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1.发明授权Silicone composition crosslinkable by dehydrogenating condensation in the presence of a metal catalyst 失效有机硅组合物可通过在金属催化剂存在下脱氢缩合而交联公开(公告)号：US06875516B2
公开(公告)日：2005-04-05
申请号：US10124270
申请日：2002-04-18
CPC分类号： C08J9/02 , C08G77/045 , C08G77/12 , C08G77/16 , C08G2101/00 , C08J2201/024 , C08J2383/04 , C08J2383/08 , C08K5/50 , C08L83/04 , C09D183/08 , Y10T428/24504 , Y10T428/249954 , Y10T428/249958 , Y10T428/31663 , C08L83/00
摘要： An ≡SiH/≡SiOH silicone composition polymerizable/crosslinkable by dehydrogenating condensation in the presence of a catalyst judiciously selected to achieve at least one of the following: kinetics, concentration/efficiency ratio of the catalyst, cost, lowering of the catalyst activation temperature (room temperature), control of the release of gaseous hydrogen and the quality of the polymerized product and the crosslinked network, and finally limitation of the secondary reactions. This composition includes: —A— at least one ≡SiH POS; —B— at least one ≡SiOH POS; —C— at least one metal catalyst selected from the group of organometallic complexes including at least one of the following metals: Ir, Ru, Mn; —D— optionally at least one crosslinking inhibitor; —E— optionally at least one POS resin; and —F— optionally at least one filler. Also disclosed is the catalyst —C— and processes which involve crosslinking of silicone by dehydrogenating condensation (non-stick coating on paper).
摘要翻译： An = SiH / = SiOH硅氧烷组合物，其通过在催化剂存在下通过脱气缩合而可聚合/交联，所述催化剂明智地选择以实现以下至少一种：动力学，催化剂的浓度/效率比，成本，催化剂活化温度的降低 室温），控制气态氢的释放以及聚合产物和交联网络的质量，最后限制二次反应。 该组合物包括：-A-至少一个= SiH POS; -B-至少一个= SiOH POS; -C-至少一种金属催化剂，其选自包括以下金属中的至少一种的有机金属络合物：Ir， Ru，Mn; -D-任选至少一种交联抑制剂; -E-任选至少一种POS树脂; 和-F-任选的至少一种填料。还公开了催化剂-C-和涉及通过脱氢冷凝（纸上不粘涂层）使硅氧烷交联的方法。
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公开(公告)号：US08846975B2
公开(公告)日：2014-09-30
申请号：US13697189
申请日：2011-05-09
CPC分类号： C07C51/316 , C07C55/14 , C07C55/02
摘要： A process for preparing dicarboxylic acids is described. More particularly a process is described for preparing adipic acid (1,6-hexanedioic acid), by the action of nitric acid, starting from cyclic ketones or alcohols which are the corresponding compounds from the standpoint of the number of carbon atoms, in the presence of one or more oxides of nitrogen at a molar concentration in the reaction mixture of greater than 2.5 mmol per kg of reaction mixture.
摘要翻译： 描述了制备二羧酸的方法。 更具体地描述了一种通过硝酸的作用制备己二酸（1,6-己二酸）的方法，该方法是在存在碳原子数的情况下，从作为相应化合物的环状酮或醇开始 的一种或多种氮氧化物，其反应混合物中摩尔浓度大于2.5mmol / kg反应混合物。
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3.发明授权Preparation of alkoxy- and/or halosilane (poly)sulfides and coupling agents comprised thereof 有权由其组成的烷氧基 - 和/或卤代硅烷（多）硫化物和偶联剂的制备公开(公告)号：US08273911B2
公开(公告)日：2012-09-25
申请号：US12514221
申请日：2007-11-09
申请人： Gérard Mignani , Samir Mansouri , Samuel Arthaud , Thierry Vidal
发明人： Gérard Mignani , Samir Mansouri , Samuel Arthaud , Thierry Vidal
IPC分类号： C07F7/04
CPC分类号： C07F7/1892 , C08K5/548 , C08L21/00
摘要： At least one (poly)thio alkoxy and/or halosilane is/are prepared by reaction of at least one sulfur-containing reagent with at least one alkoxy and/or halosilane, wherein an ionic addition of a sulfur-containing reagent to an alkoxy and/or halosilane is preferably conducted with thermal and/or actinic activation; the novel polythio alkoxy and/or halosilanes of formula (III.2) thus prepared are particularly useful as coupling agents in elastomeric compositions containing a white filler of the silica type and having the formula (III.2) wherein, for example, R1.1 and R1.3=methyl and R1.2=ethoxy.
摘要翻译： 通过使至少一种含硫试剂与至少一种烷氧基和/或卤代硅烷反应来制备至少一种（多）硫代烷氧基和/或卤代硅烷，其中含硫试剂与烷氧基的离子加成和 /或卤代硅烷优选用热和/或光化活化进行; 由此制备的式（III.2）的新型聚硫代烷氧基和/或卤代硅烷特别可用作含有二氧化硅类型的白色填料并具有式（III.2）的其中例如R 1的弹性体组合物中的偶联剂。 1和R1.3 =甲基，R1.2 =乙氧基。
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公开(公告)号：US20110162525A1
公开(公告)日：2011-07-07
申请号：US12994522
申请日：2009-05-14
申请人： Virginie Harle , Gérard Mignani
发明人： Virginie Harle , Gérard Mignani
IPC分类号： B01D53/02
CPC分类号： B01D53/02 , B01D2253/10 , B01D2257/504 , B01D2259/4009 , B01J20/28057 , B01J20/305 , B01J20/3078 , B01J20/3085 , Y02C10/08
摘要： A method for processing a CO2-containing gas in order to reduce the carbon dioxide content thereof, includes contacting the gas with a compound of at least one rare earth element, whereby the carbon dioxide is adsorbed onto the compound and a carbon dioxide-depleted gas is thus obtained; such compound is more particularly an oxide, and the rare earth element is particularly selected from among cerium, lanthanum or praseodymium.
摘要翻译： 一种用于处理含CO 2气体以减少其二氧化碳含量的方法包括使气体与至少一种稀土元素的化合物接触，由此二氧化碳被吸附到化合物和二氧化碳贫化气体 因此获得; 这种化合物更特别是氧化物，稀土元素特别选自铈，镧或镨。
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公开(公告)号：US06509023B1
公开(公告)日：2003-01-21
申请号：US09463677
申请日：2000-04-13
IPC分类号： A61K700
CPC分类号： A61Q17/04 , A61K8/585 , A61K8/891 , A61K8/895 , A61Q1/02 , A61Q1/06 , A61Q5/00 , A61Q13/00 , A61Q15/00
摘要： The invention concerns a cosmetic composition comprising a specific functionalized organopolysiloxane which is linear or cyclic. Said functionalized organopolysiloxane is used as emollient and/or carrier and/or anti-transfer agent in cosmetic compositions.
摘要翻译： 本发明涉及包含线性或环状的特定官能化有机聚硅氧烷的化妆品组合物。 所述官能化有机聚硅氧烷在化妆品组合物中用作润肤剂和/或载体和/或抗转移剂。
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6.发明授权Polyfunctional, perhalogenated polyorganosiloxanes and methods for preparation thereof 失效多官能，全卤代聚有机硅氧烷及其制备方法公开(公告)号：US06184329B2
公开(公告)日：2001-02-06
申请号：US08687044
申请日：1996-07-25
申请人： Philippe Jost , Philippe Karrer , Gérard Mignani , Philippe Olier
发明人： Philippe Jost , Philippe Karrer , Gérard Mignani , Philippe Olier
IPC分类号： C08G7724
CPC分类号： C08G77/382 , C08G77/385
摘要： Chemicaly stable, perflourinated, linear or cyclic polyorganosiloxanes (POS), and a process for the preparation thereof. Antifoams, agents for lowering surface tension, dirt repellents, antiadhesives, lubricants, oleophobic and/or hydrophobic agents, coatings and other compositions containing the perfluorinated POS are disclosed.
摘要翻译： 化学稳定的，全氟化的，直链或环状的聚有机硅氧烷（POS）及其制备方法。 公开了消泡剂，降低表面张力的试剂，防污剂，抗粘合剂，润滑剂，疏油和/或疏水剂，包含全氟化POS的涂料和其它组合物。
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公开(公告)号：US08623122B2
公开(公告)日：2014-01-07
申请号：US12994522
申请日：2009-05-14
申请人： Virginie Harle , Gérard Mignani
发明人： Virginie Harle , Gérard Mignani
IPC分类号： B01D53/02
CPC分类号： B01D53/02 , B01D2253/10 , B01D2257/504 , B01D2259/4009 , B01J20/28057 , B01J20/305 , B01J20/3078 , B01J20/3085 , Y02C10/08
摘要： A method for processing a CO2-containing gas in order to reduce the carbon dioxide content thereof, includes contacting the gas with a compound of at least one rare earth element, whereby the carbon dioxide is adsorbed onto the compound and a carbon dioxide-depleted gas is thus obtained; such compound is more particularly an oxide, and the rare earth element is particularly selected from among cerium, lanthanum or praseodymium.
摘要翻译： 一种用于处理含CO 2气体以减少其二氧化碳含量的方法包括使气体与至少一种稀土元素的化合物接触，由此二氧化碳被吸附到化合物和二氧化碳贫化气体 因此获得; 这种化合物更特别是氧化物，稀土元素特别选自铈，镧或镨。
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8.发明申请PREPARATION OF ALKOXY- AND/OR HALOSILANE (POLY)SULFIDES AND COUPLING AGENTS COMPRISED THEREOF 有权烷基和/或羧甲基纤维素（POLY）硫化物及其包含的偶联剂的制备公开(公告)号：US20100144959A1
公开(公告)日：2010-06-10
申请号：US12514221
申请日：2007-11-09
申请人： Gérard Mignani , Samir Mansouri , Samuel Arthaud , Thierry Vidal
发明人： Gérard Mignani , Samir Mansouri , Samuel Arthaud , Thierry Vidal
CPC分类号： C07F7/1892 , C08K5/548 , C08L21/00
摘要： At least one (poly)thio alkoxy and/or halosilane is/are prepared by reaction of at least one sulfur-containing reagent with at least one alkoxy and/or halosilane, wherein an ionic addition of a sulfur-containing reagent to an alkoxy and/or halosilane is preferably conducted with thermal and/or actinic activation; the novel polythio alkoxy and/or halosilanes of formula (III.2) thus prepared are particularly useful as coupling agents in elastomeric compositions containing a white filler of the silica type and having the formula (III.2) wherein, for example, R1.1 and R1.3=methyl and R1.2=ethoxy.
摘要翻译： 通过使至少一种含硫试剂与至少一种烷氧基和/或卤代硅烷反应来制备至少一种（多）硫代烷氧基和/或卤代硅烷，其中含硫试剂与烷氧基的离子加成和 /或卤代硅烷优选用热和/或光化活化进行; 由此制备的式（III.2）的新型聚硫代烷氧基和/或卤代硅烷特别可用作含有二氧化硅类型的白色填料并具有式（III.2）的其中例如R 1的弹性体组合物中的偶联剂。 1和R1.3 =甲基，R1.2 =乙氧基。
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9.发明授权Method for preparing functionalised polyorganosiloxane resins by redistribution in the presence of at least one triflic acid derivative 失效通过在至少一种三氟酸衍生物存在下再分配制备官能化聚有机硅氧烷树脂的方法公开(公告)号：US07402647B2
公开(公告)日：2008-07-22
申请号：US10509071
申请日：2003-03-20
申请人： Fernande Boisson , Gérard Mignani
发明人： Fernande Boisson , Gérard Mignani
IPC分类号： C08G77/08
摘要： The present invention relates to a process for preparing functionalized polyorganosiloxane (POS) resins comprising units M: (R3SiO1/2), Q: (SiO4/2) and M′: (YaR3-aSiO1/2) and optionally D: (R2SiO2/2) and/or D′: (RYSiO2/2) and T: (RSiO3/2) and/or T′: (YSiO3/2), with, in these units: R=C1-C10 alkyl or a C8-C12 aryl and Y a functional group (e.g.: Si—H),by redistribution of POS resins using POSf bearing functional units M′ and/or D′ and/or in the presence of an acid catalyst of the trifluoromethane-sulfonimide (TFSI) type.The present invention also relates to the aforementioned catalyst system.
摘要翻译： 本发明涉及一种制备官能化聚有机硅氧烷（POS）树脂的方法，其包括单元M：（R 3 SiO 1/2），Q：（SiO 4） / 2）和M'：（Y a a R 3-a SiO 1/2）和任选的D：（R 和/或D'：（RYSiO 2/2/2）和T：（RSiO 3/2/2） 和/或T'：（YSiO 3/2/2），在这些单元中：R = C 1 -C 10 - 通过使用POSf承载官能单元M'将POS树脂重新分配，通过重新分配POS树脂，以及Y为官能团（例如：Si-H） 和/或D'和/或在三氟甲烷 - 磺酰亚胺（TFSI）型的酸催化剂存在下进行。 本发明还涉及上述催化剂体系。
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10.发明授权Method for free radical reduction of dithiocarbonylated or dithiophosphorylated functions borne by a polymer 有权由聚合物自由基还原二硫代羰基化或二硫代磷酸化功能的方法公开(公告)号：US07109276B2
公开(公告)日：2006-09-19
申请号：US10475614
申请日：2002-05-03
申请人： Zofia Agnieszka Wilczewska , Mathias Destarac , Samir Zard , Chakib Kalai , Gérard Mignani , Hervé Adam
发明人： Zofia Agnieszka Wilczewska , Mathias Destarac , Samir Zard , Chakib Kalai , Gérard Mignani , Hervé Adam
IPC分类号： C08F4/44
CPC分类号： C08L53/00 , C08F2/38 , C08F8/04 , C08F293/005 , C08F2810/40 , C09D153/00 , C08L2666/02 , C08F120/06
摘要： The invention concerns a method for preparing a polymer, comprising a step which consists in contacting: (A) at least a living organic polymer having at its chain end a dithiocarbonylated or dithiophosphorylated function capable of being reactivated; (B) at least a source of free radicals; and (C) at least an organic compound bearing a labile hydrogen atom, whereby the dithiocarbonylated or dithiophosphorylated function present on said living organic polymer is substituted by a hydrogen atom.
摘要翻译： 本发明涉及一种制备聚合物的方法，其包括以下步骤：使（A）至少一种活性有机聚合物，其在其末端具有二硫代羰基化或二硫代磷酸化功能，其能够被再活化; （B）至少一个自由基来源; 和（C）至少一种具有不稳定氢原子的有机化合物，由此存在于所述活性有机聚合物上的二硫代羰基化或二硫代磷酸化官能团被氢原子取代。
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