公开(公告)号：US20120205286A1

公开(公告)日：2012-08-16

申请号：US13345041

申请日：2012-01-06

申请人： Jeremy FRANCIS ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

发明人： Jeremy FRANCIS ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

IPC分类号： C10G65/12 ,  B01J29/04 ,  C10G47/06

CPC分类号： B01J29/146 ,  B01J29/166 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/20 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G49/08 ,  C10G2300/301 ,  C10G2300/4018

摘要： Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g−1, and a crystal parameter a0 of the elemental mesh greater than 24.28 Å, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.

摘要翻译： 使用包含至少一种单独或混合使用的VIB族和非贵重族VIII的加氢脱氢元素的催化剂，以及包含至少一种多孔矿物基质和至少一种多孔矿物基质的载体来加氢裂化和/或加氢处理烃进料的方法 具有2.5至10的整体硅 - 铝原子比的脱铝USY沸石，相对于存在于沸石中的铝的总质量大于10％的网络外铝原子的重量百分比，测量的中孔体积 通过氮气孔隙度法大于0.07ml.g-1，并且元素网的晶体参数a0大于24.28，其中元素镍的量相对于沸石的总质量为0.5-3重量％ 沉积在所述USY沸石上，其中所述催化剂为硫化物形式。

公开(公告)号：US09914113B2

公开(公告)日：2018-03-13

申请号：US13345041

申请日：2012-01-06

申请人： Jeremy Francis ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

发明人： Jeremy Francis ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

IPC分类号： C10G45/12 ,  C10G47/06 ,  C10G65/12 ,  B01J29/04 ,  B01J29/14 ,  B01J29/16 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/20 ,  C10G49/08

CPC分类号： B01J29/146 ,  B01J29/166 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/20 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G49/08 ,  C10G2300/301 ,  C10G2300/4018

摘要： Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g−1, and a crystal parameter a0 of the elemental mesh greater than 24.28 Å, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.

公开(公告)号：US20050271582A1

公开(公告)日：2005-12-08

申请号：US11125339

申请日：2005-05-10

申请人： Eva Barea ,  Vicente Fornes ,  Avelino Corma ,  Patrick Bourges ,  Nicolas Bats ,  Emmanuelle Guillon

发明人： Eva Barea ,  Vicente Fornes ,  Avelino Corma ,  Patrick Bourges ,  Nicolas Bats ,  Emmanuelle Guillon

IPC分类号： C01B39/48 ,  C01B33/38 ,  C01B37/00 ,  C01B39/06 ,  C01B39/24 ,  C01B39/38 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  C01B39/20 ,  C01B39/26 ,  C01B39/40

CPC分类号： C01B39/06 ,  C01B33/38 ,  C01B37/005 ,  C01B39/065

摘要： The invention concerns a method for preparing a crystalline metalloaluminosilicate by direct synthesis using at least one source of aluminium and, as the source of silicon and as the source of at least one other metal M, at least one lamellar siliceous material containing metals in its framework. The invention also concerns the novel solids obtained, in particular solids with a given zeolitic structure containing particular metals in its zeolitic framework.

摘要翻译： 本发明涉及通过使用至少一种铝源和作为至少一种其它金属M的来源的硅作为至少一种其它金属M的源的直接合成来制备结晶金属铝硅酸盐的方法，至少一种在其框架中含有金属的层状硅质材料 。 本发明还涉及获得的新型固体，特别是具有在其沸石骨架中含有特定金属的给定沸石结构的固体。

公开(公告)号：US08101148B2

公开(公告)日：2012-01-24

申请号：US13178044

申请日：2011-07-07

申请人： Emmanuelle Guillon ,  Nicolas Bats ,  Antoine Fecant

发明人： Emmanuelle Guillon ,  Nicolas Bats ,  Antoine Fecant

IPC分类号： C01B33/32

CPC分类号： C01B33/38

摘要： Described is a process for the preparation of a crystallised lamellar solid formed by magadiite consisting of implementing in a step (i) mixing of at least one silica source, at least one salt of N,N,N′,N′-tetramethyl-N,N′-dibenzyloctanediammonium, at least one alkali and/or alkaline earth metal M and water and then implementing in a step (ii) hydrothermal treatment of said mixture until said crystallised lamellar solid constituted by magadiite is formed.

摘要翻译： 描述了制备由magadiite形成的结晶层状固体的方法，其包括在步骤（i）中混合至少一种二氧化硅源，至少一种N，N，N'，N'-四甲基-N ，N'-二苄基辛烷基铵，至少一种碱金属和/或碱土金属M和水，然后在步骤（ii）中实施所述混合物的水热处理，直到形成由magadiite构成的所述结晶的层状固体。

公开(公告)号：US20080159941A1

公开(公告)日：2008-07-03

申请号：US11956820

申请日：2007-12-14

申请人： Emmanuelle Guillon ,  Nicolas Bats ,  Antoine Fecant

发明人： Emmanuelle Guillon ,  Nicolas Bats ,  Antoine Fecant

IPC分类号： C01B33/26 ,  C01B33/32

CPC分类号： C01B33/38

摘要： Described is a process for the preparation of a crystallised lamellar solid formed by magadiite consisting of implementing in a step (i) mixing of at least one silica source, at least one salt of N,N,N′,N′-tetramethyl-N,N′-dibenzyloctanediammonium, at least one alkali and/or alkaline earth metal M and water and then implementing in a step (ii) hydrothermal treatment of said mixture until said crystallised lamellar solid constituted by magadiite is formed.

公开(公告)号：US20110268640A1

公开(公告)日：2011-11-03

申请号：US13178044

申请日：2011-07-07

申请人： Emmanuelle GUILLON ,  Nicolas Bats ,  Antoine Fecant

发明人： Emmanuelle GUILLON ,  Nicolas Bats ,  Antoine Fecant

IPC分类号： C01B33/32 ,  C01B33/26

CPC分类号： C01B33/38

摘要： Described is a process for the preparation of a crystallised lamellar solid formed by magadiite consisting of implementing in a step (i) mixing of at least one silica source, at least one salt of N,N,N′,N′-tetramethyl-N,N′-dibenzyloctanediammonium, at least one alkali and/or alkaline earth metal M and water and then implementing in a step (ii) hydrothermal treatment of said mixture until said crystallised lamellar solid constituted by magadiite is formed.

摘要翻译： 描述了制备由magadiite形成的结晶层状固体的方法，其包括在步骤（i）中混合至少一种二氧化硅源，至少一种N，N，N'，N'-四甲基-N ，N'-二苄基辛胺，至少一种碱金属和/或碱土金属M和水，然后在步骤（ii）中实施所述混合物的水热处理，直到形成由magadiite构成的所述结晶的层状固体。

公开(公告)号：US08021637B2

公开(公告)日：2011-09-20

申请号：US11956964

申请日：2007-12-14

申请人： Emmanuelle Guillon ,  Nicolas Bats ,  Antoine Fecant

发明人： Emmanuelle Guillon ,  Nicolas Bats ,  Antoine Fecant

IPC分类号： C01B33/32

CPC分类号： C01B33/38

摘要： Described is a process for the preparation of at least one crystallized lamellar solid formed by magadiite or kenyaite consisting of implementing in a step (i) mixing of at least one silica source, at least one organic structuring agent of the formula HO—(CH2)n—OH, with 2≦n≦5, at least one alkali and/or alkaline earth metal M and water and then implementing in a step (ii) hydrothermal treatment of said mixture until at least said crystallized lamellar solid is formed.

摘要翻译： 描述了由制备由magadiite或kenyaite形成的至少一种结晶的层状固体的方法，其包括在步骤（i）中混合至少一种二氧化硅源，至少一种式HO-（CH 2）的有机结构剂， n-OH，2和nlE; n和nl; 5，至少一种碱金属和/或碱土金属M和水，然后在步骤（ii）中实施所述混合物的水热处理，直到形成至少所述结晶的层状固体。

公开(公告)号：US07691355B2

公开(公告)日：2010-04-06

申请号：US11956820

申请日：2007-12-14

申请人： Emmanuelle Guillon ,  Nicolas Bats ,  Antoine Fecant

发明人： Emmanuelle Guillon ,  Nicolas Bats ,  Antoine Fecant

IPC分类号： C01B33/26 ,  C01B33/32

CPC分类号： C01B33/38

摘要： Described is a process for the preparation of a crystallised lamellar solid formed by magadiite consisting of implementing in a step (i) mixing of at least one silica source, at least one salt of N,N,N′,N′-tetramethyl-N,N′-dibenzyloctanediammonium, at least one alkali and/or alkaline earth metal M and water and then implementing in a step (ii) hydrothermal treatment of said mixture until said crystallised lamellar solid constituted by magadiite is formed.

摘要翻译： 描述了制备由magadiite形成的结晶层状固体的方法，其包括在步骤（i）中混合至少一种二氧化硅源，至少一种N，N，N'，N'-四甲基-N ，N'-二苄基辛烷基铵，至少一种碱金属和/或碱土金属M和水，然后在步骤（ii）中实施所述混合物的水热处理，直到形成由magadiite构成的所述结晶的层状固体。

公开(公告)号：US06921524B2

公开(公告)日：2005-07-26

申请号：US10792914

申请日：2004-03-05

申请人： Yannick Mathieu ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Nicolas Bats ,  Laurent Simon

发明人： Yannick Mathieu ,  Jean-Louis Paillaud ,  Philippe Caullet ,  Nicolas Bats ,  Laurent Simon

IPC分类号： C01B39/46 ,  C01B37/00 ,  C01B39/06 ,  C01B39/48

CPC分类号： C01B37/005 ,  C01B39/06

摘要： The invention concerns a crystalline solid, designated IM-10, which has the X ray diffraction diagram given below. Said solid has a chemical composition, expressed as the anhydrous base, in terms of moles of oxides, in accordance with the formula XO2:mYO2:pZ2O3:qR2/nO:sF, in which R represents one or more cation(s) with valency n, X represents one or more tetravalent element(s) other than germanium, Y represents germanium, Z represents at least one trivalent element and F is fluorine.

摘要翻译： 本发明涉及一种称为IM-10的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有以氧化物的摩尔数表示的无水碱的化学组成，根据式XO 2：mYO 2：pZ 2 其中R表示一个或多个具有化合价n的阳离子，X表示一个或多个四价基团 除锗以外的元素，Y表示锗，Z表示至少一个三价元素，F表示氟。

公开(公告)号：US20050058596A1

公开(公告)日：2005-03-17

申请号：US10902425

申请日：2004-07-30

申请人： Bogdan Harbuzaru ,  Jean-Louis Paillaud ,  Joel Patarin ,  Nicolas Bats ,  Laurent Simon ,  Catherine Laroche

发明人： Bogdan Harbuzaru ,  Jean-Louis Paillaud ,  Joel Patarin ,  Nicolas Bats ,  Laurent Simon ,  Catherine Laroche

IPC分类号： C07D498/08 ,  B01J20/06 ,  B01J20/10 ,  B01J20/18 ,  C01B37/00 ,  C01B39/48 ,  C01F7/00 ,  C01B33/36 ,  C01B39/00

CPC分类号： B01J20/10 ,  B01J20/06 ,  C01B37/005 ,  Y10S423/24

摘要： The invention concerns a IM-11 crystalline solid with structure type LTA, with a neutral framework, having a chemical composition expressed as the anhydrous base in terms of moles of oxide defined by the general formula XO2: mYO2:qR: sF, in which R represents one or more nitrogen-containing organic compounds, X represents one or more tetravalent elements other than germanium, Y represents germanium, F is fluorine, m, q, s represent the number of moles of YO2, R and F respectively, m is in the range 0.1 to 4, and q and s are in the range 0 to 1.

摘要翻译： 本发明涉及结构类型为LTA的IM-11结晶固体，具有中性骨架，其化学组成以无水碱表示，以通式XO2：mYO2：qR：sF所定义的氧化物的摩尔数表示，其中R 表示一种或多种含氮有机化合物，X表示一种或多种除锗以外的四价元素，Y表示锗，F表示氟，m，q表示分别为YO 2，R和F的摩尔数，m为 范围为0.1〜4，q和s为0〜1。