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    Process for preparing low molecular weight epoxy resins
    1.
    发明授权
    Process for preparing low molecular weight epoxy resins 失效
    制备低分子量环氧树脂的方法

    公开(公告)号：US4408062A

    公开(公告)日：1983-10-04

    申请号：US359463

    申请日：1982-03-18

    申请人： James L. Bertram ,  George E. Ham ,  Wuu-Nan Chen

    发明人： James L. Bertram ,  George E. Ham ,  Wuu-Nan Chen

    IPC分类号： C07D301/28 ,  C08G59/06

    CPC分类号： C08G59/063

    摘要： The epihalohydrin yield in a process for preparing low molecular weight epoxy resins by coupling a polyhydric phenol and an epihalohydrin in the presence of an alkali metal hydroxide and subsequent dehydrohalogenation is improved by employing stoichiometric quantities of the alkali metal hydroxide with respect to the polyhydric phenol in the coupling reaction and also conducting the coupling reaction in the presence of a halohydrin that is at least as reactive as the halohydrin being formed.

    摘要翻译： 通过在碱金属氢氧化物存在下偶联多元酚和表卤代醇并随后脱卤化氢制备低分子量环氧树脂的方法中的表卤代醇产率通过使用化学计量的碱金属氢氧化物相对于多元酚而得到改善 偶联反应，并且在卤代醇存在下进行偶联反应，所述卤代醇至少与形成的卤代醇具有反应性。

    Cure inhibited epoxy resin compositions and laminates prepared from the compositions
    2.
    发明授权
    Cure inhibited epoxy resin compositions and laminates prepared from the compositions 失效
    固化抑制了由组合物制备的环氧树脂组合物和层压材料

    公开(公告)号：US5721323A

    公开(公告)日：1998-02-24

    申请号：US773697

    申请日：1996-12-27

    申请人： Craig E. Schultz ,  James L. Bertram ,  William A. Clay ,  Guang-Ming Xia ,  Joseph Gan

    发明人： Craig E. Schultz ,  James L. Bertram ,  William A. Clay ,  Guang-Ming Xia ,  Joseph Gan

    IPC分类号： C08G59/18 ,  C08G59/40 ,  C08G59/50 ,  C08J3/24 ,  C08G8/28 ,  C08L63/00

    CPC分类号： C08J3/24 ,  C08G59/18 ,  C08G59/4014 ,  C08G59/50 ,  C08J2363/00

    摘要： A class of compounds which inhibits the reaction of a polyepoxide with a curing agent at low temperatures including an epoxy resin composition containing a) a polyepoxide; b) an amine or amide curing agent for the polyepoxide; c) at least about 15 meq (per equivalent of polyepoxide) of a catalyst for the reaction of the polyepoxide with the curing agent; and d) a cure inhibitor selected such that: (1) at about 171.degree. C. the composition has a gel time that is at least about 50 percent longer than a similar composition without the inhibitor, and (2) at about 175.degree. C. and higher the composition cures in no more than about 50 minutes such that the composition cures rapidly with high cross-link density because it has a high catalyst loading, while the inhibitor lengthens the gel time to permit laminating and other processing.

    摘要翻译： 一类抑制聚环氧化物与低温固化剂反应的化合物，包括含有a）聚环氧化物的环氧树脂组合物; b）用于聚环氧化物的胺或酰胺固化剂; c）至少约15meq（每当量的聚环氧化物）用于聚环氧化物与固化剂反应的催化剂; 并且d）选择的固化抑制剂使得：（1）在约171℃下，组合物的凝胶时间比没有抑制剂的类似组合物长至少约50％，和（2）在约175℃ 并且组合物固化时间不超过约50分钟，使得组合物由于其具有高催化剂负载而迅速具有高的交联密度，而抑制剂延长凝胶时间以允许层压和其它加工。

    Graft copolymer coating compositions
    3.
    发明授权
    Graft copolymer coating compositions 失效
    接枝共聚物涂料组合物

    公开(公告)号：US5426139A

    公开(公告)日：1995-06-20

    申请号：US248797

    申请日：1994-05-25

    申请人： James L. Bertram ,  Zeng K. Liao ,  Lloyd A. McCrary

    发明人： James L. Bertram ,  Zeng K. Liao ,  Lloyd A. McCrary

    IPC分类号： C08G59/62 ,  C08G65/26 ,  C08L63/00 ,  C08L71/02

    CPC分类号： C08L63/00 ,  C08G59/621 ,  C08G65/2612 ,  C08L71/02

    摘要： Graft copolymers containing:(1) a phenolic resin; and (2) a poly(alkylene oxide) chain pendant to the phenolic resin,selected such that the graft copolymer has a solubility of no more than about 10 g/L in water, are taught. The graft copolymers are useful in coatings compositions with a curing agent, a solvent, and optionally an epoxy resin. The curable compositions have improved flexibility and/or solvent resistance. They are particularly useful in can coatings.

    摘要翻译： 接枝共聚物含有：（1）酚醛树脂; 并且（2）向酚醛树脂侧链的聚（环氧烷）链被选择为使得接枝共聚物在水中的溶解度不超过约10g / L。 接枝共聚物可用于具有固化剂，溶剂和任选的环氧树脂的涂料组合物中。 可固化组合物具有改善的柔性和/或耐溶剂性。 它们在罐头涂料中特别有用。

    Amide modified epoxy resins from a dialkanolamine, a monoalkanolamine, an anhydride and (an) unsaturated monomer(s)
    6.
    发明授权
    Amide modified epoxy resins from a dialkanolamine, a monoalkanolamine, an anhydride and (an) unsaturated monomer(s) 失效
    酰胺改性环氧树脂由二烷醇胺，单链烷醇胺，酸酐和（不饱和单体）

    公开(公告)号：US4721742A

    公开(公告)日：1988-01-26

    申请号：US928485

    申请日：1986-11-07

    申请人： James L. Bertram ,  Willie L. Myles

    发明人： James L. Bertram ,  Willie L. Myles

    IPC分类号： C09D163/00 ,  C08F283/00 ,  C08G59/14 ,  C08G59/16 ,  C08G59/42 ,  C08G59/58 ,  C08G59/64

    CPC分类号： C08G59/64 ,  C08F283/00 ,  C08G59/4284 ,  C08G59/58

    摘要： Curable amide modified epoxy resins are prepared by polymerizing (I) the reaction product of (A) the reaction product of (1) an epoxy resin having an average of more than one 1,2-epoxy group per molecule and an average of from about 0 to about 30 aliphatic hydroxyl groups per molecule such as a diglycidyl ether of bisphenol A and (2) (a) a material having only one primary amine group per molecule such as monoethanolamine and (b) a material having only one secondary amine group per molecule such as diethanolamine wherein (a) and (b) are added sequentially with (a) being added first, or as a mixture with (B) an anhydride of an unsaturated dicarboxylic acid such as maleic anhydride with (II) a polymerizable ethylenically unsaturated monomer or mixture of monomers such as styrene and methacrylic acid. The resultant resin can be employed as is in the preparation of organic solvent borne coatings or it can be neutralized with a base so as to improve its stability in the preparation of aqueous coatings.

    摘要翻译： 通过聚合（I）（A）每分子平均具有多于一个1,2-环氧基的环氧树脂和（1）的反应产物的平均值来制备可固化的酰胺改性环氧树脂， 每分子具有0至约30个脂族羟基，例如双酚A的二缩水甘油醚和（2）（a）每分子仅具有一个伯胺基的材料如单乙醇胺，和（b）仅具有一个仲胺基的材料 分子如二乙醇胺，其中（a）和（b）依次加入（a）首先加入，或作为与（B）不饱和二羧酸的酸酐如马来酸酐的混合物与（II）可聚合的烯属不饱和 单体或单体混合物如苯乙烯和甲基丙烯酸。 所得树脂可以直接用于制备有机溶剂型涂料，或者可以用碱中和，以提高其在水性涂料的制备中的稳定性。

    Epoxy resins from hydroxy benzamides
    7.
    发明授权
    Epoxy resins from hydroxy benzamides 失效
    来自羟基苯甲酰胺的环氧树脂

    公开(公告)号：US4673765A

    公开(公告)日：1987-06-16

    申请号：US377660

    申请日：1982-05-13

    申请人： James L. Bertram ,  Edmund P. Woo

    发明人： James L. Bertram ,  Edmund P. Woo

    IPC分类号： C08G18/38 ,  C08G18/50 ,  C08G59/06 ,  C08G59/28 ,  C08G59/32 ,  C07C103/20

    CPC分类号： C08G18/5039 ,  C08G18/3825 ,  C08G59/063 ,  C08G59/28 ,  C08G59/3227

    摘要： New epoxy resins are prepared by reacting a hydroxybenzamide or derivative thereof with an epihalohydrin followed by dehydrohalogenation. These epoxy resins have crystalline melting points, self-cure at elevated temperatures and cure rapidly in the presence of the usual epoxy resin curing agents. Also disclosed are hydrolyzed products of these epoxy resins and subsequent reactions with polyisocyanates.

    摘要翻译： 通过使羟基苯甲酰胺或其衍生物与表卤代醇反应，然后脱卤化氢来制备新的环氧树脂。 这些环氧树脂具有结晶熔点，在升高的温度下自固化并在通常的环氧树脂固化剂存在下快速固化。 还公开了这些环氧树脂的水解产物和随后与多异氰酸酯的反应。

    Process to react epoxide-containing compounds and aliphatic alcohols
    10.
    发明授权
    Process to react epoxide-containing compounds and aliphatic alcohols 失效
    反应含环氧化合物和脂族醇的方法

    公开(公告)号：US5728796A

    公开(公告)日：1998-03-17

    申请号：US652580

    申请日：1996-05-31

    申请人： Zeng K. Liao ,  James L. Bertram

    发明人： Zeng K. Liao ,  James L. Bertram

    IPC分类号： C07D303/20 ,  C07D303/16 ,  C07D303/24 ,  C08G59/04 ,  C08G59/14 ,  C08G59/62 ,  C08G59/68 ,  C07C41/03 ,  C07C43/13

    CPC分类号： C08G59/62 ,  C07D303/16 ,  C07D303/24 ,  C08G59/04 ,  C08G59/1444 ,  C08G59/687

    摘要： A process reaction between: (1) a compound that contains one or more epoxide moieties per molecule, and (2) a compound that contains one or more primary aliphatic hydroxyl groups per molecule; is catalyzed by: (3) a catalyst compound containing one or more trifluoromethanesulfonate moieties and one or more silyl moieties and run at a temperature of no more than 130.degree. C., such that the catalyst preferably catalyzes reaction at the primary aliphatic hydroxyl group, so that the resulting resin does not gel.

    摘要翻译： 以下过程反应：（1）每分子含有一个或多个环氧化物部分的化合物，和（2）每分子含有一个或多个伯脂肪族羟基的化合物; 通过以下方式催化：（3）含有一个或多个三氟甲磺酸酯部分和一个或多个甲硅烷基部分并且在不超过130℃的温度下运行的催化剂化合物，使得催化剂优选催化在伯脂族羟基上的反应， 使得所得树脂不凝胶。