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    Flexible polyurethane foams which exhibit excellent flame resistance
    1.
    发明授权
    Flexible polyurethane foams which exhibit excellent flame resistance 失效
    具有优异阻燃性的柔性聚氨酯泡沫

    公开(公告)号：US4722942A

    公开(公告)日：1988-02-02

    申请号：US19904

    申请日：1987-02-27

    申请人： Jerram B. Nichols ,  Hans R. Friedli ,  Stephen R. Burks

    发明人： Jerram B. Nichols ,  Hans R. Friedli ,  Stephen R. Burks

    IPC分类号： C08G18/38 ,  C08G18/65 ,  C08G18/32

    CPC分类号： C08G18/3823 ,  C08G18/6523

    摘要： This invention is an active hydrogen-containing composition suitable for the production of flexible polyurethane foam when reacted with a polyisocyanate, said composition comprising,(a) a polyol having an average functionality of about 2.0 to about 4.0, having at least about 50% of its active hydroxyl groups in the form of primary hydroxyl groups, and an equivalent weight from about 500 to about 5000;(b) from about 0.5 to about 5 parts, per 100 parts by weight of component (a) of a crosslinker selected from the group consisting of monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, methylene bis(o-chloroaniline) and mixtures thereof; and(c) at least about 0.15 equivalent per equivalent of (a) and (b), of a polyfunctional flame retarding additive having an equivalent weight of less than about 300, which flame retarding additive is selected from the group consisting of (i) hydroxyl-terminated alkanes having a plurality of primary hydroxyl groups, (ii) alkylene ethers and polyethers having a plurality of primary hydroxyl groups, (iii) polyurea compounds having at least 2 hydroxyalkyl groups which are attached to a urea nitrogen atom, (iv) polycarbamates having a plurality of primary hydroxyl groups or a plurality of primary hydroxyalkyl groups attached to a tertiary nitrogen atoms.Foams prepared from this active hydrogen-containing composition have excellent burn properties, as determined by tests described herein, as well as good physical properties.

    摘要翻译： 本发明是一种适用于在与多异氰酸酯反应时生产柔性聚氨酯泡沫的活性含氢组合物，所述组合物包含（a）平均官能度为约2.0至约4.0的多元醇，其具有至少约50％ 其活性羟基为伯羟基，当量为约500至约5000; （a）交联剂的组分（a）为约0.5至约5份，选自单乙醇胺，二乙醇胺，三乙醇胺，单异丙醇胺，二异丙醇胺，亚甲基双（邻氯苯胺）及其混合物 ; 和（c）当量重量小于约300的多官能阻燃添加剂中每当量（a）和（b））至少约0.15当量，该阻燃添加剂选自（i） 具有多个伯羟基的羟基封端的烷烃，（ii）具有多个伯羟基的亚烷基醚和聚醚，（iii）与脲氮原子连接的具有至少2个羟烷基的聚脲化合物，（iv） 具有多个伯羟基的多氨基甲酸盐或与叔氮原子连接的多个伯羟基烷基。 由该活性含氢组合物制备的泡沫体具有优异的燃烧性能，如通过本文所述的测试确定的，以及良好的物理性能。

    PROCESS FOR MAKING LOW DENSITY HIGH RESILIENCY FLEXIBLE POLYURETHANE FOAM
    2.
    发明申请
    PROCESS FOR MAKING LOW DENSITY HIGH RESILIENCY FLEXIBLE POLYURETHANE FOAM 有权
    制造低密度高弹性柔性聚氨酯泡沫的方法

    公开(公告)号：US20130184368A1

    公开(公告)日：2013-07-18

    申请号：US13876620

    申请日：2010-12-07

    申请人： Issam Lazraq ,  Helmut Stegt ,  Allan James ,  Stephen R. Burks

    发明人： Issam Lazraq ,  Helmut Stegt ,  Allan James ,  Stephen R. Burks

    IPC分类号： C08J9/12

    CPC分类号： C08J9/125 ,  C08G18/482 ,  C08G18/4841 ,  C08G18/4866 ,  C08G18/5021 ,  C08G2101/0008 ,  C08J9/02 ,  C08J2205/06 ,  C08J2375/08

    摘要： A process for producing resilient, flexible polyurethane foams that function well in noise and vibration absorption applications for vehicle applications that are made from a blend of polyols (i) and an isocyanate (ii), wherein the blend of polyols (i) comprises a mixture of polyether polyols (i.a) that each has a hydroxyl equivalent weight of from 1200 to 3000 and at least 70% primary hydroxyl groups, from 5 to 80% by weight of the ethylene oxide-capped polypropylene oxides are nominally difunctional, from 0.5 to 20% by weight of the ethylene oxide-capped polypropylene oxides have a nominal functionality of four or higher, and the balance of the ethylene oxide-capped polypropylene oxides, but not less than 1.5% by weight thereof, are nominally trifunctional; an autocatalytic polyol (i.b) having a functionality in the range of 2 to 8 and a hydroxyl number in the range of 15 to 200, wherein said autocatalytic polyol compound comprising at least one tertiary amine group; and a low unsaturation polyol (i.c) having a functionality equal to or greater than 2, a hydroxyl equivalent weight of from 1800 to 2800, and a total unsaturation value of equal to or less than 0.06 meq/g.

    摘要翻译： 一种用于生产由多元醇（i）和异氰酸酯（ii）的共混物制成的车辆应用的噪声和振动吸收应用中良好的弹性，柔性聚氨酯泡沫体的方法，其中多元醇（i）的共混物包含混合物 的聚醚多元醇（ia），其各自具有1200至3000的羟基当量和至少70％的伯羟基，5至80重量％的环氧乙烷封端的聚环氧丙烷名义上为双官能的，为0.5至20 环氧乙烷封端的聚环氧丙烷的重量％具有四个或更高的标称官能度，其余的环氧乙烷封端的聚丙烯氧化物，但不小于1.5重量％，其名义上是三官能的; 官能度为2〜8，羟值在15〜200范围内的自催化多元醇（i.b），其中所述自催化多元醇化合物包含至少一个叔胺基团; 和低不饱和多元醇（i.c），其官能度等于或大于2，羟基当量为1800至2800，总不饱和度值等于或小于0.06meq / g。

    METHOD FOR MAKING LOW DENSITY POLYURETHANE FOAM FOR SOUND AND VIBRATION ABSORPTION
    3.
    发明申请
    METHOD FOR MAKING LOW DENSITY POLYURETHANE FOAM FOR SOUND AND VIBRATION ABSORPTION 有权
    制造低密度聚氨酯泡沫用于声音和振动吸收的方法

    公开(公告)号：US20120259029A1

    公开(公告)日：2012-10-11

    申请号：US13514180

    申请日：2010-12-07

    申请人： Helmut Stegt ,  Allan James ,  Stephen R. Burks ,  Jason A. Reese ,  David J. Honkomp

    发明人： Helmut Stegt ,  Allan James ,  Stephen R. Burks ,  Jason A. Reese ,  David J. Honkomp

    IPC分类号： C08J9/228 ,  C09K3/00

    CPC分类号： C08G65/2609 ,  C08G18/4812 ,  C08G2101/0008 ,  C08G2650/24

    摘要： Flexible polyurethane foams that function well in noise and vibration absorption applications are made from a mixture of polyether polyols oxides that each has a hydroxyl equivalent weight of from 1200 to 3000 and at least 70% primary hydroxyl groups. From 5 to 80% by weight of the ethylene oxide-capped polypropylene oxides are nominally difunctional, from 0.5 to 20% by weight of the ethylene oxide-capped polypropylene oxides have a nominal functionality of four or higher, and the balance of the ethylene oxide-capped polypropylene oxides, but not less than 1.5% by weight thereof, are nominally trifunctional.

    摘要翻译： 在噪声和振动吸收应用中功能良好的柔性聚氨酯泡沫体由聚醚多元醇氧化物的混合物制成，其各自具有1200至3000的羟基当量和至少70％的伯羟基。 环氧乙烷封端的聚环氧丙烷的5至80重量％通常是双官能的，0.5至20重量％的环氧乙烷封端的聚环氧丙烷具有4或更高的标称官能度，余量的环氧乙烷 但是不小于1.5重量％的聚丙烯氧化物名义上是三官能的。

    Process for making low density high resiliency flexible polyurethane foam
    4.
    发明授权
    Process for making low density high resiliency flexible polyurethane foam 有权
    制造低密度高弹性柔性聚氨酯泡沫的方法

    公开(公告)号：US08957123B2

    公开(公告)日：2015-02-17

    申请号：US13876620

    申请日：2010-12-07

    申请人： Issam Lazraq ,  Helmut Stegt ,  Allan James ,  Stephen R. Burks

    发明人： Issam Lazraq ,  Helmut Stegt ,  Allan James ,  Stephen R. Burks

    IPC分类号： C08G18/28

    CPC分类号： C08J9/125 ,  C08G18/482 ,  C08G18/4841 ,  C08G18/4866 ,  C08G18/5021 ,  C08G2101/0008 ,  C08J9/02 ,  C08J2205/06 ,  C08J2375/08

    摘要： A process for producing resilient, flexible polyurethane foams that function well in noise and vibration absorption applications for vehicle applications that are made from a blend of polyols (i) and an isocyanate (ii), wherein the blend of polyols (i) comprises a mixture of polyether polyols (i.a) that each has a hydroxyl equivalent weight of from 1200 to 3000 and at least 70% primary hydroxyl groups, from 5 to 80% by weight of the ethylene oxide-capped polypropylene oxides are nominally difunctional, from 0.5 to 20% by weight of the ethylene oxide-capped polypropylene oxides have a nominal functionality of four or higher, and the balance of the ethylene oxide-capped polypropylene oxides, but not less than 1.5% by weight thereof, are nominally trifunctional; an autocatalytic polyol (i.b) having a functionality in the range of 2 to 8 and a hydroxyl number in the range of 15 to 200, wherein said autocatalytic polyol compound comprising at least one tertiary amine group; and a low unsaturation polyol (i.c) having a functionality equal to or greater than 2, a hydroxyl equivalent weight of from 1800 to 2800, and a total unsaturation value of equal to or less than 0.06 meq/g.

    摘要翻译： 一种用于生产由多元醇（i）和异氰酸酯（ii）的共混物制成的车辆应用的噪声和振动吸收应用中良好的弹性，柔性聚氨酯泡沫体的方法，其中多元醇（i）的共混物包含混合物 的聚醚多元醇（ia），其各自具有1200至3000的羟基当量和至少70％的伯羟基，5至80重量％的环氧乙烷封端的聚环氧丙烷名义上为双官能的，为0.5至20 环氧乙烷封端的聚环氧丙烷的重量％具有四个或更高的标称官能度，其余的环氧乙烷封端的聚丙烯氧化物，但不小于1.5重量％，其名义上是三官能的; 官能度为2〜8，羟值在15〜200范围内的自催化多元醇（i.b），其中所述自催化多元醇化合物包含至少一个叔胺基团; 和低不饱和多元醇（i.c），其官能度等于或大于2，羟基当量为1800至2800，总不饱和度值等于或小于0.06meq / g。

    Method for making low density polyurethane foam for sound and vibration absorption
    5.
    发明授权
    Method for making low density polyurethane foam for sound and vibration absorption 有权
    制造低密度聚氨酯泡沫的方法，用于声音和振动吸收

    公开(公告)号：US08883934B2

    公开(公告)日：2014-11-11

    申请号：US13514180

    申请日：2010-12-07

    申请人： Helmut Stegt ,  Allan James ,  Stephen R. Burks ,  Jason A. Reese ,  David J. Honkomp

    发明人： Helmut Stegt ,  Allan James ,  Stephen R. Burks ,  Jason A. Reese ,  David J. Honkomp

    IPC分类号： C08K3/00 ,  C08J9/228 ,  C08G18/48 ,  C08G65/26 ,  C08G101/00

    CPC分类号： C08G65/2609 ,  C08G18/4812 ,  C08G2101/0008 ,  C08G2650/24

    摘要： Flexible polyurethane foams that function well in noise and vibration absorption applications are made from a mixture of polyether polyols oxides that each has a hydroxyl equivalent weight of from 1200 to 3000 and at least 70% primary hydroxyl groups. From 5 to 80% by weight of the ethylene oxide-capped polypropylene oxides are nominally difunctional, from 0.5 to 20% by weight of the ethylene oxide-capped polypropylene oxides have a nominal functionality of four or higher, and the balance of the ethylene oxide-capped polypropylene oxides, but not less than 1.5% by weight thereof, are nominally trifunctional.

    摘要翻译： 在噪声和振动吸收应用中功能良好的柔性聚氨酯泡沫体由聚醚多元醇氧化物的混合物制成，其各自具有1200至3000的羟基当量和至少70％的伯羟基。 环氧乙烷封端的聚环氧丙烷的5至80重量％通常是双官能的，0.5至20重量％的环氧乙烷封端的聚环氧丙烷具有4或更高的标称官能度，余量的环氧乙烷 但是不小于1.5重量％的聚丙烯氧化物名义上是三官能的。