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1.发明授权Photographic element with yellow dye-forming coupler and stabilizing compound having improved light stability 失效具有黄色染料形成成色剂的照相元件和具有改善的光稳定性的稳定化合物公开(公告)号：US06413707B1
公开(公告)日：2002-07-02
申请号：US09943119
申请日：2001-08-30
IPC分类号： G03C108
CPC分类号： G03C7/3013 , G03C7/39236
摘要： A photographic element is disclosed comprising a silver halide emulsion layer having associated therewith an acetanilide based yellow dye forming coupler and a compound of the following Formula I: wherein R1, R2 and R3 are each independently aromatic, cyclic, linear, or branched chained hydrocarbon groups. The invention provides photographic elements which exhibit exceptional yellow dye light stability, and which retain desirable properties derived from the use of acetanilide based yellow dye-forming couplers, particularly when used in combination with substituted phenolic and/or thiomorpholine dioxide stabilizers. In addition to stabilizing properties, compounds of Formula I have organic solvent properties, and accordingly may be advantageously used partly or totally in place of conventional high boiling permanent and/or auxiliary organic coupler solvents to disperse the acetanilide-based couplers.
摘要翻译： 公开了一种照相元件，其包含卤化银乳剂层，其具有与其形成的基于乙酰苯胺的黄色染料形成成色剂和下式I的化合物：其中R 1，R 2和R 3各自独立地为芳族，环状，直链或支链链烃基 。 本发明提供了显示出特别的黄色染料光稳定性的照相元件，并且其保留了由使用基于乙酰苯胺的形成黄色染料的成色剂得到的所需性质，特别是当与取代的酚类和/或硫代吗啉二氧化物稳定剂组合使用时。 除了稳定性能之外，式I化合物具有有机溶剂性质，因此可有利地部分或全部地代替常规的高沸点永久和/或辅助有机成色剂溶剂来分散基于乙酰苯胺的成色剂。
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公开(公告)号：US06420103B1
公开(公告)日：2002-07-16
申请号：US09266178
申请日：1999-03-10
IPC分类号： G03C138
CPC分类号： G03C7/3885 , G03C7/362 , G03C7/367 , G03C7/38
摘要： Silver halide light sensitive photographic elements are disclosed comprising a support bearing at least one yellow image forming hydrophilic colloid layer comprising a yellow dye-forming coupler and a trialkyl citrate coupler solvent of the formula C3H4(OH)(CO2R)3, where each R independently represents an alkyl group and the total number of carbon atoms for the three R groups combined is greater than 6. The combination of such citrate ester solvents with yellow dye forming couplers in photographic elements leads to both good reactivity and good image-dye light stability. The advantages of the invention are particularly useful for photographic color paper elements on reflective supports.
摘要翻译： 公开了卤化银光敏感照相材料，其包括载体，该载体承载至少一个黄色图像形成亲水胶体层，其包含黄色染料形成成色剂和式C 3 H 4（OH）（CO 2 R）3的三烷基柠檬酸酯偶联剂溶剂，其中每个R独立地 代表烷基，并且三个R基团的总碳原子数大于6.这些柠檬酸酯溶剂与形成成色剂的黄色染料在照相元件中的组合导致良好的反应性和良好的图像染料光稳定性。 本发明的优点对于反射支撑件上的照相彩色纸元件特别有用。
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3.发明授权Photographic element with yellow dye-forming coupler and stabilizing compounds 失效具有黄色染料成色剂和稳定化合物的摄影元件公开(公告)号：US06312881B1
公开(公告)日：2001-11-06
申请号：US09483396
申请日：2000-01-14
IPC分类号： G03C108
CPC分类号： G03C7/3013 , G03C7/30535 , G03C7/36 , G03C7/362 , G03C7/367 , G03C7/39236 , G03C7/39276
摘要： In accordance with one embodiment of the invention, a photographic element is disclosed comprising a silver halide emulsion layer having associated therewith an acetanilide-based yellow dye forming coupler and a stabilizer compound of the formula S-I: wherein R0 represents an aryl or heterocyclic group; Ra is H or a substituent group; L represents an alkylene linking group and p represents 0 or 1; and Rb is a substituent group, provided that substituent groups represented by Ra and Rb may be joined to form a ring. The presence of substituted amine compounds of formula S-I improves the efficiency of dye formation reaction for acetanilide-based couplers. When used in combination with known bis-phenolic stabilizers, substantial improvements in the light stability of the image dyes can be also be obtained. Accordingly, photographic elements of the present invention upon exposure and photographic processing exhibit good activity and yield yellow dye images that have low fading when exposed to light.
摘要翻译： 根据本发明的一个实施方案，公开了一种照相材料，其包含卤化银乳剂层，其具有与基于乙酰苯胺的黄色染料形成成色剂和式S-I的稳定剂化合物：其中R 0表示芳基或杂环基; Ra是H或取代基; L表示亚烷基连接基团，p表示0或1; 并且R b是取代基，条件是由R a和R b表示的取代基可以连接形成环。 式S-1的取代的胺化合物的存在提高了基于乙酰苯胺的成色剂的染料形成反应的效率。 当与已知的双酚稳定剂组合使用时，也可以获得图像染料的光稳定性的显着改善。 因此，本发明的照相元件在曝光和照相处理时表现出良好的活性，并产生当暴露于光时具有低褪色的黄色染料图像。
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4.发明授权High dye stability, high activity, low stain and low viscosity small particle yellow dispersion melt for color paper and other photographic systems 失效高染料稳定性，高活性，低污染和低粘度小颗粒黄色分散体，用于彩色纸等摄影系统
公开(公告)号：US5591568A
公开(公告)日：1997-01-07
申请号：US301745
申请日：1994-09-06
申请人： Pranab Bagchi , James L. Edwards , Danuta Gibson , Thomas A. Rosiek , Brian Thomas , Vincent J. Flow, III
发明人： Pranab Bagchi , James L. Edwards , Danuta Gibson , Thomas A. Rosiek , Brian Thomas , Vincent J. Flow, III
CPC分类号： G03C1/38 , G03C7/388 , G03C2200/20 , Y10S430/136 , Y10S516/03 , Y10S516/06
摘要： This invention provides composition and method to overcome the very high viscosity of prior small-particle dispersions when admixed with gelatin in aqueous solution for coating a photographic film element.The invention is generally accomplished by the utilization of a second surfactant in the melt formulated by the admixture of the small-particle dispersion and the gelatin solution. The surfactants of this invention, that is, utilized to control the rheology of such said melts, have the following general structure: ##STR1## wherein n=5 to 20 andx=1 to 4.
摘要翻译： 本发明提供了组合物和方法，以克服在用于涂布照相胶片元件的水溶液中与明胶混合时先前的小颗粒分散体的非常高的粘度。 本发明通常通过在通过小颗粒分散体和明胶溶液的混合物配制的熔体中利用第二表面活性剂来实现。 本发明的表面活性剂，即用于控制所述熔体的流变性，具有以下通用结构：图像（SI-1）<图像>
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公开(公告)号：US5491052A
公开(公告)日：1996-02-13
申请号：US477723
申请日：1995-06-07
CPC分类号： G03C7/3882 , G03C1/38 , G03C2200/48 , Y10S430/136
摘要： It has been discovered that when polyalkylene oxide compounds or block polymeric or block oligomeric surface active compounds comprising at least a polyoxypropylene (POP) block and a polyoxyethylene (POE) block are added to conventional dispersions of yellow couplers (that is dispersions in which the dispersed particles have a particle size of 0.1 to 0.6 .mu.m), such dispersions in a coated silver halide photographic element produce substantially higher dye yield compared to the conventional dispersion without any additive. Further, the yellow dye formed from such dispersions containing the addenda of this invention are substantially more light stable compared to dispersions that does not contain such addenda.The invention is carried out just by adding required amounts of the said polyoxyethylene (POE)--polyoxypropylene (POP) compound to a preformed milled coupler dispersion prior to coating the photographic element.
摘要翻译： 已经发现，当将至少包含聚氧丙烯（POP）嵌段和聚氧乙烯（POE）嵌段的聚环氧烷化合物或嵌段聚合或嵌段低聚表面活性化合物加入到黄色成色剂的常规分散体中时（即其中分散的 颗粒具有0.1至0.6μm的粒度），与没有任何添加剂的常规分散体相比，在涂覆的卤化银照相元件中的这种分散体产生显着更高的染料产率。 此外，由含有本发明添加剂的这种分散体形成的黄色染料与不含这种添加剂的分散体相比，显着更稳定。 本发明仅在涂布照相元件之前，将所需量的所述聚氧乙烯（POE） - 聚氧丙烯（POP）化合物添加到预先形成的研磨的偶联剂分散体中进行。
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6.发明授权High dye stability, high activity, low stain and low viscosity small particle yellow dispersion melt for color paper and other photographic systems 失效高染料稳定性，高活性，低污染和低粘度小颗粒黄色分散体，用于彩色纸等摄影系统
公开(公告)号：US5358831A
公开(公告)日：1994-10-25
申请号：US627154
申请日：1990-12-13
申请人： Pranab Bagchi , James L. Edwards , Danuta Gibson , Thomas A. Rosiek , Brian Thomas , Vincent J. Flow, III
发明人： Pranab Bagchi , James L. Edwards , Danuta Gibson , Thomas A. Rosiek , Brian Thomas , Vincent J. Flow, III
CPC分类号： G03C1/38 , G03C7/388 , G03C2200/20 , Y10S430/136 , Y10S516/03 , Y10S516/06
摘要： This invention provides composition and method to overcome the very high viscosity of prior small-particle dispersions when admixed with gelatin in aqueous solution for coating a photographic film element.The invention is generally accomplished by the utilization of a second surfactant in the melt formulated by the admixture of the small-particle dispersion and the gelatin solution. The surfactants of this invention, that is, utilized to control the theology of such said melts, have the following general structure: ##STR1## wherein n=5 to 20 andx=1 to 4.
摘要翻译： 本发明提供了组合物和方法，以克服在用于涂布照相胶片元件的水溶液中与明胶混合时先前的小颗粒分散体的非常高的粘度。 本发明通常通过在通过小颗粒分散体和明胶溶液的混合物配制的熔体中利用第二表面活性剂来实现。 本发明的表面活性剂，即用于控制所述熔体的神学具有以下通用结构：图像（SI-1）<图像>
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公开(公告)号：US08467648B2
公开(公告)日：2013-06-18
申请号：US13448003
申请日：2012-04-16
申请人： Liang Dong , Brian Thomas , Libin Fu
发明人： Liang Dong , Brian Thomas , Libin Fu
CPC分类号： G02F1/365 , C03B37/0122 , C03B2201/82 , C03B2201/86 , C03B2203/10 , C03B2203/14 , C03B2203/42 , C03B2205/08 , C03B2205/10 , G02B6/02214 , G02B6/02333 , G02B6/02357 , G02F1/395 , H01S3/0057 , H01S3/06729 , H01S3/06754
摘要： Various embodiments of optical fiber designs and fabrication processes for ultra small core fibers (USCF) are disclosed. In some embodiments, the USCF includes a core that is at least partially surrounded by a region comprising first features. The USCF further includes a second region at least partially surrounding the first region. The second region includes second features. In an embodiment, the first features are smaller than the second features, and the second features have a filling fraction greater than about 90 percent. The first features and/or the second features may include air holes. Embodiments of the USCF may provide dispersion tailoring. Embodiments of the USCF may be used with nonlinear optical devices configured to provide, for example, a frequency comb or a supercontinuum.
摘要翻译： 公开了用于超小芯纤维（USCF）的光纤设计和制造工艺的各种实施例。 在一些实施例中，USCF包括至少部分地被包括第一特征的区域包围的芯。 USCF还包括至少部分围绕第一区域的第二区域。 第二个区域包括第二个特征。 在一个实施例中，第一特征小于第二特征，并且第二特征具有大于约90％的填充分数。 第一特征和/或第二特征可以包括气孔。 USCF的实施例可以提供色散调整。 USCF的实施例可以与被配置为提供例如频率梳或超连续谱的非线性光学装置一起使用。
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公开(公告)号：US08262730B2
公开(公告)日：2012-09-11
申请号：US11608128
申请日：2006-12-07
申请人： Brian Thomas , Kai Zhang , Garryl Hudgins , Robert Hodorek
发明人： Brian Thomas , Kai Zhang , Garryl Hudgins , Robert Hodorek
CPC分类号： A61L24/06 , A61L24/0031 , A61L27/16 , A61L27/52 , C08L29/04
摘要： This invention provides methods and processes to attach or bond hydrogels to suitable surfaces using irradiation techniques and also provides methods and processes to create crosslinked regions in hydrogel articles using these irradiation techniques. Specifically, lasers at wavelengths tuned to the irradiation absorption bands of hydroxyl groups, carboxylic acid groups or water may be used to attach or bond hydrogels to surfaces such as soft tissue and hydrogel surfaces or to crosslink regions in hydrogel articles.
摘要翻译： 本发明提供了使用照射技术将水凝胶附着或粘合到合适表面上的方法和方法，并且还提供使用这些照射技术在水凝胶制品中产生交联区域的方法和方法。 具体地，可以使用调谐到羟基，羧酸基团或水的照射吸收带的波长的激光器将水凝胶附着或粘合到表面，例如软组织和水凝胶表面，或者在水凝胶制品中交联区域。
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公开(公告)号：US08062739B2
公开(公告)日：2011-11-22
申请号：US11848698
申请日：2007-08-31
申请人： Kaifeng Liu , Brian Thomas , Steven Charlebois
发明人： Kaifeng Liu , Brian Thomas , Steven Charlebois
摘要： The present invention provides a hydrogel article having a multi-layered structure and exhibiting a gradient in polymer molecular weight. The invention also provides a method of forming a hydrogel article having a multi-layered structure and exhibiting a gradient in polymer molecular weight.
摘要翻译： 本发明提供具有多层结构且呈现聚合物分子量梯度的水凝胶制品。 本发明还提供了形成具有多层结构且呈现聚合物分子量梯度的水凝胶制品的方法。
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10.发明申请Synthetic Polymer Adhesives And Methods For Making, Using And Delivering The Same 有权合成聚合物粘合剂及其制备，使用和提供方法公开(公告)号：US20110276088A1
公开(公告)日：2011-11-10
申请号：US13099549
申请日：2011-05-03
申请人： Brian Thomas , Donald Yakimicki
发明人： Brian Thomas , Donald Yakimicki
CPC分类号： A61B17/00491 , A61B2017/00495 , A61B2017/00707 , A61L24/043 , C08K3/22 , C08K3/38 , C09J129/04 , G09B23/285
摘要： A synthetic polymer based adhesive formulation that has properties substantially simulating selected properties of fibrin glue, and methods of making and using the same. The adhesive formulation includes a discrete acid solution and discrete base solution that when combined form a synthetic polymer based adhesive that substantially simulates selected properties of fibrin glue. The discrete acid solution includes a polymer and a cross-linking agent precursor. The discrete base solution includes a polymer and a base.
摘要翻译： 具有基本上模拟纤维蛋白胶的选择性质的性质的合成聚合物基粘合剂制剂及其制备和使用方法。 粘合剂制剂包括离散的酸溶液和离散的碱性溶液，当组合形成基本上模拟纤维蛋白胶的选定性质的基于合成聚合物的粘合剂时。 离散酸溶液包括聚合物和交联剂前体。 离散碱溶液包括聚合物和碱。
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