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1.发明授权
公开(公告)号：US5710328A
公开(公告)日：1998-01-20
申请号：US562860
申请日：1995-11-27
IPC分类号： B01J27/198 , C07C51/083 , C07C51/567 , C07C51/00
CPC分类号： B01J23/002 , B01J27/198 , C07C51/083 , C07C51/567 , B01J2523/00
摘要： Disclosed is a process for the preparation of .alpha.,.beta.-unsaturated carboxylic acids and anhydrides thereof which comprises contacting formaldehyde or a source of formaldehyde with a carboxylic anhydride in the presence of a catalyst comprising mixed oxides of vanadium, phosphorus and, optionally, a third component selected from titanium, aluminum or, preferably silicon.
摘要翻译： 公开了一种制备α，β-不饱和羧酸及其酸酐的方法，其包括使甲醛或甲醛源与羧酸酐在催化剂存在下接触，所述催化剂包含钒，磷和任选的第三 组分选自钛，铝或优选硅。
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2.发明授权
公开(公告)号：US5998657A
公开(公告)日：1999-12-07
申请号：US60468
申请日：1998-04-15
IPC分类号： C07C67/08 , C07B61/00 , C07C51/353 , C07C57/04 , C07C67/343 , C07C69/54 , C07C69/52 , C07B35/00
CPC分类号： C07C51/353 , C07C67/343
摘要： A process using a niobium catalyst includes the step of reacting an ester or carboxylic acid with oxygen and an alcohol in the presence a niobium catalyst to respectively produce an .alpha.,.beta.-unsaturated ester or carboxylic acid. Methanol may be used as the alcohol, and the ester or carboxylic acid may be passed over the niobium catalyst in a vapor stream containing oxygen and methanol. Alternatively, the process using a niobium catalyst may involve the step of reacting an ester and oxygen in the presence the niobium catalyst to produce an .alpha.,.beta.-unsaturated carboxylic acid. In this case the ester may be a methyl ester. In either case, niobium oxide may be used as the niobium catalyst with the niobium oxide being present on a support. The support may be an oxide selected from the group consisting of silicon oxide, aluminum oxide, titanium oxide and mixtures thereof. The catalyst may be formed by reacting niobium fluoride with the oxide serving as the support. The niobium catalyst may contain elemental niobium within the range of 1 wt % to 70 wt %, and more preferably within the range of 10 wt % to 30 wt %. The process may be operated at a temperature from 150 to 450.degree. C. and preferably from 250 to 350.degree. C. The process may be operated at a pressure from 0.1 to 15 atm. absolute and preferably from 0.5-5 atm. absolute. The flow rate of reactants may be from 10 to 10,000 L/kg.sub.(cat) /h, and preferably from 100 to 1,000 L/kg.sub.(cat) /h.
摘要翻译： 使用铌催化剂的方法包括在铌催化剂存在下使酯或羧酸与氧和醇反应以分别产生α，β-不饱和酯或羧酸的步骤。 可以使用甲醇作为醇，并且酯或羧酸可以在含有氧和甲醇的蒸气流中通过铌催化剂。 或者，使用铌催化剂的方法可以包括在存在铌催化剂的情况下使酯和氧反应以产生α，β-不饱和羧酸的步骤。 在这种情况下，酯可以是甲酯。 在任一情况下，可以使用铌氧化物作为铌催化剂，其中铌氧化物存在于载体上。 载体可以是选自氧化硅，氧化铝，氧化钛及其混合物的氧化物。 催化剂可以通过使氟化铌与作为载体的氧化物反应而形成。 铌催化剂可以含有1重量％〜70重量％的范围内的元素铌，更优选在10重量％〜30重量％的范围内。 该方法可以在150至450℃，优选250至350℃的温度下操作。该方法可以在0.1至15atm的压力下操作。 绝对的，优选为0.5-5atm。 绝对。 反应物的流速可以为10〜10000L / kg（cat）/ h，优选为100〜1000L / kg（cat）/ h。
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3.发明授权Vapor phase carbonylation process using group 4 metal promoted iridium catalyst 有权气相羰基化工艺使用第4族金属促进铱催化剂公开(公告)号：US06355837B1
公开(公告)日：2002-03-12
申请号：US09383124
申请日：1999-08-25
IPC分类号： C07C5112
摘要： A method for producing esters and carboxylic acids from lower alkyl alcohols, ethers, esters and ester-alcohol reactant mixtures and includes the step of contacting a vaporous mixture of the reactants, carbon monoxide and a halide with a supported catalyst under vapor-phase carbonylation conditions. The catalyst includes iridium and a second metal selected from group 4 (titanium, zirconium, hafnium) metals of the periodic table of elements. Desirably, the iridium and secondary metal are deposited on activated carbon as a support material. In a preferred aspect of the invention, the vapor phase carbonylation process is useful for preparing acetic acid, methyl acetate or a mixture thereof.
摘要翻译： 一种从低级烷基醇，醚，酯和酯 - 醇反应物混合物生产酯和羧酸的方法，包括在气相羰基化条件下使反应物，一氧化碳和卤化物的气态混合物与负载催化剂接触的步骤 。 催化剂包括铱和选自元素周期表第4族（钛，锆，铪）金属的第二种金属。 理想地，铱和二次金属作为载体材料沉积在活性炭上。 在本发明的优选方面，气相羰基化方法可用于制备乙酸，乙酸甲酯或其混合物。
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4.发明授权公开(公告)号：US06903045B2
公开(公告)日：2005-06-07
申请号：US09884775
申请日：2001-06-19
IPC分类号： B01J31/30 , B01J21/18 , B01J23/62 , B01J37/02 , B01J37/04 , C07C51/12 , C07C67/36 , B01J31/08 , B01J23/02 , B01J27/13 , B01J27/135
CPC分类号： C07C51/12 , B01J21/18 , B01J23/626 , B01J37/0205 , C07C67/36 , C07C53/08 , C07C69/14
摘要： A carbonylation catalyst useful for producing esters and carboxylic acids in a vapor phase carbonylation process, wherein the catalyst includes a solid component having a catalytically effective amount of platinum and tin associated with a solid catalyst support material and a vaporous halide promoter component.
摘要翻译： 一种用于在气相羰基化方法中生产酯和羧酸的羰基化催化剂，其中所述催化剂包括具有催化有效量的与固体催化剂载体材料和气态卤化物助催化剂组分相关的铂和锡的固体组分。
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5.发明授权
公开(公告)号：US6137000A
公开(公告)日：2000-10-24
申请号：US250666
申请日：1999-02-16
IPC分类号： B01J23/63 , C07B61/00 , C07C27/00 , C07C51/12 , C07C53/08 , C07C67/08 , C07C67/36 , C07C69/14 , C07C51/10
摘要： A vapor phase process for the carbonylation of lower alkyl alcohols to esters and optionally, carboxylic acids using a catalyst containing iridium and at least one second metal selected from the Lanthanide Series. Desirably, the iridium and secondary metal are deposited on activated carbon as a support material. In a preferred aspect of the invention, the vapor phase process is useful for preparing acetic acid, methyl acetate or a mixture thereof by contacting the catalyst with a vapor comprising methanol, a halide and carbon monoxide under carbonylation process conditions.
摘要翻译： 使用含有铱和至少一种选自镧系元素的第二金属的催化剂将低级烷基醇羰基化成酯和任选的羧酸的气相方法。 理想地，铱和二次金属作为载体材料沉积在活性炭上。 在本发明的优选方面，气相法可用于通过在羰基化工艺条件下使催化剂与包含甲醇，卤化物和一氧化碳的蒸气接触来制备乙酸，乙酸甲酯或其混合物。
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公开(公告)号：US5900505A
公开(公告)日：1999-05-04
申请号：US010776
申请日：1998-01-22
申请人： Gerald Charles Tustin , Joseph Robert Zoeller , Horace Lawrence Browning, Jr. , Andy Hugh Singleton
发明人： Gerald Charles Tustin , Joseph Robert Zoeller , Horace Lawrence Browning, Jr. , Andy Hugh Singleton
IPC分类号： B01J23/46 , B01J23/652 , B01J23/656 , C07C51/12 , C07C53/08 , C07C67/36 , C07C69/14 , C07C51/10
摘要： Disclosed is a process wherein a mixture of methanol or a methanol source, a halide and carbon monoxide are contacted in the vapor phase with a supported catalyst comprising iridium and at least one second metal selected from ruthenium, molybdenum, tungsten, palladium, platinum and rhenium deposited on a catalyst support material.
摘要翻译： 公开了一种方法，其中甲醇或甲醇源，卤化物和一氧化碳的混合物在汽相中与负载的催化剂接触，所述载体催化剂包含铱和至少一种选自钌，钼，钨，钯，铂和铼的第二金属 沉积在催化剂载体材料上。
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公开(公告)号：US06506933B1
公开(公告)日：2003-01-14
申请号：US09575537
申请日：2000-05-22
IPC分类号： C07C5112
摘要： Disclosed herein is a vapor phase carbonylation process useful for producing carboxylic acids, esters and mixtures thereof from lower aliphatic alcohols, ethers, ester, and ester-alcohol mixtures. The vapor phase carbonylation process is characterized in that it utilizes a solid supported catalyst having an effective amount of gold associated with a solid support material.
摘要翻译： 本文公开了一种气相羰基化方法，其用于从低级脂族醇，醚，酯和酯 - 醇混合物制备羧酸，酯及其混合物。 气相羰基化方法的特征在于其利用具有与固体支持材料相关的有效量的金的固体负载型催化剂。
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公开(公告)号：US06355595B1
公开(公告)日：2002-03-12
申请号：US09382957
申请日：1999-08-25
IPC分类号： B01J2300
CPC分类号： C07C67/37 , B01J23/468 , C07C51/12 , C07C67/36 , Y02P20/142 , C07C53/08 , C07C69/14
摘要： A solid supported catalyst suitable for the vapor phase carbonylation of lower aliphatic alcohols, ethers, ester, and ester-alcohol mixtures, and desirably, methanol, to produce acetic acid, methyl acetate and mixtures thereof. The solid supported catalyst includes an effective amount of iridium and at least one second metal selected from group metals of the periodic table of elements, their respective salts and mixtures thereof associated with a solid support material. Desirably, the support material is selected from carbon, activated carbon, pumice, alumina, silica, silica-alumina, magnesia, diatomaceous earth, bauxite, titania, zirconia, clay, magnesium silicate, silicon carbide, zeolites, ceramics and combinations thereof.
摘要翻译： 适用于低级脂族醇，醚，酯和酯 - 醇混合物以及理想的甲醇的气相羰基化产生乙酸，乙酸甲酯及其混合物的固体负载型催化剂。 固体负载催化剂包括有效量的铱和至少一种选自元素周期表的族金属的第二金属，它们各自的盐和与固体支持材料的混合物。 理想地，载体材料选自碳，活性炭，浮石，氧化铝，二氧化硅，二氧化硅 - 氧化铝，氧化镁，硅藻土，铝土矿，二氧化钛，氧化锆，粘土，硅酸镁，碳化硅，沸石，陶瓷及其组合。
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公开(公告)号：US5719315A
公开(公告)日：1998-02-17
申请号：US766258
申请日：1996-12-13
CPC分类号： C07C67/46
摘要： This invention pertains to the preparation of vinyl acetate by contacting within a contact zone a mixture of ketene and acetaldehyde with an acid catalyst at about one bar pressure and between about 85.degree. and 200.degree. C. and removing the reaction products from the contact zone.
摘要翻译： 本发明涉及醋酸乙烯酯的制备，该接触区是乙烯酮和乙醛的混合物与酸催化剂在约一巴压力和约85-200℃之间接触并从接触区中除去反应产物。
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10.发明授权Method for carbonylation of lower aliphatic alcohols using tin promoted platinum catalyst 失效使用锡促进的铂催化剂羰基化低级脂族醇的方法公开(公告)号：US06613938B2
公开(公告)日：2003-09-02
申请号：US09884815
申请日：2001-06-19
IPC分类号： C07C6736
摘要： A vapor-phase carbonylation method for producing esters and carboxylic acids from reactants comprising lower alkyl alcohols, lower alkyl alcohol generating compositions and mixtures thereof. The method includes contacting the reactants and carbon monoxide in a carbonylation zone of a carbonylation reactor under vapor-phase conditions with a catalyst having a catalytically effective amount of platinum and tin associated with a solid carrier material.
摘要翻译： 一种用于由包含低级烷基醇，低级烷基醇生成组合物及其混合物的反应物生产酯和羧酸的气相羰基化方法。 该方法包括在气相条件下将羰基化反应器的羰基化反应物和一氧化碳与具有催化有效量的与固体载体材料相关的锡和锡的催化剂接触。
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