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1.发明申请METHODS OF DECREASING VISCOSITY OF A POLYARYLENE SULFIDE-CONTAINING POLYMER MELT 审中-公开降低聚合物含硫聚合物熔体粘度的方法公开(公告)号：US20130012638A1
公开(公告)日：2013-01-10
申请号：US13636233
申请日：2011-03-16
申请人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Zheng-Zheng Huang , Lakshmi Krishnamurthy , John C. Howe , Marios Avgousti , Zuohong Yin
发明人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Zheng-Zheng Huang , Lakshmi Krishnamurthy , John C. Howe , Marios Avgousti , Zuohong Yin
CPC分类号： C08K5/098 , C08J3/20 , C08J3/226 , C08J2481/02 , C08J2481/04 , C08K5/0008 , C08L81/02
摘要： This invention relates to methods for decreasing the complex viscosity of a polyarylene sulfide polymer melt while maintaining the molecular weight of the polyarylene sulfide with time. This invention also relates to polymer melt compositions comprising a polyarylene sulfide, wherein the complex viscosity of the composition is decreased relative to the complex viscosity of the native polyarylene sulfide measured under the same conditions, and the weight average molecular weight of the polyarylene sulfide is maintained. The methods of decreasing the complex viscosity of a polyarylene sulfide-containing polymer melt, and the polymer melt compositions so obtained, are useful in processes to produce fibers, films, nonwovens, and molded parts from polyarylene sulfides.
摘要翻译： 本发明涉及降低聚芳硫醚聚合物熔体的复数粘度同时保持聚芳硫醚的分子量随时间的方法。 本发明还涉及包含聚芳硫醚的聚合物熔融组合物，其中组合物的复合粘度相对于在相同条件下测量的天然聚芳硫醚的复数粘度降低，并且保持聚芳硫醚的重均分子量 。 降低含聚芳硫醚的聚合物熔体的复数粘度的方法和如此获得的聚合物熔体组合物可用于从聚亚芳基硫化物制备纤维，膜，无纺布和模制部件的方法中。
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公开(公告)号：US20130012637A1
公开(公告)日：2013-01-10
申请号：US13636136
申请日：2011-03-21
申请人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Lakshmi Krishnamurthy , John C. Howe , Harry Vaughn Samuelson , Marios Avgousti , Zheng-Zheng Huang , Robert John Duff
发明人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Lakshmi Krishnamurthy , John C. Howe , Harry Vaughn Samuelson , Marios Avgousti , Zheng-Zheng Huang , Robert John Duff
摘要： An improved process for forming polyarylene sulfide fibers is provided. The process comprises forming at least one fiber from a polymer melt comprising a polyarylene sulfide and at least one tin additive comprising a branched tin(II) carboxylate. Using such a melt, the fiber forming continuity is improved compared to that of the native polyarylene sulfide melt processed under the same conditions.
摘要翻译： 提供了一种改进的形成聚芳硫醚纤维的方法。 该方法包括由包含聚芳硫醚的聚合物熔体和至少一种包含支化的（II）羧酸锡的锡添加剂形成至少一种纤维。 使用这样的熔体，与在相同条件下处理的天然聚芳硫醚熔体相比，纤维形成连续性得到改善。
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公开(公告)号：US20130210307A1
公开(公告)日：2013-08-15
申请号：US13635913
申请日：2011-03-22
申请人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Yefim Brun , Lakshmi Krishnamurthy , Zheng-Zheng Huang , John C. Howe , Laurie A. Howe , Harry Vaughn Samuelson , Zuohong Yin
发明人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Yefim Brun , Lakshmi Krishnamurthy , Zheng-Zheng Huang , John C. Howe , Laurie A. Howe , Harry Vaughn Samuelson , Zuohong Yin
IPC分类号： C08K5/098
CPC分类号： C08K5/098 , C08J5/18 , C08J2381/02 , C08J2381/04 , C08K5/0008 , C08K5/0091 , C08K5/57 , D01F1/10 , D01F6/765 , Y10T442/60 , C08L81/02
摘要： Provided are novel compositions comprising a polyarylene sulfide and at least one tin additive comprising a branched tin(II) carboxylate selected from the group consisting of Sn(O2CR)2, Sn(O2CR)(O2CR′), Sn(O2CR)(O2CR″), and mixtures thereof, where the carboxylate moieties O2CR and O2CR′ independently represent branched carboxylate anions and the carboxylate moiety O2CR″ represents a linear carboxylate anion. Articles comprising the novel compositions are also provided. In addition, methods to improve the thermal stability of polyarylene sulfides, and methods to improve the thermo-oxidative stability of polyarylene sulfides, through the use of the disclosed branched tin(II) carboxylates are provided. The polyarylene sulfide compositions are useful in various applications which require superior thermal resistance, chemical resistance, and electrical insulating properties.
摘要翻译： 提供了包含聚芳硫醚和至少一种锡添加剂的新型组合物，其包含选自Sn（O 2CR）2，Sn（O 2 CR）（O 2 CR'），Sn（O 2 CR）（O 2 CR） '）及其混合物，其中羧酸酯部分O 2 CR和O 2 C''独立地表示支链羧酸根阴离子，羧酸酯部分O 2 CR“表示直链羧酸根阴离子。 还提供了包含新型组合物的制品。 此外，提供了通过使用所公开的支化的（II）羧酸盐来改善聚亚芳基硫醚的热稳定性的方法和改进聚亚芳基硫醚的热氧化稳定性的方法。 聚芳硫醚组合物可用于需要优异的耐热性，耐化学性和电绝缘性的各种应用中。
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公开(公告)号：US20130012092A1
公开(公告)日：2013-01-10
申请号：US13636351
申请日：2011-03-22
申请人： Joel M. Pollino , Lakshmi Krishnamurthy , Joachim C. Ritter , Robert John Duff , Yefim Brun , Zheng-Zheng Huang , Zuohong Yin
发明人： Joel M. Pollino , Lakshmi Krishnamurthy , Joachim C. Ritter , Robert John Duff , Yefim Brun , Zheng-Zheng Huang , Zuohong Yin
IPC分类号： D04H13/00
CPC分类号： D01F8/16 , D01F1/10 , D04H1/541 , Y10T442/637
摘要： A nonwoven web comprising bicomponent fibers. The fibers have continuous phases each of a first polyarylene sulfide (PAS) component and a polymer component. The polymer component may also be a second polyarylene sulfide. The first polyarylene sulfide component contains a tin or a zinc additive or both, and the first polyarylene sulfide component of any given fiber is at least partially exposed to the external surface of that fiber.
摘要翻译： 包含双组分纤维的非织造纤维网。 纤维具有各自具有第一聚芳硫醚（PAS）组分和聚合物组分的连续相。 聚合物组分也可以是第二聚芳硫醚。 第一聚芳硫醚组分含有锡或锌添加剂或两者，并且任何给定纤维的第一聚芳硫醚组分至少部分地暴露于该纤维的外表面。
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公开(公告)号：US20130018135A1
公开(公告)日：2013-01-17
申请号：US13635025
申请日：2011-03-22
申请人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Yefim Brun , Zheng-Zheng Huang , John C. Howe
发明人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Yefim Brun , Zheng-Zheng Huang , John C. Howe
CPC分类号： C08K5/098 , C08K5/0008 , C08K5/0091 , C08L81/02
摘要： Provided are novel compositions comprising a polyarylene sulfide and at least one tin additive comprising a branched tin(II) carboxylate selected from the group consisting of Sn(O2CR)2, Sn(O2CR)(O2CR′), Sn(O2CR)(O2CR″), and mixtures thereof, where the carboxylate moieties O2CR and O2CR′ independently represent branched carboxylate anions and the carboxylate moiety O2CR″ represents a linear carboxylate anion. Articles comprising the novel compositions are also provided. In addition, methods to improve the thermal stability of polyarylene sulfides, and methods to improve the thermo-oxidative stability of polyarylene sulfides, through the use of the disclosed branched tin(II) carboxylates are provided. The polyarylene sulfide compositions are useful in various applications which require superior thermal resistance, chemical resistance, and electrical insulating properties.
摘要翻译： 提供了包含聚芳硫醚和至少一种锡添加剂的新型组合物，其包含选自Sn（O 2CR）2，Sn（O 2 CR）（O 2 CR'），Sn（O 2 CR）（O 2 CR） ）及其混合物，其中羧酸酯部分O 2CR和O 2 CCR'独立地表示支链羧酸根阴离子，羧酸酯部分O 2 CR“表示直链羧酸根阴离子。 还提供了包含新型组合物的制品。 此外，提供了通过使用所公开的羧基支链的（II）羧酸盐来提高聚亚芳基硫醚的热稳定性的方法和改进聚亚芳基硫醚的热氧化稳定性的方法。 聚芳硫醚组合物可用于需要优异的耐热性，耐化学性和电绝缘性的各种应用中。
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公开(公告)号：US20130005890A1
公开(公告)日：2013-01-03
申请号：US13634969
申请日：2011-03-22
申请人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Yefim Brun , Zheng-Zheng Huang , John C. Howe
发明人： Joachim C. Ritter , Joel M. Pollino , Michael T. Pottiger , Yefim Brun , Zheng-Zheng Huang , John C. Howe
CPC分类号： C08K5/098 , C08K5/0008 , C08L81/02
摘要： Provided are novel compositions comprising a polyarylene sulfide and at least one tin additive comprising a branched tin(II) carboxylate selected from the group consisting of Sn(O2CR)2, Sn(O2CR)(O2CR′), Sn(O2CR)(O2CR″), and mixtures thereof, where the carboxylate moieties O2CR and O2CR′ independently represent branched carboxylate anions and the carboxylate moiety O2CR″ represents a linear carboxylate anion. Articles comprising the novel compositions are also provided. In addition, methods to improve the thermal stability of polyarylene sulfides, and methods to improve the thermo-oxidative stability of polyarylene sulfides, through the use of the disclosed branched tin(II) carboxylates are provided. The polyarylene sulfide compositions are useful in various applications which require superior thermal resistance, chemical resistance, and electrical insulating properties.
摘要翻译： 提供了包含聚芳硫醚和至少一种锡添加剂的新型组合物，其包含选自Sn（O 2CR）2，Sn（O 2 CR）（O 2 CR'），Sn（O 2 CR）（O 2 CR） ）及其混合物，其中羧酸酯部分O 2CR和O 2 CCR'独立地表示支链羧酸根阴离子，羧酸酯部分O 2 CR“表示直链羧酸根阴离子。 还提供了包含新型组合物的制品。 此外，提供了通过使用所公开的羧基支链的（II）羧酸盐来提高聚亚芳基硫醚的热稳定性的方法和改进聚亚芳基硫醚的热氧化稳定性的方法。 聚芳硫醚组合物可用于需要优异的耐热性，耐化学性和电绝缘性的各种应用中。
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公开(公告)号：US20130011544A1
公开(公告)日：2013-01-10
申请号：US13636380
申请日：2011-03-16
申请人： Joel M. Pollino , Lakshmi Krishnamurthy , Joachim C. Ritter , Robert John Duff , Yefim Brun , Zheng-Zheng Zhuang , Zuohong Yin
发明人： Joel M. Pollino , Lakshmi Krishnamurthy , Joachim C. Ritter , Robert John Duff , Yefim Brun , Zheng-Zheng Zhuang , Zuohong Yin
摘要： A method for stabilizing a polymeric structure against thermo-oxidative degradation is described. A polymeric core structure is provided with a skin layer that contains a skin resin in which the skin resin at least partially envelops a portion of the core structure. The skin structure then provides a barrier that thereby stabilizes the portion of the structure that is enveloped. The skin resin is made from a treated polyarylene sulfide.
摘要翻译： 描述了一种稳定聚合物结构免受热氧化降解的方法。 聚合物芯结构设置有包含表皮树脂的表皮层，其中表皮树脂至少部分地包封芯结构的一部分。 皮肤结构然后提供了一个屏障，从而使被包封的结构的部分稳定。 皮肤树脂由经处理的聚芳硫醚制成。
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公开(公告)号：US20120318136A1
公开(公告)日：2012-12-20
申请号：US13160830
申请日：2011-06-15
申请人： ROBERT JOHN DUFF , Zheng-Zheng Jenny Huang , Lakshmi Krishnamurthy , Rakesh Nambiar , Joel M. Pollino , Joachim C. Ritter , Harry Vaughn Samuelson , Cheng-Hang Chi
发明人： ROBERT JOHN DUFF , Zheng-Zheng Jenny Huang , Lakshmi Krishnamurthy , Rakesh Nambiar , Joel M. Pollino , Joachim C. Ritter , Harry Vaughn Samuelson , Cheng-Hang Chi
CPC分类号： B01D39/1623 , B01D2239/0457 , B01D2273/20 , D01F1/10 , D01F6/765
摘要： A nonwoven felt for hot gas filtration. The fibers have a polyarylene sulfide (PAS) component that contains a zinc compound. In one embodiment, the PAS comprises at least one zinc(II) salt of an organic carboxylic acid. Also a method for filtering hot gases employing a bag made from a PAS component that contains a zinc or a zinc based additive.
摘要翻译： 用于热气体过滤的非织造毡。 纤维具有含有锌化合物的聚芳硫醚（PAS）成分。 在一个实施方案中，PAS包含至少一种有机羧酸的锌（II）盐。 也是使用由包含锌或锌基添加剂的PAS组分制成的袋来过滤热气体的方法。
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公开(公告)号：US20110218317A1
公开(公告)日：2011-09-08
申请号：US12873428
申请日：2010-09-01
申请人： Neville Everton Drysdale , Surbhi Mahajan , Kenneth Gene Moloy , Fredrik Nederberg , Joel M. Pollino , Joachim C. Ritter
发明人： Neville Everton Drysdale , Surbhi Mahajan , Kenneth Gene Moloy , Fredrik Nederberg , Joel M. Pollino , Joachim C. Ritter
IPC分类号： C08G63/682 , C08G63/78
CPC分类号： C08G63/6826 , D06M15/507 , D06M2200/11 , Y10T428/1429 , Y10T428/3154 , Y10T428/31544
摘要： Disclosed are polyesters, particularly poly(trimethylene terephthalate), comprising fluorovinylether functionalized aromatic repeat units, and methods to make the polyester polymers. The polymers are useful for imparting soil resistance to polyesters, particularly in the form of fibers, fabrics, and carpets.
摘要翻译： 公开了聚酯，特别是包含氟乙烯基醚官能化芳族重复单元的聚（对苯二甲酸丙二醇酯），以及制备聚酯聚合物的方法。 聚合物可用于赋予聚酯耐污性，特别是以纤维，织物和地毯的形式。
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公开(公告)号：US08779186B2
公开(公告)日：2014-07-15
申请号：US12874452
申请日：2010-09-02
申请人： Neville Everton Drysdale , Kenneth Gene Moloy , Joachim C. Ritter , Joel M. Pollino , Surbhi Mahajan Du
发明人： Neville Everton Drysdale , Kenneth Gene Moloy , Joachim C. Ritter , Joel M. Pollino , Surbhi Mahajan Du
摘要： New fluorinated ethers of aromatic acids and diesters are disclosed. These compositions can be applied to, e.g., fibers, yarns, carpets, garments, films, molded parts, paper and cardboard, stone, and tile to impart soil, water and oil resistance. By incorporating the fluorinated ethers of aromatic acids, or diesters thereof, into polymer backbones, more lasting soil, water and oil resistance, as well as improved flame retardance, can be achieved.
摘要翻译： 公开了芳族酸和二酯的新的氟化醚。 这些组合物可以应用于例如纤维，纱线，地毯，衣服，薄膜，模制件，纸和纸板，石头和瓦片，以赋予土壤，水和耐油性。 通过将芳族酸或其二酯的氟化醚引入聚合物主链中，可以实现更持久的土壤，耐水和耐油性以及改进的阻燃性。
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