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1.发明授权Method for making supported catalyst systems and catalyst systems therefrom 失效从其制备负载型催化剂体系和催化剂体系的方法
公开(公告)号：US5721184A
公开(公告)日：1998-02-24
申请号：US708136
申请日：1996-08-27
IPC分类号： C08F4/02 , C08F4/42 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/14 , C08F210/16
CPC分类号： C08F10/00 , C08F210/14 , C08F210/16 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： Catalyst systems and methods for supporting catalysts and their components, particularly metallocene catalyst components, are provided. The method involves techniques for evenly distributing a small volume of catalyst component over and among a porous support material. Such even distribution is thought to result in reduced fouling.
摘要翻译： 提供用于支持催化剂及其组分，特别是金属茂催化剂组分的催化剂体系和方法。 该方法涉及在多孔载体材料之上和之间均匀分布少量催化剂组分的技术。 这种均匀分布被认为会导致结垢减少。
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2.发明授权Method for making supported catalyst systems and catalyst systems therefrom 失效从其制备负载型催化剂体系和催化剂体系的方法
公开(公告)号：US5665665A
公开(公告)日：1997-09-09
申请号：US559928
申请日：1995-11-17
IPC分类号： C08F4/02 , C08F4/42 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F10/00 , C08F210/14 , C08F210/16 , B01J19/06
CPC分类号： C08F10/00 , C08F210/14 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61922 , Y10S502/503 , Y10S526/943
摘要： Catalyst systems and methods for supporting catalysts and their components, particularly metallocene catalyst components, are provided. The method involves teqhniques for evenly distributing a small volume of catalyst component over and among a porous support material. Such even distribution is thought to result in reduced fouling.
摘要翻译： 提供用于支持催化剂及其组分，特别是金属茂催化剂组分的催化剂体系和方法。 该方法涉及在多孔载体材料之上和之间均匀分布少量催化剂组分的方法。 这种均匀分布被认为会导致结垢减少。
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公开(公告)号：US6114479A
公开(公告)日：2000-09-05
申请号：US691848
申请日：1996-07-30
CPC分类号： C08F10/00 , C08F2410/02 , C08F4/61912 , C08F4/61916 , C08F4/61927 , Y10S526/943
摘要： This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported bulky ligand transition metal catalyst which when utilized in a polymerication process substantially reduces the reactor fouling and sheeting in a gas, slurry or liquid pool polymerization process.
摘要翻译： 本发明通常涉及用于聚合烯烃的负载型催化剂体系。 支持本发明的催化剂的方法提供了一种负载的大体积配体过渡金属催化剂，其在聚合过程中使用时，基本上减少了反应器在气体，浆液或液池聚合过程中的结垢和压片。
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公开(公告)号：US6087291A
公开(公告)日：2000-07-11
申请号：US959965
申请日：1997-10-24
申请人： Anthony Nicholas Speca , Jeffrey Lawrence Brinen , George Alan Vaughan , Patrick Brant , Terry John Burkhardt
发明人： Anthony Nicholas Speca , Jeffrey Lawrence Brinen , George Alan Vaughan , Patrick Brant , Terry John Burkhardt
IPC分类号： B01J31/00 , B01J37/00 , C08F4/02 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06
CPC分类号： C08F10/00 , C08F110/06 , C08F4/61912 , C08F4/61916 , C08F4/61927 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst system of the invention provides for a metallocene catalyst and alumoxane activator supported on a porous support using a total volume of catalyst solution that is less than that of which a slurry is formed. The metallocene and alumoxane aer mixed in solution, then the solution is added to a porous support in a volume between the total pore volume of the support and the volume at which a slurry forms. The solvent is then removed, leaving an activated supported metallocene.
摘要翻译： 本发明通常涉及用于聚合烯烃的负载型催化剂体系。 用于支撑本发明的催化剂体系的方法提供了使用小于形成浆料的催化剂溶液的总体积的负载在多孔载体上的茂金属催化剂和铝氧烷激活剂。 将金属茂和铝氧烷混合在溶液中，然后将溶液以支撑体的总孔体积和浆料形成的体积之间的体积加入到多孔载体中。 然后除去溶剂，留下活化的负载金属茂。
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公开(公告)号：US6124230A
公开(公告)日：2000-09-26
申请号：US502231
申请日：1995-07-13
CPC分类号： C08F10/00 , C08F2410/02 , C08F4/61912 , C08F4/61916 , C08F4/61927 , Y10S526/943
摘要： This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported bulky ligand transition metal catalyst which when utilized in a polymerization process substantially reduces the reactor fouling and sheeting in a gas, slurry or liquid pool polymerization process.
摘要翻译： 本发明通常涉及用于聚合烯烃的负载型催化剂体系。 用于支撑本发明的催化剂的方法提供了支撑的大体积配体过渡金属催化剂，当其用于聚合方法时，基本上减少了反应器在气体，浆液或液池聚合方法中的结垢和压片。
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公开(公告)号：US06806316B2
公开(公告)日：2004-10-19
申请号：US10303448
申请日：2002-11-25
申请人： Aspy Keki Mehta , Michael Chia-Chao Chen , Chon-Yie Lin , James John McAlpin , Anthony Nicholas Speca , Kelly Tormaschy
发明人： Aspy Keki Mehta , Michael Chia-Chao Chen , Chon-Yie Lin , James John McAlpin , Anthony Nicholas Speca , Kelly Tormaschy
IPC分类号： C08L2300
CPC分类号： C08J5/18 , C08F10/00 , C08F10/06 , C08F210/06 , C08F210/16 , C08F297/08 , C08J2323/10 , C08J2323/12 , C08L23/12 , C08L23/14 , C08L23/142 , C08L2205/02 , C08L2308/00 , C08L2314/02 , C08L2314/06 , Y10T428/24942 , C08F2/001 , C08L2666/06 , C08F2500/12 , C08F4/65904 , C08L2666/04 , C08F2500/15 , C08F2500/05 , C08F2500/03 , C08F2500/01 , C08F2500/26
摘要： This invention relates generally to crystalline polypropylene polymers and methods for their production. Specifically, this invention relates to crystalline polypropylene polymer compositions comprising both propylene homopolymers and propylene copolymers. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymers and copolymers using propylene with a small amount of comonomer, preferably ethylene. The resulting polymers are excellent for use in the production of biaxially oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional polypropylene polymers.
摘要翻译： 本发明一般涉及结晶聚丙烯聚合物及其生产方法。 具体地说，本发明涉及包含丙烯均聚物和丙烯共聚物的结晶聚丙烯聚合物组合物。 在聚合过程中使用包含至少两种金属茂的茂金属催化剂体系来制备组合物，该方法涉及使用丙烯与少量共聚单体，优选乙烯的丙烯均聚物和共聚物的顺序或平行聚合。 得到的聚合物非常适用于生产双轴取向膜。 用这些丙烯聚合物制备的膜具有显着更宽的加工性能范围，与传统聚丙烯聚合物制备的膜相比，可以在较低温度下均匀地拉伸。
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公开(公告)号：US07026040B2
公开(公告)日：2006-04-11
申请号：US10930477
申请日：2004-08-31
申请人： Aspy Keki Mehta , Michael Chia-Chao Chen , Chon-Yie Lin , James John Mcalpin , Anthony Nicholas Speca , Kelly Tormaschy
发明人： Aspy Keki Mehta , Michael Chia-Chao Chen , Chon-Yie Lin , James John Mcalpin , Anthony Nicholas Speca , Kelly Tormaschy
CPC分类号： C08J5/18 , C08F10/00 , C08F10/06 , C08F210/06 , C08F210/16 , C08F297/08 , C08J2323/10 , C08J2323/12 , C08L23/12 , C08L23/14 , C08L23/142 , C08L2205/02 , C08L2308/00 , C08L2314/02 , C08L2314/06 , Y10T428/24942 , C08F2/001 , C08L2666/06 , C08F2500/12 , C08F4/65904 , C08L2666/04 , C08F2500/15 , C08F2500/05 , C08F2500/03 , C08F2500/01 , C08F2500/26
摘要： This invention relates generally to films made from crystalline polypropylene polymers. Specifically, this invention relates to films comprising crystalline polypropylene polymer compositions containing both propylene homopolymers and propylene copolymers. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymers and copolymers using propylene with a small amount of comonomer, preferably ethylene. The resulting polymers are excellent for use in the production of biaxially oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional polypropylene polymers.
摘要翻译： 本发明一般涉及由结晶聚丙烯聚合物制成的薄膜。 具体地，本发明涉及包含含有丙烯均聚物和丙烯共聚物的结晶聚丙烯聚合物组合物的薄膜。 在聚合过程中使用包含至少两种金属茂的茂金属催化剂体系来制备组合物，该方法涉及使用丙烯与少量共聚单体，优选乙烯的丙烯均聚物和共聚物的顺序或平行聚合。 得到的聚合物非常适用于生产双轴取向膜。 用这些丙烯聚合物制备的膜具有显着更宽的加工性能范围，与传统聚丙烯聚合物制备的膜相比，可以在较低温度下均匀地拉伸。
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8.发明授权
公开(公告)号：US5688734A
公开(公告)日：1997-11-18
申请号：US710589
申请日：1996-09-19
IPC分类号： C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/656 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61927 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/904 , Y10S526/943
摘要： The invention relates to a supported, prepolymerized metallocene catalyst system as well as its production and use in olefin polymerization. The method for producing the prepolymerized catalyst system involves prepolymerizing a metallocene catalyst system containing a volume of solution that is the equivalent of or less than the total pore volume of the supported catalyst system.
摘要翻译： 本发明涉及负载的预聚合的茂金属催化剂体系，以及其在烯烃聚合中的生产和应用。 制备预聚合的催化剂体系的方法包括预聚合茂金属催化剂体系，所述茂金属催化剂体系含有等于或小于负载型催化剂体系总孔体积的溶液体积。
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公开(公告)号：US6013594A
公开(公告)日：2000-01-11
申请号：US71294
申请日：1998-04-29
IPC分类号： B01J31/06 , B01J32/00 , B01J37/00 , C08F4/02 , C08F4/64 , C08F10/00 , B01J31/00 , C08F4/44 , C08F4/60
CPC分类号： C08F10/00 , Y10S526/901 , Y10S526/943
摘要： This invention relates to catalyst supports made by spray drying an emulsion polymerized latex and the novel supported catalysts utilizing these supports. This invention further relates to a method for forming supported catalysts by spray drying a latex of microparticles containing catalyst or catalyst components. The polymizerable monomers used in the latex are e.g. styrenes, vinyl benzenes, vinyl cyclohexane and vinyl cyclohexene and can form homo- or copolymers which may be crosslinked. The catalysts supported include metallocenes as well as Ziegler-Natta catalysts. Processes of polymerizing olefins using such catalysts are also described.
摘要翻译： 本发明涉及通过喷雾干燥乳液聚合胶乳制得的催化剂载体和利用这些载体的新型载体催化剂。 本发明还涉及通过喷雾干燥含有催化剂或催化剂组分的微粒的胶乳形成负载型催化剂的方法。 在胶乳中使用的可聚合单体是例如。 苯乙烯，乙烯基苯，乙烯基环己烷和乙烯基环己烯，并且可以形成可以交联的均聚物或共聚物。 负载的催化剂包括金属茂以及齐格勒 - 纳塔催化剂。 还描述了使用这种催化剂聚合烯烃的方法。
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公开(公告)号：US6117955A
公开(公告)日：2000-09-12
申请号：US688344
申请日：1996-07-30
CPC分类号： C08F10/00 , C08F2410/02 , C08F4/61912 , C08F4/61916 , C08F4/6192
摘要： This invention is generally directed toward a supported catalyst system useful for polymerizing olefins. The method for supporting the catalyst of the invention provides for a supported metallocene catalyst which when utilized in a polymerization process substantially reduces reactor fouling and sheeting in a gas or slurry polymerization process.
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