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    Photographic film base comprising a poly(ethylene terephthalate)-based material
    1.
    发明授权
    Photographic film base comprising a poly(ethylene terephthalate)-based material 失效
    包含聚（对苯二甲酸乙二醇酯）基材料的照相胶片基材

    公开(公告)号：US06558884B1

    公开(公告)日：2003-05-06

    申请号：US10036668

    申请日：2001-12-21

    申请人： Jehuda Greener ,  Yuanqiao Rao ,  Dennis J. Massa ,  Yeh-Hung Lai

    发明人： Jehuda Greener ,  Yuanqiao Rao ,  Dennis J. Massa ,  Yeh-Hung Lai

    IPC分类号： G03C1795

    CPC分类号： G03C1/7954 ,  B41M5/41 ,  G03C1/498 ,  G03C5/16 ,  G03C2005/168

    摘要： This invention relates to a poly(ethylene terephthalate)-based photographic film base having improved properties with regard to cutting, perforating, and other finishing or phototofinishing operations. The film base comprises a material in which a specified amount of monomeric units derived from 1,4-cyclohexane dimethanol (CHDM), such that the film base has a specified cutting-related property. The level of CHDM in the PET-based polyester material can be adjusted either by physical blending of polyesters containing CHDM monomeric units or by synthetic incorporation of CHDM monomer units into a PET-based polyester backbone.

    摘要翻译： 本发明涉及基于聚对苯二甲酸乙二醇酯的照相胶片基材，其具有改进的关于切割，穿孔和其它整理或光固化作业的性能。 薄膜基材包括其中特定量的衍生自1,4-环己烷二甲醇（CHDM）的单体单元的材料，使得薄膜基材具有特定的切割相关性质。 PET基聚酯材料中CHDM的含量可以通过物理混合含有CHDM单体单元的聚酯或通过将CHDM单体单元合成并入PET基聚酯骨架中进行调节。

    Photographic film base comprising a poly(ethylene terephthalate)-based material
    3.
    发明授权
    Photographic film base comprising a poly(ethylene terephthalate)-based material 失效
    包含聚（对苯二甲酸乙二醇酯）基材料的照相胶片基材

    公开(公告)号：US06555303B1

    公开(公告)日：2003-04-29

    申请号：US10027023

    申请日：2001-12-21

    申请人： Yuanqiao Rao ,  Jehuda Greener ,  Yeh-Hung Lai

    发明人： Yuanqiao Rao ,  Jehuda Greener ,  Yeh-Hung Lai

    IPC分类号： G03C1795

    CPC分类号： G03C1/7954 ,  B41M5/41

    摘要： This invention relates to a poly(ethylene terephthalate)-based photographic film base having improved properties with regard to slitting, perforating, and other finishing or cutting operations. The film base comprises a polyester material in which a specified amount of monomer units derived from 1,4-cyclohexane dimethanol (CHDM), such that the film base has a specified cutting-related property. The level of CHDM can be adjusted in the PET-based polyester material either by physical blending of polyesters containing CHDM monomer units or by synthetic incorporation of CHDM monomer units into a PET-based polyester backbone.

    摘要翻译： 本发明涉及对于分切，穿孔和其它精加工或切割操作具有改进性能的聚（对苯二甲酸乙二醇酯）基照相胶片基材。 薄膜基材包括其中特定量的衍生自1,4-环己烷二甲醇（CHDM）的单体单元的聚酯材料，使得薄膜基料具有特定的切割相关性质。 通过物理混合含有CHDM单体单元的聚酯或通过合成将CHDM单体单元并入PET基聚酯主链，可以在PET基聚酯材料中调节CHDM的含量。

    Multi-layered compensation film using specified Tg material as a birefringent layer
    4.
    发明授权
    Multi-layered compensation film using specified Tg material as a birefringent layer 有权
    使用规定的Tg材料作为双折射层的多层补偿膜

    公开(公告)号：US07479309B2

    公开(公告)日：2009-01-20

    申请号：US11165090

    申请日：2005-06-23

    申请人： Jehuda Greener ,  James F. Elman ,  YuanQiao Rao ,  Jon A. Hammerschmidt ,  David B. Bailey

    发明人： Jehuda Greener ,  James F. Elman ,  YuanQiao Rao ,  Jon A. Hammerschmidt ,  David B. Bailey

    IPC分类号： G02F1/13363

    CPC分类号： G02F1/133634 ,  G02B5/3083 ,  Y10T428/1036 ,  Y10T428/1041

    摘要： A multilayer compensator includes one or more polymeric first layers and one or more polymeric second layers. The first layers comprise a polymer having an out-of-plane birefringence between −0.005 and +0.005. The second layers comprise an amorphous polymer having an out-of-plane birefringence that is either less than −0.005 or greater than +0.005. The overall in-plane retardation of the multilayer compensator is greater than 20 nm, and the out-of-plane retardation is more negative than −20 nm or more positive than +20 nm. The amorphous polymer of the second layer(s) has a glass transition temperature (Tg) such that 110° C.≦Tg≦180° C. when the Rth of the multilayer compensator is more negative than −20 nm, and 100° C.≦Tg≦160° C. when the Rth of the multilayer compensator is more positive than +20 nm.

    摘要翻译： 多层补偿器包括一个或多个聚合物第一层和一个或多个聚合物第二层。 第一层包括具有在-0.005和+0.005之间的面外双折射的聚合物。 第二层包括具有小于-0.005或大于+0.005的面外双折射的无定形聚合物。 多层补偿器的整体面内延迟大于20nm，并且面外延迟比+ 20nm的-20nm以上更加负。 当第二层的无定形聚合物的玻璃化转变温度（Tg）为110℃，Tg = 180℃，多层补偿器的Rth比-20nm更负，而100 当多层补偿器的Rth比+ 20nm更正时，<= Tg <= 160℃。

    Multi-layered compensation film using specified Tg material as a birefringent layer
    8.
    发明申请
    Multi-layered compensation film using specified Tg material as a birefringent layer 有权
    使用规定的Tg材料作为双折射层的多层补偿膜

    公开(公告)号：US20060153998A1

    公开(公告)日：2006-07-13

    申请号：US11165090

    申请日：2005-06-23

    申请人： Jehuda Greener ,  James Elman ,  YuanQiao Rao ,  Jon Hammerschmidt ,  David Bailey

    发明人： Jehuda Greener ,  James Elman ,  YuanQiao Rao ,  Jon Hammerschmidt ,  David Bailey

    IPC分类号： C09K19/00

    CPC分类号： G02F1/133634 ,  G02B5/3083 ,  Y10T428/1036 ,  Y10T428/1041

    摘要： A multilayer compensator includes one or more polymeric first layers and one or more polymeric second layers. The first layers comprise a polymer having an out-of-plane birefringence between −0.005 and +0.005. The second layers comprise an amorphous polymer having an out-of-plane birefringence that is either less than −0.005 or greater than +0.005. The overall in-plane retardation of the multilayer compensator is greater than 20 nm, and the out-of-plane retardation is more negative than −20 nm or more positive than +20 nm. The amorphous polymer of the second layer(s) has a glass transition temperature (Tg) such that 110° C.≦Tg≦180° C. when the Rth of the multilayer compensator is more negative than −20 nm, and 100° C.≦Tg≦160° C. when the Rth of the multilayer compensator is more positive than +20 nm.

    摘要翻译： 多层补偿器包括一个或多个聚合物第一层和一个或多个聚合物第二层。 第一层包括具有在-0.005和+0.005之间的面外双折射的聚合物。 第二层包括具有小于-0.005或大于+0.005的面外双折射的无定形聚合物。 多层补偿器的整体面内延迟大于20nm，并且面外延迟比+ 20nm的-20nm以上更加负。 第二层的无定形聚合物的玻璃化转变温度（Tg）为110℃，当多层补偿器的第<！ - SIPO < 当多层补偿器的第R个比+ 20nm更正时，<= Tg <= 160℃。

    Process for making polyester photographic film base and photographic element comprising said base
    9.
    发明授权
    Process for making polyester photographic film base and photographic element comprising said base 失效
    制造聚酯照相胶片基材和包含所述碱的照相元件的方法

    公开(公告)号：US06737226B1

    公开(公告)日：2004-05-18

    申请号：US10279891

    申请日：2002-10-24

    申请人： Yuanqiao Rao ,  Jehuda Greener ,  Michael R. Brickey

    发明人： Yuanqiao Rao ,  Jehuda Greener ,  Michael R. Brickey

    IPC分类号： G03C1765

    CPC分类号： C08J5/18 ,  B29C55/143 ,  B29K2067/00 ,  C08J2367/02 ,  G03C1/498 ,  G03C1/7954 ,  G03C5/14 ,  G03C5/16 ,  G03C5/17 ,  G03C2005/168 ,  Y10T428/31786

    摘要： A process for making polyester film base material comprising more than 65 mol % of 1,4-cyclohexanedimethanol (CHDM) of the total glycol component in the polyester material. The film base is prepared by sequentially carrying out the following steps: (a) casting a molten polyester resin in a machine direction onto a casting surface to form a continuous sheet, (b) drafting the sheet by stretching in the machine direction at a stretch ratio of from 2 to 4, and at a temperature ranging from 70° C. to 130° C., (c) tentering the sheet in the transverse direction by stretching at a stretch ratio of from 2 to 4, and at a temperature ranging from 70° C. to 130° C. to obtain a biaxially oriented film, (d) heat-setting the oriented film at an actual temperature of from 160° C. to 200° C., and (e) cooling the heat-set film without substantial detentering to obtain a biaxially oriented, heat-set polyester-based film having a cutting index of 1 to 1.5 and a tensile toughness ranging from 15 to 55 MPa. The invention is also directed towards a silver halide light sensitive photographic element comprising the PET-based film base made by the present process. The photographic film base of the invention exhibits excellent dimensional stability, optical clarity and mechanical strength while also possessing a crystalline morphology that enables finishing by cutting, chopping or perforating techniques at reduced cutting index without requiring a detentering step after heat-setting.

    摘要翻译： 一种制备聚酯薄膜基材的方法，其包含聚酯材料中总二醇组分的多于65mol％的1,4-环己烷二甲醇（CHDM）。 通过依次进行以下步骤制备薄膜基材：（a）在机器方向上将熔融聚酯树脂浇铸到铸造表面上以形成连续薄片，（b）通过在纵向上拉伸拉伸薄片 比例为2至4，温度范围为70℃至130℃，（c）通过以2至4的拉伸比拉伸并在温度范围内将片材横向拉伸 从70℃至130℃，得到双轴取向膜，（d）在160℃至200℃的实际温度下热定形取向膜，（e） 在没有显着的滞留的情况下获得具有1至1.5的切割指数和15至55MPa的拉伸韧性的双轴取向的热固性聚酯基薄膜。 本发明还涉及包含通过本方法制备的基于PET的薄膜基材的卤化银感光照相材料。 本发明的照相胶卷底片显示出优异的尺寸稳定性，光学透明度和机械强度，同时还具有能够以减小的切割指数通过切割，切割或穿孔技术进行精加工的结晶形态，而不需要在热定形之后的定向步骤。

    Optical compensation films produced by a carrier-web-casting process
    10.
    发明授权
    Optical compensation films produced by a carrier-web-casting process 有权
    通过载体网络铸造工艺生产的光学补偿膜

    公开(公告)号：US07713595B2

    公开(公告)日：2010-05-11

    申请号：US11254109

    申请日：2005-10-18

    申请人： Jehuda Greener ,  James F. Elman ,  Jon A. Hammerschmidt ,  Elizabeth K. Priebe

    发明人： Jehuda Greener ,  James F. Elman ,  Jon A. Hammerschmidt ,  Elizabeth K. Priebe

    IPC分类号： C09K19/00 ,  G02F1/1333 ,  G02F1/1335

    CPC分类号： G02F1/133634 ,  G02B5/3083 ,  Y10T428/10 ,  Y10T428/1005 ,  Y10T428/1036

    摘要： A method of forming an optical compensation film includes coating one or more first layers and one or more second layers onto a carrier substrate, and stretching the first layers and second layers simultaneously. The one or more first layers include a polymer having an out-of-plane birefringence (Δnth) not more negative than −0.005 and not more positive than +0.005, and the one or more second layers include a polymer having an out-of-plane birefringence more negative than −0.005 or more positive than +0.005. The overall in-plane retardation (Rin) of the optical compensation film is greater than 20 nm and the out-of-plane retardation (Rth) of the optical compensation film is more negative than −20 nm or more positive than +20 nm.

    摘要翻译： 形成光学补偿膜的方法包括将一个或多个第一层和一个或多个第二层涂覆到载体基底上，同时拉伸第一层和第二层。 一个或多个第一层包括具有不大于-0.005且不大于+0.005的正面的平面外双折射（＆Dgr; n）的聚合物，并且所述一个或多个第二层包括具有外部 - 平面双折射比-0.005或更大的正负值比+0.005更负。 光学补偿膜的整体面内延迟（Rin）大于20nm，并且光学补偿膜的面外延迟（Rth）比+20nm的-20nm以上更加负。