公开(公告)号：US4251600A

公开(公告)日：1981-02-17

申请号：US107760

申请日：1979-12-27

申请人： James W. Sim ,  Kimio Kinoshita

发明人： James W. Sim ,  Kimio Kinoshita

IPC分类号： C01F7/04 ,  C04B35/113 ,  H01M2/16 ,  H01M8/02 ,  H01M8/14 ,  B28B1/26

CPC分类号： H01M2/1646 ,  C01F7/043 ,  C04B35/113 ,  H01M8/0295 ,  H01M2300/0048

摘要： A porous sintered tile is formed of lithium aluminate for retaining moltenlectrolyte within a fuel cell. The tile is prepared by reacting lithium hydroxide in aqueous solution with alumina particles to form beta lithium aluminate particles. The slurry is evaporated to dryness and the solids dehydrated to form a beta lithium aluminate powder. The powder is compacted into the desired shape and sintered at a temperature in excess of 1200 K. but less than 1900 K. to form a porous integral structure that is subsequently filled with molten electrolyte. A tile of this type is intended for use in containing molten alkali metal carbonates as electolyte for use in a fuel cell having porous metal or metal oxide electrodes for burning a fuel gas such as hydrogen and/or carbon monoxide with an oxidant gas containing oxygen.

摘要翻译： 多孔烧结砖由铝酸锂形成，用于将熔融电解质保持在燃料电池内。 通过使氢氧化锂在水溶液中与氧化铝颗粒反应形成β铝酸锂颗粒来制备瓦。 将浆料蒸发至干，固体脱水形成β-铝酸锂粉末。 将粉末压实成所需的形状并在超过1200K但低于1900K的温度下烧结以形成随后用熔融电解质填充的多孔整体结构。 这种瓷砖用于将熔融碱金属碳酸盐作为电解液用于含有多孔金属或金属氧化物电极的燃料电池中，所述多孔金属或金属氧化物电极用含氧气的氧化剂气体燃烧诸如氢气和/或一氧化碳的燃料气体。

公开(公告)号：US4721513A

公开(公告)日：1988-01-26

申请号：US343606

申请日：1982-01-28

申请人： James L. Smith ,  James W. Sim ,  Eugenia H. Kucera

发明人： James L. Smith ,  James W. Sim ,  Eugenia H. Kucera

IPC分类号： H01M4/86 ,  H01M4/88 ,  H01M8/14 ,  H01M6/00

CPC分类号： H01M4/8875 ,  H01M4/8878 ,  H01M4/8885 ,  H01M4/9016 ,  H01M8/142 ,  H01M2004/8689 ,  H01M2008/147 ,  H01M2300/0051 ,  H01M8/148 ,  Y02E60/526 ,  Y10T29/49115

摘要： A method of preparing a porous cathode structure for use in a molten carbonate fuel cell begins by providing a porous integral plaque of sintered nickel oxide particles. The nickel oxide plaque can be obtained by oxidizing a sintered plaque of nickel metal or by compacting and sintering finely divided nickel oxide particles to the desired pore structure. The porous sintered nickel oxide plaque is contacted with a lithium salt for a sufficient time to lithiate the nickel oxide structure and thus enhance its electronic conductivity. The lithiation can be carried out either within an operating fuel cell or prior to assembling the plaque as a cathode within the fuel cell.

摘要翻译： 制备用于熔融碳酸盐燃料电池的多孔阴极结构的方法是通过提供一种多孔的烧结氧化镍颗粒的整体板开始的。 镍氧化物斑块可以通过氧化镍金属的烧结斑块或通过将细碎的氧化镍颗粒压实和烧结成所需的孔结构来获得。 多孔烧结镍氧化物斑块与锂盐接触足够的时间以锂化氧化镍结构，从而增强其电导率。 锂化可以在运行中的燃料电池内部或在将作为阴极的板块组装在燃料电池内之前进行。

公开(公告)号：US4564567A

公开(公告)日：1986-01-14

申请号：US550697

申请日：1983-11-10

申请人： Gene H. Kucera ,  James L. Smith ,  James W. Sim

发明人： Gene H. Kucera ,  James L. Smith ,  James W. Sim

IPC分类号： C04B35/01 ,  H01M4/86 ,  H01M4/90 ,  H01M8/14

CPC分类号： H01M4/9016 ,  C04B35/016 ,  H01M8/142 ,  H01M2008/147 ,  H01M2300/0051 ,  Y02E60/526

摘要： A high temperature, ceramic composition having electronic conductivity as measured by resistivity below about 500 ohm-cm, chemical stability particularly with respect to cathode conditions in a molten carbonate fuel cell, and composed of an alkali metal, transition metal oxide containing a dopant metal in the crystalline structure to replace a portion of the alkali metal or transition metal.

摘要翻译： 具有电阻率低于约500欧姆 - 厘米的电导率的高温陶瓷组合物，特别是熔融碳酸盐燃料电池中阴极条件下的化学稳定性，由碱金属，含有掺杂剂金属的过渡金属氧化物组成 用于取代一部分碱金属或过渡金属的晶体结构。