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公开(公告)号：US5491052A
公开(公告)日：1996-02-13
申请号：US477723
申请日：1995-06-07
CPC分类号： G03C7/3882 , G03C1/38 , G03C2200/48 , Y10S430/136
摘要： It has been discovered that when polyalkylene oxide compounds or block polymeric or block oligomeric surface active compounds comprising at least a polyoxypropylene (POP) block and a polyoxyethylene (POE) block are added to conventional dispersions of yellow couplers (that is dispersions in which the dispersed particles have a particle size of 0.1 to 0.6 .mu.m), such dispersions in a coated silver halide photographic element produce substantially higher dye yield compared to the conventional dispersion without any additive. Further, the yellow dye formed from such dispersions containing the addenda of this invention are substantially more light stable compared to dispersions that does not contain such addenda.The invention is carried out just by adding required amounts of the said polyoxyethylene (POE)--polyoxypropylene (POP) compound to a preformed milled coupler dispersion prior to coating the photographic element.
摘要翻译： 已经发现，当将至少包含聚氧丙烯（POP）嵌段和聚氧乙烯（POE）嵌段的聚环氧烷化合物或嵌段聚合或嵌段低聚表面活性化合物加入到黄色成色剂的常规分散体中时（即其中分散的 颗粒具有0.1至0.6μm的粒度），与没有任何添加剂的常规分散体相比，在涂覆的卤化银照相元件中的这种分散体产生显着更高的染料产率。 此外，由含有本发明添加剂的这种分散体形成的黄色染料与不含这种添加剂的分散体相比，显着更稳定。 本发明仅在涂布照相元件之前，将所需量的所述聚氧乙烯（POE） - 聚氧丙烯（POP）化合物添加到预先形成的研磨的偶联剂分散体中进行。
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2.发明授权High dye stability, high activity, low stain and low viscosity small particle yellow dispersion melt for color paper and other photographic systems 失效高染料稳定性，高活性，低污染和低粘度小颗粒黄色分散体，用于彩色纸等摄影系统
公开(公告)号：US5591568A
公开(公告)日：1997-01-07
申请号：US301745
申请日：1994-09-06
申请人： Pranab Bagchi , James L. Edwards , Danuta Gibson , Thomas A. Rosiek , Brian Thomas , Vincent J. Flow, III
发明人： Pranab Bagchi , James L. Edwards , Danuta Gibson , Thomas A. Rosiek , Brian Thomas , Vincent J. Flow, III
CPC分类号： G03C1/38 , G03C7/388 , G03C2200/20 , Y10S430/136 , Y10S516/03 , Y10S516/06
摘要： This invention provides composition and method to overcome the very high viscosity of prior small-particle dispersions when admixed with gelatin in aqueous solution for coating a photographic film element.The invention is generally accomplished by the utilization of a second surfactant in the melt formulated by the admixture of the small-particle dispersion and the gelatin solution. The surfactants of this invention, that is, utilized to control the rheology of such said melts, have the following general structure: ##STR1## wherein n=5 to 20 andx=1 to 4.
摘要翻译： 本发明提供了组合物和方法，以克服在用于涂布照相胶片元件的水溶液中与明胶混合时先前的小颗粒分散体的非常高的粘度。 本发明通常通过在通过小颗粒分散体和明胶溶液的混合物配制的熔体中利用第二表面活性剂来实现。 本发明的表面活性剂，即用于控制所述熔体的流变性，具有以下通用结构：图像（SI-1）<图像>
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3.发明授权High dye stability, high activity, low stain and low viscosity small particle yellow dispersion melt for color paper and other photographic systems 失效高染料稳定性，高活性，低污染和低粘度小颗粒黄色分散体，用于彩色纸等摄影系统
公开(公告)号：US5358831A
公开(公告)日：1994-10-25
申请号：US627154
申请日：1990-12-13
申请人： Pranab Bagchi , James L. Edwards , Danuta Gibson , Thomas A. Rosiek , Brian Thomas , Vincent J. Flow, III
发明人： Pranab Bagchi , James L. Edwards , Danuta Gibson , Thomas A. Rosiek , Brian Thomas , Vincent J. Flow, III
CPC分类号： G03C1/38 , G03C7/388 , G03C2200/20 , Y10S430/136 , Y10S516/03 , Y10S516/06
摘要： This invention provides composition and method to overcome the very high viscosity of prior small-particle dispersions when admixed with gelatin in aqueous solution for coating a photographic film element.The invention is generally accomplished by the utilization of a second surfactant in the melt formulated by the admixture of the small-particle dispersion and the gelatin solution. The surfactants of this invention, that is, utilized to control the theology of such said melts, have the following general structure: ##STR1## wherein n=5 to 20 andx=1 to 4.
摘要翻译： 本发明提供了组合物和方法，以克服在用于涂布照相胶片元件的水溶液中与明胶混合时先前的小颗粒分散体的非常高的粘度。 本发明通常通过在通过小颗粒分散体和明胶溶液的混合物配制的熔体中利用第二表面活性剂来实现。 本发明的表面活性剂，即用于控制所述熔体的神学具有以下通用结构：图像（SI-1）<图像>
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公开(公告)号：US06420103B1
公开(公告)日：2002-07-16
申请号：US09266178
申请日：1999-03-10
IPC分类号： G03C138
CPC分类号： G03C7/3885 , G03C7/362 , G03C7/367 , G03C7/38
摘要： Silver halide light sensitive photographic elements are disclosed comprising a support bearing at least one yellow image forming hydrophilic colloid layer comprising a yellow dye-forming coupler and a trialkyl citrate coupler solvent of the formula C3H4(OH)(CO2R)3, where each R independently represents an alkyl group and the total number of carbon atoms for the three R groups combined is greater than 6. The combination of such citrate ester solvents with yellow dye forming couplers in photographic elements leads to both good reactivity and good image-dye light stability. The advantages of the invention are particularly useful for photographic color paper elements on reflective supports.
摘要翻译： 公开了卤化银光敏感照相材料，其包括载体，该载体承载至少一个黄色图像形成亲水胶体层，其包含黄色染料形成成色剂和式C 3 H 4（OH）（CO 2 R）3的三烷基柠檬酸酯偶联剂溶剂，其中每个R独立地 代表烷基，并且三个R基团的总碳原子数大于6.这些柠檬酸酯溶剂与形成成色剂的黄色染料在照相元件中的组合导致良好的反应性和良好的图像染料光稳定性。 本发明的优点对于反射支撑件上的照相彩色纸元件特别有用。
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5.发明授权Photographic element with yellow dye-forming coupler and stabilizing compound having improved light stability 失效具有黄色染料形成成色剂的照相元件和具有改善的光稳定性的稳定化合物公开(公告)号：US06413707B1
公开(公告)日：2002-07-02
申请号：US09943119
申请日：2001-08-30
IPC分类号： G03C108
CPC分类号： G03C7/3013 , G03C7/39236
摘要： A photographic element is disclosed comprising a silver halide emulsion layer having associated therewith an acetanilide based yellow dye forming coupler and a compound of the following Formula I: wherein R1, R2 and R3 are each independently aromatic, cyclic, linear, or branched chained hydrocarbon groups. The invention provides photographic elements which exhibit exceptional yellow dye light stability, and which retain desirable properties derived from the use of acetanilide based yellow dye-forming couplers, particularly when used in combination with substituted phenolic and/or thiomorpholine dioxide stabilizers. In addition to stabilizing properties, compounds of Formula I have organic solvent properties, and accordingly may be advantageously used partly or totally in place of conventional high boiling permanent and/or auxiliary organic coupler solvents to disperse the acetanilide-based couplers.
摘要翻译： 公开了一种照相元件，其包含卤化银乳剂层，其具有与其形成的基于乙酰苯胺的黄色染料形成成色剂和下式I的化合物：其中R 1，R 2和R 3各自独立地为芳族，环状，直链或支链链烃基 。 本发明提供了显示出特别的黄色染料光稳定性的照相元件，并且其保留了由使用基于乙酰苯胺的形成黄色染料的成色剂得到的所需性质，特别是当与取代的酚类和/或硫代吗啉二氧化物稳定剂组合使用时。 除了稳定性能之外，式I化合物具有有机溶剂性质，因此可有利地部分或全部地代替常规的高沸点永久和/或辅助有机成色剂溶剂来分散基于乙酰苯胺的成色剂。
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6.发明授权Photographic element with yellow dye-forming coupler and stabilizing compounds 失效具有黄色染料成色剂和稳定化合物的摄影元件公开(公告)号：US06312881B1
公开(公告)日：2001-11-06
申请号：US09483396
申请日：2000-01-14
IPC分类号： G03C108
CPC分类号： G03C7/3013 , G03C7/30535 , G03C7/36 , G03C7/362 , G03C7/367 , G03C7/39236 , G03C7/39276
摘要： In accordance with one embodiment of the invention, a photographic element is disclosed comprising a silver halide emulsion layer having associated therewith an acetanilide-based yellow dye forming coupler and a stabilizer compound of the formula S-I: wherein R0 represents an aryl or heterocyclic group; Ra is H or a substituent group; L represents an alkylene linking group and p represents 0 or 1; and Rb is a substituent group, provided that substituent groups represented by Ra and Rb may be joined to form a ring. The presence of substituted amine compounds of formula S-I improves the efficiency of dye formation reaction for acetanilide-based couplers. When used in combination with known bis-phenolic stabilizers, substantial improvements in the light stability of the image dyes can be also be obtained. Accordingly, photographic elements of the present invention upon exposure and photographic processing exhibit good activity and yield yellow dye images that have low fading when exposed to light.
摘要翻译： 根据本发明的一个实施方案，公开了一种照相材料，其包含卤化银乳剂层，其具有与基于乙酰苯胺的黄色染料形成成色剂和式S-I的稳定剂化合物：其中R 0表示芳基或杂环基; Ra是H或取代基; L表示亚烷基连接基团，p表示0或1; 并且R b是取代基，条件是由R a和R b表示的取代基可以连接形成环。 式S-1的取代的胺化合物的存在提高了基于乙酰苯胺的成色剂的染料形成反应的效率。 当与已知的双酚稳定剂组合使用时，也可以获得图像染料的光稳定性的显着改善。 因此，本发明的照相元件在曝光和照相处理时表现出良好的活性，并产生当暴露于光时具有低褪色的黄色染料图像。
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公开(公告)号：US06824936B1
公开(公告)日：2004-11-30
申请号：US10634710
申请日：2003-08-05
IPC分类号： G03C179
CPC分类号： B41M5/502 , B41M5/504 , B41M5/506 , B41M5/5227 , G03C1/79 , G03C1/815 , G03G7/0013 , G03G7/002 , G03G7/0026 , G03G7/0033 , G03G7/004 , G03G7/0046
摘要： The present invention relates to an imaged element comprising at least one imaged layer comprising at least one yellow dye and a support, wherein said support comprises at least one face side resin layer comprising a material capable of improving the yellow dark stability of said imaged element, wherein said materials has the formula:
摘要翻译： 本发明涉及一种成像元件，其包括至少一个成像层，其包含至少一种黄色染料和支持体，其中所述载体包括至少一个正面侧树脂层，其包含能够改善所述成像元件的黄色暗稳定性的材料， 其中所述材料具有下式：
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8.发明授权Color paper post process Dmin keeping with a bis-vinylsulfonyl as the hardener and a chromanol stabilizer 失效彩色纸后处理用二乙烯基磺酰基作为固化剂和色氨醇稳定剂保持
公开(公告)号：US5879870A
公开(公告)日：1999-03-09
申请号：US735371
申请日：1996-10-21
CPC分类号： G03C7/3012 , G03C1/30 , G03C7/3885
摘要： Improvements in post process Dmin are provided in a photographic element that has a preferred coupler, hardener, and permanent solvent. The coupler of the element comprises between about 20 and 40 percent by weight of the coupler and oil phase components and the element further comprises chromanol stabilizer.
摘要翻译： 在具有优选的成色剂，硬化剂和永久溶剂的照相元件中提供后处理Dmin的改进。 元件的成色剂包含约20至40重量％的成色剂和油相组分，并且该元素还包含色甘醇稳定剂。
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9.发明授权Liquid or low melting bis-phenol stabilizers for yellow image dye stabilization in ektacolor paper 失效液体或低熔点双酚稳定剂，用于在ektacolor纸中稳定黄色图像
公开(公告)号：US5426021A
公开(公告)日：1995-06-20
申请号：US86977
申请日：1993-07-02
IPC分类号： C07C69/017 , C07C315/04 , C07C317/22 , C07F9/12 , G03C7/392 , G03C7/36
CPC分类号： G03C7/39216 , C07C315/04 , C07C69/017 , C07F9/12
摘要： A photographic element containing a silver halide emulsion layer having associated therewith, a dye-forming coupler and a dye stabilizer which has a melting point of less than 150.degree. C. (and preferably less than 100.degree. C.) and is of the formula: ##STR1## wherein R, m, q, X, Y, r, and (R.sup.7).sub.n are defined in the specification.The element particularly contains a coupler which forms a yellow dye upon reaction with oxidized developer. A method of making stabilizers of the above type using particular solvents and a non-aqueous workup, is also provided.
摘要翻译： 含有与其相关的卤化银乳剂层的照相元件，染料成色剂和染料稳定剂，其熔点低于150℃（优选小于100℃），并具有下式： ）n在规范中定义。 元素特别包含与氧化显影剂反应形成黄色染料的成色剂。 还提供了使用特定溶剂和非水处理制备上述类型的稳定剂的方法。
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公开(公告)号：US06555304B1
公开(公告)日：2003-04-29
申请号：US10051531
申请日：2002-01-18
申请人： Walter H. Isaac , Vincent J. Flow , James S. Honan , Jeffrey C. Smitley , Patrick W. Webber , Glenn M. Brown , Cynthia A. Fitzgerald , Jess B. Hendricks , Thomas A. Rosiek , John H. Harder , Carolyn H. Ellinger
发明人： Walter H. Isaac , Vincent J. Flow , James S. Honan , Jeffrey C. Smitley , Patrick W. Webber , Glenn M. Brown , Cynthia A. Fitzgerald , Jess B. Hendricks , Thomas A. Rosiek , John H. Harder , Carolyn H. Ellinger
IPC分类号： G03C146
CPC分类号： G03C7/3225 , G03C7/3041 , G03C2200/53
摘要： Disclosed is a silver halide direct view multicolor photographic element comprising a red record containing (1) a red light sensitized silver halide emulsion, (2) a cyan dye-forming NB first coupler, and (3) a second coupler selected from (a) a magenta dye forming coupler in an amount of 2-30 mole % of the total coupler in the red record and (b) a cyan dye-forming coupler having a greater absorption in the green spectra than the first coupler in an amount sufficient to provide a Status A green density in the range of 0.27 to 0.40 using a red light separation exposure at a Status A red density of 1.0. Such an element exhibits improved flesh tone reproduction and good dye dark stability.
摘要翻译： 公开了一种卤化银直观多色照相元件，其包括红色记录，其包含（1）红光增感卤化银乳剂，（2）青色染料形成NB第一偶联剂，和（3）选自（a） 红色记录中的总成色剂的2-30摩尔％的品红色染料形成成色剂，和（b）绿色光谱中比第一成色剂具有更大吸收的青色染料形成成色剂，其量足以提供 状态在状态A红色密度为1.0的红光分离曝光的范围为0.27至0.40的绿色密度。 这样的元素表现出改善的肉色再现和良好的染料黑暗稳定性。
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