公开(公告)号：US4879344A

公开(公告)日：1989-11-07

申请号：US229269

申请日：1988-08-08

Applicant: James T. K. Woo ,  John C. Reising ,  Richard M. Marcinko ,  David E. Miles

Inventor： James T. K. Woo ,  John C. Reising ,  Richard M. Marcinko ,  David E. Miles

IPC: C08F8/42 ,  C08L83/06 ,  C09D133/06

CPC classification number: C09D133/066 ,  C08F8/42 ,  C08L83/06

Abstract: A powder paint coating is based upon a thermosetting polymeric binder comprising a hydroxyl functional arcylic copolymer adapted to coreact upon heating with solid cyclic silicone resin.

Abstract translation: 粉末涂料基于热固性聚合物粘合剂，其包含适于在用固体环状有机硅树脂加热时起核心作用的羟基官能的甲酰基共聚物。

公开(公告)号：US4482671A

公开(公告)日：1984-11-13

申请号：US438375

申请日：1982-11-01

Applicant: James T. K. Woo ,  Vincent W. Ting ,  Richard M. Marcinko

Inventor： James T. K. Woo ,  Vincent W. Ting ,  Richard M. Marcinko

IPC: C08F283/10 ,  C09D151/00 ,  C08L63/02 ,  C08L67/00

CPC classification number: C08F283/10 ,  C09D151/00 ,  Y10S525/93 ,  Y10T428/31529

Abstract: Provides new and improved water-reducible coating compositions and methods of making them. Three preferred processes are disclosed. These differ in the manner of incorporating and chemical nature of an extender polymer.Broadly, the process of the invention is one for forming an aqueous dispersion of a fluent resinous composition ofa. a mixture in an organic solvent of(i) an ionizable graft polymer of an epoxy resin and an addition polymerized resin, the addition polymerized resin being bonded to aliphatic backbone carbon atoms of the epoxy resin by carbon-to-carbon bonds, and(ii) an extender resin;b. an aqueous vehicle, andc. an ionizing agent;the ionization present from said combined components being sufficient to establish the components as a dispersion in the aqueous vehicle, and then addition polymerizing a quantity of addition polymerizable monomer, under addition polymerizing conditions, in said aqueous dispersion, the aqueous dispersion serving as a vehicle therefor.In another aspect of the invention, a grafting base is produced by advancing an aromatic epoxy resin in the presence of at least one extender resin and a sufficient amount of an organic solvent to render the initial mixture and grafting base product fluent.

Abstract translation: 提供新的和改进的可水稀释涂料组合物及其制备方法。 公开了三个优选的方法。 这些不同之处在于掺入和化学性质的增量聚合物。 广泛地说，本发明的方法是用于形成流体树脂组合物的水分散体。 在（i）环氧树脂的可离子化接枝聚合物和加成聚合树脂的有机溶剂中的混合物，加成聚合树脂通过碳 - 碳键与环氧树脂的脂族主链碳原子键合，和（ii ）增量树脂; b。 水性载体，和c。 电离剂; 存在于所述组合组分中的电离足以建立作为水性载体中的分散体的组分，然后在加入的聚合条件下在所述水性分散体中加入聚合一定量的可加成聚合单体，作为载体的水性分散体 。 在本发明的另一方面，通过在至少一种增量树脂和足够量的有机溶剂的存在下使芳族环氧树脂前进来制备接枝碱，以使初始混合物和基料产物流动。

公开(公告)号：US5532297A

公开(公告)日：1996-07-02

申请号：US451147

申请日：1995-05-26

Applicant: James T. K. Woo ,  Gary C. Pompignano ,  Donston E. Awarski ,  Kevan A. Packard

Inventor： James T. K. Woo ,  Gary C. Pompignano ,  Donston E. Awarski ,  Kevan A. Packard

IPC: C08F287/00 ,  C09D151/00 ,  C08K3/20 ,  C08L63/02

CPC classification number: C09D151/00 ,  C08F287/00

Abstract: The invention pertains to aqueous dispersed, crosslinked microgel polymers useful as a polymeric binder in protective coatings. The microgel polymeric binder comprises epoxy-acrylic graft copolymer dispersed into water, emulsion copolymerized monoethylenically unsaturated monomer, and emulsion copolymerized divinyl benzene adapted to crosslink in the emulsion copolymerization step with the monoethylenic monomers to produce the crosslinked microgel polymer particles. The microgel polymer is particularly useful as binder for can coatings adapted to be heat cured to form a protective film.

Abstract translation: 本发明涉及用作保护涂层中的聚合物粘合剂的水性分散的交联微凝胶聚合物。 微凝胶聚合物粘合剂包括分散在水中的环氧 - 丙烯酸接枝共聚物，乳液共聚单烯属不饱和单体和适于在乳液共聚步骤中与单烯属单体交联的乳液共聚二乙烯基苯，以产生交联的微凝胶聚合物颗粒。 微凝胶聚合物特别可用作适于热固化以形成保护膜的罐涂料的粘合剂。

公开(公告)号：US4241200A

公开(公告)日：1980-12-23

申请号：US98909

申请日：1979-11-30

Applicant: James T. K. Woo

Inventor： James T. K. Woo

IPC: C08F299/06 ,  C08G18/86 ,  C09D5/44 ,  C08G18/30

CPC classification number: C08F299/06 ,  C08G18/86 ,  C09D5/4411 ,  C09D5/4465

Abstract: An improved electrocoating composition can be produced by first reacting an isocyanate terminated prepolymer with a minor amount of peroxide to provide a polyurethane polymer blocked with pendant peroxide groups, and then coreacting acrylic monomers with minor amounts of other ethylenically unsaturated monomers in the presence of the preformed polyurethane-peroxide polymer to provide polyurethane copolymer with said monomers. The resulting polyurethane acrylic block copolymer can contain carboxyl or amine groups for dispersing into a dilute aqueous solution and provide an anodic or cathodic electrocoating composition.

Abstract translation: 可以通过首先使异氰酸酯封端的预聚物与少量过氧化物反应来提供改进的电涂组合物，以提供用过氧化物侧基封端的聚氨酯聚合物，然后在预成型的存在下将丙烯酸单体与少量其它烯属不饱和单体共聚 聚氨酯过氧化物聚合物，以提供与所述单体的聚氨酯共聚物。 所得到的聚氨酯丙烯酸嵌段共聚物可含有用于分散到稀水溶液中的羧基或胺基，并提供阳极或阴极电涂组合物。

公开(公告)号：US4119599A

公开(公告)日：1978-10-10

申请号：US813082

申请日：1977-07-05

Applicant: James T. K. Woo ,  James M. Evans

Inventor： James T. K. Woo ,  James M. Evans

IPC: C08L63/02 ,  C09D5/44 ,  C25D13/06 ,  C08L61/28

CPC classification number: C09D5/443 ,  C08L63/00 ,  Y10S524/901 ,  Y10T428/31529 ,  Y10T428/31688

Abstract: Heat cured coatings cathodically electrodeposited from an aqueous dispersion of (a) an ionized reaction product of an epoxy resin and a monoamino alcohol or phenol, said reaction product also having a pendant hydrocarbon group, (b) an acid-functional aminoplast resin, and (c) a water soluble acid solubilizer, where the dispersion is free from water soluble acid which will be retained in the heat cured resinous coating are found to provide exceptional resistance to corrosion of ferrous metal substrates upon exposure to salt spray or detergent solutions.

公开(公告)号：US4882372A

公开(公告)日：1989-11-21

申请号：US229461

申请日：1988-08-08

Applicant: James T. K. Woo ,  Richard M. Marcinko

Inventor： James T. K. Woo ,  Richard M. Marcinko

IPC: C08J7/04 ,  C09D163/00

CPC classification number: C08J7/047 ,  C09D163/00 ,  C08J2433/00 ,  C08J2463/00 ,  Y10T428/249991 ,  Y10T428/31511

Abstract: A water-dispersed paint coating composition particularly useful for plastic substrates such as polystyrene foam comprises a polymeric binder of a functional acrylic copolymer and epoxy resin. Preferably, the epoxy resin is a coreaction product containing sorbitol. The polymers are water-dispersed and are adapted to cure and crosslink at ambient temperatures.

Abstract translation: 特别适用于塑料基材如聚苯乙烯泡沫的水分散漆涂料组合物包括官能丙烯酸共聚物和环氧树脂的聚合物粘合剂。 优选地，环氧树脂是含有山梨醇的核心产物。 聚合物是水分散的并适于在环境温度下固化和交联。

公开(公告)号：US4778862A

公开(公告)日：1988-10-18

申请号：US7505

申请日：1987-01-28

Applicant: James T. K. Woo ,  Richard M. Marcinko

Inventor： James T. K. Woo ,  Richard M. Marcinko

IPC: C08F283/12 ,  C09D151/08 ,  C08G77/04

CPC classification number: C09D151/085 ,  C08F283/12

Abstract: A fluorinated-silicone-acrylic terpolymer useful as a binder in powder coatings is prepared by step-wise synthesis. The process comprises reacting silicone resin with a fluorinated component to produce a fluorinated silicone resin followed by further reaction with hydroxylated acrylic prepolymer to form the flourinated-silicone-acrylic terpolymer.

Abstract translation: 通过逐步合成制备用作粉末涂料中粘合剂的氟化硅氧烷 - 丙烯酸三元共聚物。 该方法包括使硅氧烷树脂与氟化组分反应以产生氟化硅氧烷树脂，随后与羟基化丙烯酸预聚物进一步反应形成有机硅 - 丙烯酸三元共聚物。

公开(公告)号：US4487860A

公开(公告)日：1984-12-11

申请号：US558292

申请日：1983-12-05

Applicant: Peter P. Winner ,  James T. K. Woo

Inventor： Peter P. Winner ,  James T. K. Woo

IPC: C08F291/00 ,  C08L33/06 ,  C09D157/00 ,  C08L63/00 ,  C09D5/02

CPC classification number: C08F291/00 ,  C09D157/00 ,  C08L33/062

Abstract: The composition comprises an aqueous polyelectrolyte polymer intermixed with a phosphated polymer and a self-curing water dispersed polymer containing copolymerized functional monomer and alkylol acrylamide monomer. The polyelectrolyte polymer is produced by copolymerizing ethylenically unsaturated monomers, including hydroxyl or carboxyl monomers in the presence of an ionizing agent.

Abstract translation: 该组合物包含与磷酸化聚合物和含有共聚官能单体和羟烷基丙烯酰胺单体的自固化水分散聚合物混合的水性聚电解质聚合物。 聚电解质聚合物通过在电离剂存在下共聚乙烯基不饱和单体（包括羟基或羧基单体）来制备。

公开(公告)号：US4335028A

公开(公告)日：1982-06-15

申请号：US188996

申请日：1980-09-22

Applicant: Vincent W. Ting ,  James T. K. Woo ,  David A. Borovicka, Sr.

Inventor： Vincent W. Ting ,  James T. K. Woo ,  David A. Borovicka, Sr.

IPC: C08F283/10 ,  C09D5/44 ,  C08L63/00

CPC classification number: C09D5/4473 ,  C08F283/10 ,  Y10T428/31529

Abstract: A base-functional graft polymer-containing resinous reaction product is made by incorporating an amine in a graft polymer molecule. An epoxy resin is reacted with ethylenically unsaturated monomer in the presence of a free radical initiator having hydrogen abstraction capability, to form a graft polymer resinous reaction product. The monomer may comprise a copolymerizable unsaturated amine or an unsaturated epoxide that, after the addition polymerization - grafting reaction, is reacted with a primary or secondary amine. Upon the addition of an ionizing agent and water, an aqueous dispersion or solution can be established.The resinous reaction products are useful in the formulation of coating compositions, and particularly, coating compositions useful for cathodic electrocoating.

Abstract translation: 通过在接枝聚合物分子中引入胺制备含基础官能的含接枝聚合物的树脂反应产物。 在具有取氢能力的自由基引发剂的存在下，环氧树脂与烯属不饱和单体反应，形成接枝聚合物树脂反应产物。 单体可以包含可共聚的不饱和胺或不饱和环氧化物，其在加成聚合 - 接枝反应后与伯胺或仲胺反应。 加入电离剂和水后，可以建立水分散体或溶液。 树脂反应产物可用于涂料组合物的制剂，特别是可用于阴极电泳的涂料组合物。

公开(公告)号：US4328144A

公开(公告)日：1982-05-04

申请号：US131166

申请日：1980-03-17

Applicant: James T. K. Woo

Inventor： James T. K. Woo

IPC: C08F220/36 ,  C08G18/62 ,  C08G59/40 ,  C08L33/06 ,  C09D133/06 ,  C08L33/08 ,  C08L33/10 ,  C08L61/00 ,  C08L75/04

CPC classification number: C08G59/4042 ,  C08F220/36 ,  C08G18/6283 ,  C09D133/062 ,  C08L2205/02 ,  C08L33/062

Abstract: Room temperature curable latices can be produced by copolymerizing ketimine derivative ethylenically unsaturated monomers with conventional ethylenically unsaturated monomers in an emulsion process at a controlled pH greater than about 7.2 to produce a coagulum-free latex containing blocked amine (--NH.sub.2) groups. In use, the pH of the latex can be adjusted to acidic below 7 to generate unblocked reactive amino groups which can be cured or cross-linked at about room temperature with water-dispersed polymers such as epoxy, double bond or isothiocyanate containing polymers.

Abstract translation: 室温可固化胶乳可通过在受控pH大于约7.2的乳液法中将酮亚胺衍生物烯键式不饱和单体与常规烯属不饱和单体共聚来制备含有封闭胺（-NH 2）基团的无凝结胶乳。 在使用中，可以将胶乳的pH调节至低于7的酸性，以产生未封闭的反应性氨基，其可以在约室温下用水分散的聚合物如环氧树脂，双键或含异硫氰酸酯的聚合物固化或交联。