee ,  Bok Nam Jang ,  Young Gil Jang ,  Sung Hee Ahn ,  Su Hak Bae ,  Jong-Cheol Lim ,  Kyung-Hoon Seo ,  Sam-Joo Yang

IPC分类号： C08K5/5399 ,  C08L25/00 ,  C08L69/00 ,  C08L71/12

CPC分类号： C08L77/00 ,  C07F9/6533 ,  C08F279/02 ,  C08F279/04 ,  C08K5/06 ,  C08K5/1515 ,  C08K5/49 ,  C08K5/523 ,  C08K5/5399 ,  C08L25/12 ,  C08L27/18 ,  C08L33/06 ,  C08L51/04 ,  C08L53/00 ,  C08L55/02 ,  C08L61/06 ,  C08L61/14 ,  C08L67/02 ,  C08L69/00 ,  C08L71/12 ,  C08L71/123 ,  C08L77/02 ,  C08L77/06 ,  C08L2666/02 ,  C08L2666/14 ,  C08L2666/24 ,  C08L2666/04 ,  C08L2666/16 ,  C08L61/04 ,  C08L71/00

摘要： The present invention relates to a flame retardant thermoplastic resin composition that contains a phenol resin derivative having good char formability, regardless of the base resin. A flame retardant thermoplastic resin composition according to the present invention comprises (A) 100 parts by weight of a thermoplastic resin as a base resin, (B) about 0.1˜100 parts by weight of a phenol resin derivative, and (C) about 0.1˜50 parts by weight of a phosphoric acid ester morpholide compound or a mixture of phosphoric acid ester morpholide compounds. Another flame retardant thermoplastic resin composition according to the present invention comprises (A) 100 parts by weight of a thermoplastic resin as a base resin, (B) about 0.1˜100 parts by weight of polyphenylene ether, (C) about 0.1˜100 parts by weight of a phenol resin derivative, and (D) about 0.1˜50 parts by weight of a phosphoric acid ester morpholide compound or a mixture of phosphoric acid ester morpholide compounds. The thermoplastic resin composition containing polyphenylene ether resin may also contain up to 5.0 parts by weight of an anti-dripping agent based on 100 parts by weight of the base resin.

摘要翻译： 本发明涉及一种阻燃热塑性树脂组合物，其含有具有良好的成型性的酚醛树脂衍生物，而与基础树脂无关。 根据本发明的阻燃热塑性树脂组合物包含（A）100重量份作为基础树脂的热塑性树脂，（B）约0.1〜100重量份的酚醛树脂衍生物，和（C）约0.1 约50重量份的磷酸酯吗啉化合物或磷酸酯吗啉化合物的混合物。 根据本发明的另一种阻燃热塑性树脂组合物包含（A）100重量份作为基础树脂的热塑性树脂，（B）约0.1〜100重量份的聚苯醚，（C）约0.1〜100重量份 的酚醛树脂衍生物，和（D）约0.1〜50重量份的磷酸酯吗啉化合物或磷酸酯吗啉化合物的混合物。 含有聚苯醚树脂的热塑性树脂组合物还可以含有最多5.0重量份的基于100重量份的基础树脂的防滴剂。

公开(公告)号：US07691924B2

公开(公告)日：2010-04-06

申请号：US11507030

申请日：2006-08-21

申请人： Jong-Cheol Lim ,  Sang Hyun Hong ,  Kyung-Hoon Seo ,  Sam-Joo Yang

发明人： Jong-Cheol Lim ,  Sang Hyun Hong ,  Kyung-Hoon Seo ,  Sam-Joo Yang

IPC分类号： C08K5/357 ,  C08K5/5399 ,  C08K5/521

CPC分类号： C08F279/02 ,  C08F279/04 ,  C08K5/5399 ,  C08L21/00 ,  C08L25/00 ,  C08L27/12 ,  C08L33/00 ,  C08L35/06 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  C08L2666/04 ,  C08L2666/02 ,  C08L2666/14

摘要： The present invention relates to a flame retardant polycarbonate thermoplastic resin composition that comprises a polycarbonate resin, a rubber modified vinyl-grafted copolymer, a phosphorous mixture of a cyclic phosphazene oligomer compound and a phosphate ester morpholide compound or a phosphoric acid ester as a flame retardant, and, optionally, a fluorinated polyolefin resin, which has good flame retardancy, heat resistance, mechanical strength, impact strength, heat stability, processability, and appearance.

摘要翻译： 本发明涉及一种阻燃聚碳酸酯热塑性树脂组合物，其包含聚碳酸酯树脂，橡胶改性的乙烯基接枝共聚物，环状磷腈低聚物化合物和磷酸酯吗啉化合物的磷混合物或磷酸酯作为阻燃剂 和可选地具有良好的阻燃性，耐热性，机械强度，冲击强度，热稳定性，加工性和外观的氟化聚烯烃树脂。

公开(公告)号：US06900256B2

公开(公告)日：2005-05-31

申请号：US10223450

申请日：2002-08-19

申请人： Jong-Cheol Lim ,  Kyung-Hoon Seo ,  Sam-Joo Yang

发明人： Jong-Cheol Lim ,  Kyung-Hoon Seo ,  Sam-Joo Yang

IPC分类号： C08J5/00 ,  C07F9/6533 ,  C08F279/02 ,  C08F279/04 ,  C08K5/521 ,  C08K5/523 ,  C08K5/5399 ,  C08L25/00 ,  C08L25/12 ,  C08L27/12 ,  C08L27/18 ,  C08L33/04 ,  C08L33/06 ,  C08L51/00 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  C08L71/12

CPC分类号： C08K5/5399 ,  C07F9/6533 ,  C08F279/02 ,  C08F279/04 ,  C08K5/523 ,  C08L25/12 ,  C08L27/18 ,  C08L33/06 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/14

摘要： The present invention relates to polyphosphate ester morpholides, compositions comprising mixtures thereof and thermoplastic resin compositions containing the polyphosphate ester morpholide composition as a flame retardant. The flame retardant compositions comprise mixtures of polyphosphate ester morpholides which are represented by the following general formula I: in which X is 1 or 2; R1 is a C6-C20 aryl group, an alkyl substituted C6-C20 aryl group or a derivative thereof; R2 is a C6-C30 arylene group, an alkyl substituted C6-C30 arylene group or a derivative thereof; n is the average number of morpholide repeating units, m is the average number of R1 repeating units, and n+m is 1 to 5. In accordance with the present invention, it is possible to provide a flame retardant thermoplastic resin compositions having improved flame retardancy even when small amounts of the flame retardant are used. The thermoplastic compositions according to the present invention also have a desirable balance of properties such as workability, impact strength, heat resistance, appearance and the like.

摘要翻译： 本发明涉及多磷酸酯吗啉，包含其混合物的组合物和含有聚磷酸酯吗啉化合物作为阻燃剂的热塑性树脂组合物。 阻燃剂组合物包含由以下通式I表示的聚磷酸酯吗啉的混合物：其中X为1或2; R 1是C 6 -C 20芳基，烷基取代的C 6 -C 20芳基， 20芳基或其衍生物; R 2是C 6 -C 30亚芳基，烷基取代的C 6 -C 30亚烷基， 亚芳基或其衍生物; n是平均的吗啉重复单元数，m是R 1重复单元的平均数，n + m是1〜5。根据本发明，可以提供一种 阻燃热塑性树脂组合物即使使用少量的阻燃剂也具有改善的阻燃性。 根据本发明的热塑性组合物还具有所需的性能平衡，例如可加工性，冲击强度，耐热性，外观等。

公开(公告)号：US06437029B1

公开(公告)日：2002-08-20

申请号：US09752814

申请日：2000-12-29

申请人： Jong-Cheol Lim ,  Kyung-Hoon Seo ,  Sam-Joo Yang

发明人： Jong-Cheol Lim ,  Kyung-Hoon Seo ,  Sam-Joo Yang

IPC分类号： C08L6900

CPC分类号： C08K5/5399 ,  C07F9/6533 ,  C08F279/02 ,  C08F279/04 ,  C08K5/523 ,  C08L25/12 ,  C08L27/18 ,  C08L33/06 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/14

摘要： The present invention relates to a flame retardant thermoplastic resin composition that comprises a polycarbonate resin, a rubber modified styrene-grafted copolymer, a styrene-containing copolymer, a (meth)acrylic acid ester copolymer, a phosphoric acid ester as a flame retardant and a fluorinated polyolefin resin, which does not show coalescence of the domain resin that might be caused by the low viscosity at a high temperature, and poor flame retardancy, weld-line strength and mechanical properties such as impact strength, and which has a good balance of physical properties such as impact strength, heat resistance, heat stability, processability and appearance.

公开(公告)号：US06576161B2

公开(公告)日：2003-06-10

申请号：US09997781

申请日：2001-11-28

申请人： Jong-Cheol Lim ,  Kyung-Hoon Seo ,  Sam-Joo Yang

发明人： Jong-Cheol Lim ,  Kyung-Hoon Seo ,  Sam-Joo Yang

IPC分类号： C08K551

CPC分类号： C08K5/5399 ,  C07F9/6533 ,  C08F279/02 ,  C08F279/04 ,  C08K5/523 ,  C08L25/12 ,  C08L27/18 ,  C08L33/06 ,  C08L51/04 ,  C08L55/02 ,  C08L69/00 ,  C08L2666/02 ,  C08L2666/04 ,  C08L2666/14

摘要： The present invention relates to polyphosphate ester morpholides, compositions comprising mixtures thereof and thermoplastic resin compositions containing the polyphosphate ester morpholide composition as a flame retardant. The flame retardant compositions comprise mixtures of polyphosphate ester morpholides which are represented by the following general formula I: in which X is 1 or 2; R1 is a C6-C20 aryl group, an alkyl substituted C6-C20 aryl group or a derivative thereof; R2 is a C6-C30 arylene group, an alkyl substituted C6-C30 arylene group or a derivative thereof; n is the average number of morpholide repeating units, m is the average number of R1 repeating units, and n+m is 1 to 5. In accordance with the present invention, it is possible to provide a flame retardant thermoplastic resin compositions having improved flame retardancy even when small amounts of the flame retardant are used. The thermoplastic compositions according to the present invention also have a desirable balance of properties such as workability, impact strength, heat resistance, appearance and the like.

摘要翻译： 本发明涉及多磷酸酯吗啉，包含其混合物的组合物和含有聚磷酸酯吗啉化合物作为阻燃剂的热塑性树脂组合物。 阻燃剂组合物包含由以下通式I表示的聚磷酸酯吗啉的混合物：其中X为1或2; R1是C6-C20芳基，烷基取代的C6-C20芳基或其衍生物; R2是C6-C30亚芳基，烷基取代的C6-C30亚芳基或其衍生物; n是平均的吗啉重复单元数，m是R1重复单元的平均数，n + m是1〜5。根据本发明，可以提供具有改进的火焰的阻燃性热塑性树脂组合物 即使使用少量的阻燃剂也是阻燃性的。 根据本发明的热塑性组合物还具有所需的性能平衡，例如可加工性，冲击强度，耐热性，外观等。