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    Curable phase change compositions and methods for using such compositions
    1.
    发明授权
    Curable phase change compositions and methods for using such compositions 有权
    固化相变组合物和使用这些组合物的方法

    公开(公告)号：US07538145B2

    公开(公告)日：2009-05-26

    申请号：US11289521

    申请日：2005-11-30

    申请人： Jennifer L. Belelie ,  Peter G. Odell ,  Darly Vanbesien ,  Marcel P. Breton

    发明人： Jennifer L. Belelie ,  Peter G. Odell ,  Darly Vanbesien ,  Marcel P. Breton

    IPC分类号： C08F2/50 ,  C09D4/00 ,  C09D11/10 ,  C09D11/12

    CPC分类号： C08F290/06 ,  C08F283/00 ,  C08F290/061 ,  C08F299/00 ,  C08G18/6715 ,  C08G18/73 ,  C09D4/00 ,  C09D11/101 ,  C09D11/34 ,  C09D175/16

    摘要： The phase change, curable composition comprises curable monomer, photoinitiator that initiates polymerization of the curable monomer, and phase change agent that provides the composition with an increase in viscosity of at least four orders of magnitude, from a first temperature, the first temperature being from 50° C. to 130° C., to a second temperature, the second temperature being from 0° C. to 70° C., wherein the second temperature is at least 10° C. below the first temperature. A coating over an image may be applied by providing a composition comprising curable monomer at a first temperature; applying the composition over the image, the image being at a second temperature; and exposing the composition to radiation to initiate polymerization of the curable monomer. In this process, the composition has a viscosity at the second temperature that is at least four orders of magnitude greater than its viscosity at the first temperature.

    摘要翻译： 相变可固化组合物包括可固化单体，引发可固化单体的聚合的光引发剂和从第一温度提供粘度增加至少四个数量级的组合物的相变剂，第一温度来自 50℃至130℃，至第二温度，第二温度为0℃至70℃，其中第二温度低于第一温度至少10℃。 可以通过在第一温度下提供包含可固化单体的组合物来施加图像上的涂层; 在所述图像上施加所述组合物，所述图像处于第二温度; 并将组合物暴露于辐射以引发可固化单体的聚合。 在该方法中，组合物在第二温度下具有比其在第一温度下的粘度大至少四个数量级的粘度。

    Radiation curable inks containing curable gelator additives
    10.
    发明授权
    Radiation curable inks containing curable gelator additives 有权
    含可固化凝胶剂添加剂的可辐射固化油墨

    公开(公告)号：US07459014B2

    公开(公告)日：2008-12-02

    申请号：US11034866

    申请日：2005-01-14

    申请人： Marcel P. Breton ,  Peter G. Odell ,  Christine E. Bedford ,  Jennifer L. Belelie ,  Jeffrey H. Banning

    发明人： Marcel P. Breton ,  Peter G. Odell ,  Christine E. Bedford ,  Jennifer L. Belelie ,  Jeffrey H. Banning

    IPC分类号： C09D11/00 ,  C09D11/10 ,  C08F2/46 ,  C08F2/50 ,  C08J3/28

    CPC分类号： C09D11/101

    摘要： An ink preferably used in piezoelectric ink jet devices includes an ink vehicle that includes at least one curable monomer, at least one polymerizable organic gelator, at least one initiator, at least one colorant and optionally at least one low molecular mass non-reactive organic gelator and/or at least one thermal solvent. The use of the curable gelator enables the ink to form a gel state having a viscosity of at least 102.5 cps at very low temperatures of about 30° C. to about 50° C. The ink may thus be jetted at low temperatures of about 50° C. to about 90° C. The ink is heated to a first temperature above the gel point of the ink, jetted onto a surface maintained at a second temperature at which the ink forms a gel state, and when on the image receiving substrate, is exposed to radiation energy to polymerize the polymerizable components of the ink.

    摘要翻译： 优选用于压电喷墨装置的油墨包括油墨载体，其包含至少一种可固化单体，至少一种可聚合有机胶凝剂，至少一种引发剂，至少一种着色剂和任选的至少一种低分子量非反应性有机胶凝剂 和/或至少一种热溶剂。 使用可固化胶凝剂使得油墨能够在约30℃至约50℃的非常低的温度下形成粘度至少为102.5cps的凝胶状态。因此，油墨可以在约50℃的低温下喷射 将油墨加热到高于墨水凝胶点的第一温度，喷射到保持在油墨形成凝胶状态的第二温度的表面上，并且当在图像接收基板上时 暴露于辐射能量以聚合油墨的可聚合组分。