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1.发明授权Method for making supported catalyst systems and catalyst systems therefrom 失效从其制备负载型催化剂体系和催化剂体系的方法
公开(公告)号：US5721184A
公开(公告)日：1998-02-24
申请号：US708136
申请日：1996-08-27
IPC分类号： C08F4/02 , C08F4/42 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/14 , C08F210/16
CPC分类号： C08F10/00 , C08F210/14 , C08F210/16 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： Catalyst systems and methods for supporting catalysts and their components, particularly metallocene catalyst components, are provided. The method involves techniques for evenly distributing a small volume of catalyst component over and among a porous support material. Such even distribution is thought to result in reduced fouling.
摘要翻译： 提供用于支持催化剂及其组分，特别是金属茂催化剂组分的催化剂体系和方法。 该方法涉及在多孔载体材料之上和之间均匀分布少量催化剂组分的技术。 这种均匀分布被认为会导致结垢减少。
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2.发明授权Method for making supported catalyst systems and catalyst systems therefrom 失效从其制备负载型催化剂体系和催化剂体系的方法
公开(公告)号：US5665665A
公开(公告)日：1997-09-09
申请号：US559928
申请日：1995-11-17
IPC分类号： C08F4/02 , C08F4/42 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F10/00 , C08F210/14 , C08F210/16 , B01J19/06
CPC分类号： C08F10/00 , C08F210/14 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61922 , Y10S502/503 , Y10S526/943
摘要： Catalyst systems and methods for supporting catalysts and their components, particularly metallocene catalyst components, are provided. The method involves teqhniques for evenly distributing a small volume of catalyst component over and among a porous support material. Such even distribution is thought to result in reduced fouling.
摘要翻译： 提供用于支持催化剂及其组分，特别是金属茂催化剂组分的催化剂体系和方法。 该方法涉及在多孔载体材料之上和之间均匀分布少量催化剂组分的方法。 这种均匀分布被认为会导致结垢减少。
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公开(公告)号：US06806316B2
公开(公告)日：2004-10-19
申请号：US10303448
申请日：2002-11-25
申请人： Aspy Keki Mehta , Michael Chia-Chao Chen , Chon-Yie Lin , James John McAlpin , Anthony Nicholas Speca , Kelly Tormaschy
发明人： Aspy Keki Mehta , Michael Chia-Chao Chen , Chon-Yie Lin , James John McAlpin , Anthony Nicholas Speca , Kelly Tormaschy
IPC分类号： C08L2300
CPC分类号： C08J5/18 , C08F10/00 , C08F10/06 , C08F210/06 , C08F210/16 , C08F297/08 , C08J2323/10 , C08J2323/12 , C08L23/12 , C08L23/14 , C08L23/142 , C08L2205/02 , C08L2308/00 , C08L2314/02 , C08L2314/06 , Y10T428/24942 , C08F2/001 , C08L2666/06 , C08F2500/12 , C08F4/65904 , C08L2666/04 , C08F2500/15 , C08F2500/05 , C08F2500/03 , C08F2500/01 , C08F2500/26
摘要： This invention relates generally to crystalline polypropylene polymers and methods for their production. Specifically, this invention relates to crystalline polypropylene polymer compositions comprising both propylene homopolymers and propylene copolymers. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymers and copolymers using propylene with a small amount of comonomer, preferably ethylene. The resulting polymers are excellent for use in the production of biaxially oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional polypropylene polymers.
摘要翻译： 本发明一般涉及结晶聚丙烯聚合物及其生产方法。 具体地说，本发明涉及包含丙烯均聚物和丙烯共聚物的结晶聚丙烯聚合物组合物。 在聚合过程中使用包含至少两种金属茂的茂金属催化剂体系来制备组合物，该方法涉及使用丙烯与少量共聚单体，优选乙烯的丙烯均聚物和共聚物的顺序或平行聚合。 得到的聚合物非常适用于生产双轴取向膜。 用这些丙烯聚合物制备的膜具有显着更宽的加工性能范围，与传统聚丙烯聚合物制备的膜相比，可以在较低温度下均匀地拉伸。
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公开(公告)号：US07026040B2
公开(公告)日：2006-04-11
申请号：US10930477
申请日：2004-08-31
申请人： Aspy Keki Mehta , Michael Chia-Chao Chen , Chon-Yie Lin , James John Mcalpin , Anthony Nicholas Speca , Kelly Tormaschy
发明人： Aspy Keki Mehta , Michael Chia-Chao Chen , Chon-Yie Lin , James John Mcalpin , Anthony Nicholas Speca , Kelly Tormaschy
CPC分类号： C08J5/18 , C08F10/00 , C08F10/06 , C08F210/06 , C08F210/16 , C08F297/08 , C08J2323/10 , C08J2323/12 , C08L23/12 , C08L23/14 , C08L23/142 , C08L2205/02 , C08L2308/00 , C08L2314/02 , C08L2314/06 , Y10T428/24942 , C08F2/001 , C08L2666/06 , C08F2500/12 , C08F4/65904 , C08L2666/04 , C08F2500/15 , C08F2500/05 , C08F2500/03 , C08F2500/01 , C08F2500/26
摘要： This invention relates generally to films made from crystalline polypropylene polymers. Specifically, this invention relates to films comprising crystalline polypropylene polymer compositions containing both propylene homopolymers and propylene copolymers. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymers and copolymers using propylene with a small amount of comonomer, preferably ethylene. The resulting polymers are excellent for use in the production of biaxially oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional polypropylene polymers.
摘要翻译： 本发明一般涉及由结晶聚丙烯聚合物制成的薄膜。 具体地，本发明涉及包含含有丙烯均聚物和丙烯共聚物的结晶聚丙烯聚合物组合物的薄膜。 在聚合过程中使用包含至少两种金属茂的茂金属催化剂体系来制备组合物，该方法涉及使用丙烯与少量共聚单体，优选乙烯的丙烯均聚物和共聚物的顺序或平行聚合。 得到的聚合物非常适用于生产双轴取向膜。 用这些丙烯聚合物制备的膜具有显着更宽的加工性能范围，与传统聚丙烯聚合物制备的膜相比，可以在较低温度下均匀地拉伸。
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5.发明授权
公开(公告)号：US5688734A
公开(公告)日：1997-11-18
申请号：US710589
申请日：1996-09-19
IPC分类号： C08F4/619 , C08F4/6192 , C08F4/642 , C08F4/656 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61927 , C08F4/65912 , C08F4/65916 , C08F4/65927 , Y10S526/904 , Y10S526/943
摘要： The invention relates to a supported, prepolymerized metallocene catalyst system as well as its production and use in olefin polymerization. The method for producing the prepolymerized catalyst system involves prepolymerizing a metallocene catalyst system containing a volume of solution that is the equivalent of or less than the total pore volume of the supported catalyst system.
摘要翻译： 本发明涉及负载的预聚合的茂金属催化剂体系，以及其在烯烃聚合中的生产和应用。 制备预聚合的催化剂体系的方法包括预聚合茂金属催化剂体系，所述茂金属催化剂体系含有等于或小于负载型催化剂体系总孔体积的溶液体积。
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6.发明授权Method for making supported catalyst systems and catalyst systems therefrom 失效从其制备负载型催化剂体系和催化剂体系的方法
公开(公告)号：US5625015A
公开(公告)日：1997-04-29
申请号：US461795
申请日：1995-06-05
IPC分类号： C08F4/02 , C08F4/42 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/642 , C08F10/00 , C08F210/14 , C08F210/16
CPC分类号： C08F10/00 , C08F210/14 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61922 , Y10S502/503 , Y10S526/943
摘要： Catalyst systems and methods for supporting catalysts and their components, particularly metallocene catalyst components, are provided. The method involves techniques for evenly distributing a small volume of catalyst component over and among a porous support material. Such even distribution is thought to result in reduced fouling.
摘要翻译： 提供用于支持催化剂及其组分，特别是金属茂催化剂组分的催化剂体系和方法。 该方法涉及在多孔载体材料之上和之间均匀分布少量催化剂组分的技术。 这种均匀分布被认为会导致结垢减少。
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公开(公告)号：US20050032983A1
公开(公告)日：2005-02-10
申请号：US10930477
申请日：2004-08-31
申请人： Aspy Mehta , Michael Chen , Chon-Yie Lin , James Mcalpin , Anthony Speca , Kelly Tormaschy
发明人： Aspy Mehta , Michael Chen , Chon-Yie Lin , James Mcalpin , Anthony Speca , Kelly Tormaschy
IPC分类号： C08F4/642 , C08F10/00 , C08F10/06 , C08F210/06 , C08F210/16 , C08F297/08 , C08J5/18 , C08L23/12 , C08L23/14 , C08L23/00
CPC分类号： C08J5/18 , C08F10/00 , C08F10/06 , C08F210/06 , C08F210/16 , C08F297/08 , C08J2323/10 , C08J2323/12 , C08L23/12 , C08L23/14 , C08L23/142 , C08L2205/02 , C08L2308/00 , C08L2314/02 , C08L2314/06 , Y10T428/24942 , C08F2/001 , C08L2666/06 , C08F2500/12 , C08F4/65904 , C08L2666/04 , C08F2500/15 , C08F2500/05 , C08F2500/03 , C08F2500/01 , C08F2500/26
摘要： This invention relates generally to films made from crystalline polypropylene polymers. Specifically, this invention relates to films comprising crystalline polypropylene polymer compositions containing both propylene homopolymers and propylene copolymers. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymers and copolymers using propylene with a small amount of comonomer, preferably ethylene. The resulting polymers are excellent for use in the production of biaxially oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional polypropylene polymers.
摘要翻译： 本发明一般涉及由结晶聚丙烯聚合物制成的薄膜。 具体地，本发明涉及包含含有丙烯均聚物和丙烯共聚物的结晶聚丙烯聚合物组合物的薄膜。 在聚合过程中使用包含至少两种金属茂的茂金属催化剂体系来制备组合物，该方法涉及使用丙烯与少量共聚单体，优选乙烯的丙烯均聚物和共聚物的顺序或平行聚合。 得到的聚合物非常适用于生产双轴取向膜。 用这些丙烯聚合物制备的膜具有显着更宽的加工性能范围，与传统聚丙烯聚合物制备的膜相比，可以在较低温度下均匀地拉伸。
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公开(公告)号：US06583227B2
公开(公告)日：2003-06-24
申请号：US09800238
申请日：2001-03-06
申请人： Aspy K. Mehta , Michael C. Chen , James J. McAlpin , Anthony N. Speca , Kelly Tormaschy , Chon Y. Lin
发明人： Aspy K. Mehta , Michael C. Chen , James J. McAlpin , Anthony N. Speca , Kelly Tormaschy , Chon Y. Lin
IPC分类号： C08L2314
CPC分类号： C08F10/00 , C08F10/06 , C08F210/06 , C08F210/16 , C08F297/08 , C08J5/18 , C08J2323/10 , C08J2323/12 , C08L23/12 , C08L23/142 , C08L2205/02 , C08L2308/00 , C08L2314/06 , Y10S526/943 , C08F4/65904 , C08F2/001 , C08L2666/04 , C08F2500/15 , C08F2500/05 , C08F2500/03 , C08F2500/01 , C08F2500/26 , C08F2500/12
摘要： This invention relates generally to crystalline propylene polymers, to methods for their production and to methods for their use in film applications. Specifically, this invention relates to crystalline propylene polymers comprising both propylene homopolymer and propylene copolymer. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymer and copolymer using propylene with a small amount of comonomer, preferably ethylene. The polymerization is catalyzed by a dual metallocene catalyst system. The resulting polymers have a broad, bimodal molecular weight distribution. The resulting polymers are excellent for use in the production of biaxially oriented films or non-oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional propylene polymer.
摘要翻译： 本发明一般涉及结晶丙烯聚合物，其制备方法及其用于膜应用的方法。 具体地说，本发明涉及包含丙烯均聚物和丙烯共聚物的结晶丙烯聚合物。 在聚合过程中使用包含至少两种金属茂的茂金属催化剂体系制备组合物，其涉及使用丙烯与少量共聚单体，优选乙烯的丙烯均聚物和共聚物的顺序或平行聚合。 聚合由双茂金属催化剂体系催化。 所得聚合物具有宽的双峰分子量分布。 所得聚合物非常适用于制备双轴取向膜或非取向膜。 用这些丙烯聚合物制备的膜具有显着更宽的加工性能范围，与传统丙烯聚合物制备的膜相比，可以在较低的温度下均匀地拉伸。
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公开(公告)号：US06576306B2
公开(公告)日：2003-06-10
申请号：US09800239
申请日：2001-03-06
申请人： Aspy K. Mehta , Michael C. Chen , James J. McAlpin , Anthony N. Speca , Kelly Tormaschy , Chon Y. Lin
发明人： Aspy K. Mehta , Michael C. Chen , James J. McAlpin , Anthony N. Speca , Kelly Tormaschy , Chon Y. Lin
IPC分类号： B32B108
CPC分类号： C08J5/18 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/00 , C08F10/06 , C08F210/06 , C08F210/16 , C08F297/08 , C08J2323/10 , C08J2323/12 , C08L23/12 , C08L23/142 , C08L2205/02 , C08L2308/00 , C08L2314/06 , Y10T428/1345 , Y10T428/1352 , C08F4/65904 , C08F2/001 , C08F2500/15 , C08F2500/05 , C08F2500/03 , C08F2500/01 , C08F2500/26 , C08L2666/04 , C08F2500/12
摘要： This invention relates generally to crystalline propylene polymers, to methods for their production and to methods for their use in film applications. Specifically, this invention relates to crystalline propylene polymers comprising both propylene homopolymer and propylene copolymer. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymer and copolymer using propylene with a small amount of comonomer, preferably ethylene. The polymerization is catalyzed by a dual metallocene catalyst system. The resulting polymers have a broad, bimodal molecular weight distribution. The resulting polymers are excellent for use in the production of biaxially oriented films or non-oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional propylene polymer.
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