公开(公告)号：US20120205286A1

公开(公告)日：2012-08-16

申请号：US13345041

申请日：2012-01-06

申请人： Jeremy FRANCIS ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

发明人： Jeremy FRANCIS ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

IPC分类号： C10G65/12 ,  B01J29/04 ,  C10G47/06

CPC分类号： B01J29/146 ,  B01J29/166 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/20 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G49/08 ,  C10G2300/301 ,  C10G2300/4018

摘要： Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g−1, and a crystal parameter a0 of the elemental mesh greater than 24.28 Å, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.

摘要翻译： 使用包含至少一种单独或混合使用的VIB族和非贵重族VIII的加氢脱氢元素的催化剂，以及包含至少一种多孔矿物基质和至少一种多孔矿物基质的载体来加氢裂化和/或加氢处理烃进料的方法 具有2.5至10的整体硅 - 铝原子比的脱铝USY沸石，相对于存在于沸石中的铝的总质量大于10％的网络外铝原子的重量百分比，测量的中孔体积 通过氮气孔隙度法大于0.07ml.g-1，并且元素网的晶体参数a0大于24.28，其中元素镍的量相对于沸石的总质量为0.5-3重量％ 沉积在所述USY沸石上，其中所述催化剂为硫化物形式。

公开(公告)号：US09914113B2

公开(公告)日：2018-03-13

申请号：US13345041

申请日：2012-01-06

申请人： Jeremy Francis ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

发明人： Jeremy Francis ,  Laurent Simon ,  Emmanuelle Guillon ,  Nicolas Bats ,  Avelino Corma ,  Christophe Pichon

IPC分类号： C10G45/12 ,  C10G47/06 ,  C10G65/12 ,  B01J29/04 ,  B01J29/14 ,  B01J29/16 ,  B01J35/00 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  B01J37/20 ,  C10G49/08

CPC分类号： B01J29/146 ,  B01J29/166 ,  B01J35/002 ,  B01J35/0066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0205 ,  B01J37/20 ,  B01J2229/14 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/36 ,  B01J2229/37 ,  B01J2229/38 ,  B01J2229/42 ,  C10G49/08 ,  C10G2300/301 ,  C10G2300/4018

摘要： Process for hydrocracking and/or hydrotreatment of hydrocarbon feeds utilizing a catalyst comprising at least one hydro-dehydrogenating element of group VIB and of non-precious group VIII used alone or mixed, and a support comprising at least one porous mineral matrix and at least one dealuminated USY zeolite having an overall silicon-to-aluminium atomic ratio comprised between 2.5 and 10, a fraction by weight of extra-network aluminium atom greater than 10% relative to the total mass of the aluminium present in the zeolite, a mesopore volume measured by nitrogen porosimetry greater than 0.07 ml.g−1, and a crystal parameter a0 of the elemental mesh greater than 24.28 Å, in which a quantity of the element nickel comprised between 0.5 and 3% by weight relative to the total mass of the zeolite is deposited on said USY zeolite and in which said catalyst is in the sulphide form.

公开(公告)号：US20050271582A1

公开(公告)日：2005-12-08

申请号：US11125339

申请日：2005-05-10

申请人： Eva Barea ,  Vicente Fornes ,  Avelino Corma ,  Patrick Bourges ,  Nicolas Bats ,  Emmanuelle Guillon

发明人： Eva Barea ,  Vicente Fornes ,  Avelino Corma ,  Patrick Bourges ,  Nicolas Bats ,  Emmanuelle Guillon

IPC分类号： C01B39/48 ,  C01B33/38 ,  C01B37/00 ,  C01B39/06 ,  C01B39/24 ,  C01B39/38 ,  B01J29/08 ,  B01J29/18 ,  B01J29/40 ,  C01B39/20 ,  C01B39/26 ,  C01B39/40

CPC分类号： C01B39/06 ,  C01B33/38 ,  C01B37/005 ,  C01B39/065

摘要： The invention concerns a method for preparing a crystalline metalloaluminosilicate by direct synthesis using at least one source of aluminium and, as the source of silicon and as the source of at least one other metal M, at least one lamellar siliceous material containing metals in its framework. The invention also concerns the novel solids obtained, in particular solids with a given zeolitic structure containing particular metals in its zeolitic framework.

摘要翻译： 本发明涉及通过使用至少一种铝源和作为至少一种其它金属M的来源的硅作为至少一种其它金属M的源的直接合成来制备结晶金属铝硅酸盐的方法，至少一种在其框架中含有金属的层状硅质材料 。 本发明还涉及获得的新型固体，特别是具有在其沸石骨架中含有特定金属的给定沸石结构的固体。

公开(公告)号：US20060100471A1

公开(公告)日：2006-05-11

申请号：US11269531

申请日：2005-11-09

申请人： Jose' Serra Alfaro ,  Avelino Corma ,  Emmanuelle Guillon

发明人： Jose' Serra Alfaro ,  Avelino Corma ,  Emmanuelle Guillon

IPC分类号： C07C15/12

CPC分类号： C07C6/126 ,  C07C2529/44 ,  C07C2529/80 ,  C07C15/08

摘要： A process for transalkylation of an alkyl-aromatic hydrocarbon feedstock that has at least 9 carbon atoms per molecule that comprises a) the introduction of said alkyl-aromatic hydrocarbon feedstock at the inlet of a first reaction zone where it is brought into contact with at least a first zeolitic catalyst, b) the introduction of at least a portion of the effluent that is obtained from stage a) and a feedstock that contains benzene and/or toluene at the inlet of a second reaction zone that contains at least a second zeolitic catalyst, and c) the separation of at least a portion of the effluent that is obtained from stage b) is described.

公开(公告)号：US20050234279A1

公开(公告)日：2005-10-20

申请号：US11104622

申请日：2005-04-13

申请人： Jose Serra ,  Avelino Corma ,  Emmanuelle Guillon

发明人： Jose Serra ,  Avelino Corma ,  Emmanuelle Guillon

IPC分类号： B01J23/36 ,  B01J29/18 ,  B01J29/26 ,  B01J29/40 ,  B01J29/48 ,  B01J29/70 ,  B01J29/78 ,  B01J29/80 ,  B01J35/00 ,  B01J37/00 ,  B01J37/04 ,  B01J37/20 ,  C07B61/00 ,  C07C6/12 ,  C07C15/04 ,  C07C15/08 ,  C07C5/22 ,  B01J29/06

CPC分类号： B01J29/80 ,  B01J29/18 ,  B01J29/185 ,  B01J29/26 ,  B01J29/40 ,  B01J29/405 ,  B01J29/48 ,  B01J29/70 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/78 ,  B01J29/7815 ,  B01J35/0006 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C07C6/126

摘要： A catalyst is described which comprises at least one zeolite with channels with openings defined by a ring having 10 oxygen atoms (10 MR), at least one zeolite with at least channels or side pockets with openings defined by a ring having 12 oxygen atoms (12 MR), at least one metal selected from the group constituted by group IIIA and VIIB metals and at least one porous mineral matrix. Said catalyst optionally also contains at least one metal selected from the group constituted by group IVA and VIB metals. The catalyst of the invention is used in a process for the transalkylation of alkylaromatic hydrocarbons such as toluene or benzene and alkylaromatics containing at least 9 carbon atoms.

摘要翻译： 描述了一种催化剂，其包含至少一种沸石，其通道具有由具有10个氧原子的环（10MR）限定的开口，至少一种具有至少通道或侧袋的沸石，其具有由具有12个氧原子的环（12 MR），选自由IIIA和VIIB族金属构成的组中的至少一种金属和至少一种多孔矿物基质。 所述催化剂任选地还含有选自由IVA族和VIB族金属构成的族群中的至少一种金属。 本发明的催化剂用于烷基芳族烃如甲苯或苯的烷基转移和含有至少9个碳原子的烷基芳族化合物的方法。

公开(公告)号：US07025948B2

公开(公告)日：2006-04-11

申请号：US11102879

申请日：2005-04-11

申请人： Eva Barea ,  Vicente Fornes ,  Avelino Corma ,  Patrick Bourges ,  Emmanuelle Guillon

发明人： Eva Barea ,  Vicente Fornes ,  Avelino Corma ,  Patrick Bourges ,  Emmanuelle Guillon

IPC分类号： C01B39/48

CPC分类号： C01B37/005 ,  C01B39/06

摘要： The invention concerns a crystalline solid, designated ITQ-31, which has the X ray diffraction diagram given below. Said solid has a chemical composition, expressed as the anhydrous base in terms of moles of oxide, defined by the general formula XO2: mYO2:pZ2O3:qR:sF, in which R represents an organic nitrogen-containing template, X represents one or more tetravalent elements other than germanium, Y represents germanium, Z represents at least one trivalent element and F is fluorine.

摘要翻译： 本发明涉及一种称为ITQ-31的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有以通式XO 2定义的氧化物摩尔数表示为无水碱的化学组成：mYO 2：pZ 2 qR：sF，其中R表示有机含氮模板，X表示一种或多种除锗以外的四价元素，Y表示锗，Z表示至少一种三价元素 F是氟。

公开(公告)号：US20050244330A1

公开(公告)日：2005-11-03

申请号：US11102879

申请日：2005-04-11

申请人： Eva Barea ,  Vicente Fornes ,  Avelino Corma ,  Patrick Bourges ,  Emmanuelle Guillon

发明人： Eva Barea ,  Vicente Fornes ,  Avelino Corma ,  Patrick Bourges ,  Emmanuelle Guillon

IPC分类号： C01B39/46 ,  C01B37/00 ,  C01B39/06 ,  C01B39/48

CPC分类号： C01B37/005 ,  C01B39/06

摘要： The invention concerns a crystalline solid, designated ITQ-31, which has the X ray diffraction diagram given below. Said solid has a chemical composition, expressed as the anhydrous base in terms of moles of oxide, defined by the general formula XO2: mYO2:pZ2O3:qR:sF, in which R represents an organic nitrogen-containing template, X represents one or more tetravalent elements other than germanium, Y represents germanium, Z represents at least one trivalent element and F is fluorine.

摘要翻译： 本发明涉及一种称为ITQ-31的结晶固体，其具有以下给出的X射线衍射图。 所述固体具有以通式XO 2定义的氧化物摩尔数表示为无水碱的化学组成：mYO 2：pZ 2 qR：sF，其中R表示有机含氮模板，X表示一种或多种除锗以外的四价元素，Y表示锗，Z表示至少一种三价元素 F是氟。

公开(公告)号：US07629499B2

公开(公告)日：2009-12-08

申请号：US11269531

申请日：2005-11-09

申请人： José Manuel Serra Alfaro ,  Avelino Corma ,  Emmanuelle Guillon

发明人： José Manuel Serra Alfaro ,  Avelino Corma ,  Emmanuelle Guillon

IPC分类号： C07C6/12

CPC分类号： C07C6/126 ,  C07C2529/44 ,  C07C2529/80 ,  C07C15/08

摘要： A process for transalkylation of an alkyl-aromatic hydrocarbon feedstock that has at least 9 carbon atoms per molecule that comprises a) the introduction of said alkyl-aromatic hydrocarbon feedstock at the inlet of a first reaction zone where it is brought into contact with at least a first zeolitic catalyst, b) the introduction of at least a portion of the effluent that is obtained from stage a) and a feedstock that contains benzene and/or toluene at the inlet of a second reaction zone that contains at least a second zeolitic catalyst, and c) the separation of at least a portion of the effluent that is obtained from stage b) is described.

摘要翻译： 每个分子具有至少9个碳原子的烷基 - 芳族烃原料的烷基转移的方法，其包括a）在第一反应区的入口处引入所述烷基 - 芳烃原料至少与其接触 第一沸石催化剂，b）引入至少一部分从步骤a）获得的流出物和在含有至少第二沸石催化剂的第二反应区的入口处含有苯和/或甲苯的原料 ，和c）描述了从阶段b）获得的至少一部分流出物的分离。

公开(公告)号：US07314843B2

公开(公告)日：2008-01-01

申请号：US11045469

申请日：2005-01-31

申请人： Eva Barea ,  Vicente Fornes ,  Avelino Corma ,  Patrick Bourges ,  Emmanuelle Guillon

发明人： Eva Barea ,  Vicente Fornes ,  Avelino Corma ,  Patrick Bourges ,  Emmanuelle Guillon

IPC分类号： B01J21/16 ,  C01B33/20 ,  C01B33/24

CPC分类号： B01J29/049 ,  C01B33/38 ,  C01B33/44

摘要： The invention relates to a process for synthesis of lamellar solids based on silicates comprising: i) a mixing stage, during which a mixture that comprises an alkaline metal, a silica source, water and an organic structuring agent is prepared, and ii) a crystallization stage during which this mixture is kept under conditions allowing the formation of a crystalline solid. The organic structuring agent that is used in this process comprises an alcohol group and an amine group that are separated by a hydrocarbon chain.

摘要翻译： 本发明涉及一种基于硅酸盐的层状固体的合成方法，其包括：i）混合阶段，其中制备包含碱金属，二氧化硅源，水和有机结构剂的混合物，和ii）结晶 其中将该混合物保持在允许形成结晶固体的条件下。 在该方法中使用的有机结构剂包括被烃链分离的醇基和胺基。

公开(公告)号：US07029642B2

公开(公告)日：2006-04-18

申请号：US11071582

申请日：2005-03-04

申请人： Eva Barea ,  Patrick Bourges ,  Emmanuelle Guillon ,  Patrick Euzen ,  Vicente Fornes ,  Avelino Corma

发明人： Eva Barea ,  Patrick Bourges ,  Emmanuelle Guillon ,  Patrick Euzen ,  Vicente Fornes ,  Avelino Corma

IPC分类号： C01B33/38

CPC分类号： C01B39/48 ,  B01J29/04 ,  B01J29/70 ,  B01J29/74 ,  B01J29/89 ,  C01B37/005 ,  C01B37/02 ,  C01B39/08 ,  C01B39/085 ,  C10G49/08

摘要： The invention concerns a novel crystalline solid UVL-1 which has an X ray diffraction diagram containing at least the following characteristic peaks: dhkl (A)2theta (°)I/I0 11.697.55mw to vs 7.5011.79vw to w 5.7615.36w to mw 3.7024.00m to s 3.5724.91s 3.3626.49vs 3.1428.48w to mw 2.5035.88vw 2.4137.30vw and with a chemical composition, expressed as the anhydrous compound, in terms of moles of oxide: (XO2):(Y2O3)m:(Z2/nO)p in which: X represents at least one tetravalent element selected from the group formed by Si, Ge; Y represents at least one trivalent element selected from Al, B, Cr, Ga; Z represents at least one cation with valency n; and in which: n is in the range 2 to 4, m is in the range 0 to 0.2, preferably in the range 0 to 0.05, and p is in the range 0 to 0.2, preferably in the range 0 to 0.05. The invention also concerns a hydrocracking/hydroconversion process and a hydrorefining process employing said solid in the catalyst composition.