摘要:
The invention relates to novel coated post-formable films, to surface-coating compositions for such films, to a combined method for curing the surface-coating compositions and for post-forming, as well as to molded bodies produced from the coated films.
摘要:
The invention relates to novel coated post-formable films, to surface-coating compositions for such films, to a combined method for curing the surface-coating compositions and for post-forming, as well as to moulded bodies produced from the coated films.
摘要:
The present invention relates to printed films, to a process for printing said films, to the curing of layers applied by printing processes, and to molded articles produced from said layers.
摘要:
An organic polyisocyanate with at least one unsaturated functional group is capable of copolymerizing when exposed to actinic radiation. The polyisocyanate comprises structural units with the formula (1): wherein: X is an electron-attracting group; R1, and R2 are hydrogen atoms, a saturated or unsaturated aliphatic or cycloaliphatic radical, or an aromatic or araliphatic radical; and n is an integer from 0 to 5. A process for producing this polyisocyanate is also disclosed.
摘要:
The present invention relates to a process for coating a substrate by applying to a substrate a coating composition containing A) at least one compound which contains at least two (meth)acrylate groups and at least one isocyanate-reactive group and which is free from isocyanate groups and blocked isocyanate groups, B) at least one blocked polyisocyanate, which does not contain any ethylenically unsaturated groups and C) at least one photoinitiator, curing the coating composition by the action of UV light and post-curing by increasing the temperature of the coating.
摘要:
The invention relates to novel coated post-formable films, to surface-coating compositions for such films, to a combined method for curing the surface-coating compositions and for post-forming, as well as to moulded bodies produced from the coated films.
摘要:
The present invention relates to a process for preparing low-viscosity, allophanate-containing and NCO-free polyurethane prepolymers curable by actinic radiation, and to the products obtainable by this process. The prepolymers have residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, and are prepared by a process in which A) diisocyanates, B) hydroxy-functional compounds containing groups which react with ethylenically unsaturated compounds on exposure to actinic radiation, and C) polyester, polyether or polycarbonate polyols having a functionality of at least 1.9 and a number-average molecular weight (Mn) of at least 1000 g/mol, D) optionally in the presence of a catalyst, are reacted to form NCO-group-containing prepolymers having radiation-curing groups, which are subsequently reacted E) optionally after addition of monofunctional isocyanates in the presence F) of an allophanatization catalyst to give allophanate-containing prepolymers, the ratio of NCO groups of the compounds from A) to the OH groups of the compounds from B) and C) being 1.45:1.0 to 1.1:1.0 and the ratio of the OH groups from B) to the OH groups from C) being 8.0:1 to 1.5:1.
摘要:
The present invention relates to a process for preparing low-viscosity, allophanate-containing and NCO-free polyurethane prepolymers curable by actinic radiation, and to the products obtainable by this process. The prepolymers have residual monomer contents of less than 0.5% by weight and an NCO content of less than 1% by weight, and are prepared by a process in which A) diisocyanates, B) hydroxy-functional compounds containing groups which react with ethylenically unsaturated compounds on exposure to actinic radiation, and C) polyester, polyether or polycarbonate polyols having a functionality of at least 1.9 and a number-average molecular weight (Mn) of at least 1000 g/mol, D) optionally in the presence of a catalyst, are reacted to form NCO-group-containing prepolymers having radiation-curing groups, which are subsequently reacted E) optionally after addition of monofunctional isocyanates in the presence F) of an allophanatization catalyst to give allophanate-containing prepolymers, the ratio of NCO groups of the compounds from A) to the OH groups of the compounds from B) and C) being 1.45:1.0 to 1.1:1.0 and the ratio of the OH groups from B) to the OH groups from C) being 8.0:1 to 1.5:1.
摘要翻译:本发明涉及一种制备可通过光化辐射固化的低粘度,含有脲基甲酸酯和不含NCO的聚氨酯预聚物和通过该方法获得的产品的方法。 预聚物的残留单体含量小于0.5重量%,NCO含量小于1重量%,并且通过以下方法制备:A)二异氰酸酯,B)含有与烯属不饱和基团反应的基团的羟基官能化合物 化合物暴露于光化辐射,以及C)官能度为至少1.9,数均分子量(M N n N)至少为1000g / mol的聚酯,聚醚或聚碳酸酯多元醇,D )任选地在催化剂存在下反应以形成具有辐射固化基团的含有NCO基团的预聚物,其随后在式I化合物催化剂存在下加入单官能异氰酸酯后反应E),得到脲基甲酸酯 - 来自B)和C)的化合物的OH基的比例为1.45:1.0至1.1:1.0,并且B基中的OH基与OH基的比例 C)为8.0:1 至1.5:1。
摘要:
The present invention relates to a process for preparing radiation-curing binders containing allophanate groups by reacting, at temperatures of ≦130° C., A) one or more compounds containing uretdione groups with B) one or more OH-functional compounds which contain groups which react, with polymerization, with ethylenically unsaturated compounds on exposure to actinic radiation (radiation-curing groups), C) optionally NCO-reactive compounds other than B), in the presence of D) a catalyst containing at least one zinc compound, to form allophanate groups by opening the uretdione ring. The present invention also relates to the binders obtained by the process of the invention and to coating compositions containing these binders.
摘要:
The invention relates to new, low viscosity radiation-hardenable urethane acrylates prepared from oxalkylated polyols with 25 to 75 mole % of a polyol having a degree of oxalkylation between 3 and 5 and 75 to 25 mole % of a polyol having a degree of oxalkylation between 8 and 25, the resulting coatings having improved abrasion resistance, as well as their use as coating compositions, in particular for flooring materials.