Herbicidal cycloalkyl-substituted thiadiazolyloxyacetamides
    2.
    发明授权
    Herbicidal cycloalkyl-substituted thiadiazolyloxyacetamides 失效
    除草剂环己基取代的三羟甲基纤维素

    公开(公告)号:US5169427A

    公开(公告)日:1992-12-08

    申请号:US706127

    申请日:1991-05-28

    CPC分类号: C07D285/13 A01N43/82

    摘要: Herbicidal cycloalkyl-substituted thiadiazolyloxyacetamides of the formula ##STR1## in which R.sup.1 represents hydrogen, or represents an optionally substituted radical selected from the group consisting of alkyl, alkenyl, alkynyl and aralkyl,R.sup.2 represents an optionally substituted radical selected from the group consisting of alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, aralkyl, aryl, alkoxy, alkenyloxy and alkynyloxy, orR.sup.1 and R.sup.2, together with the nitrogen atom to which they are bonded, form an optionally substituted saturated or unsaturated nitrogen-heterocyclic radical, which can contain further hetero atoms and to which a benzo grouping can be fused, andR.sup.3 represents optionally substituted cycloalkyl.Intermediates of the formula ##STR2## are also new.

    摘要翻译: 式(I)的除草环烷基取代的噻二唑氧基乙酰胺,其中R 1表示氢,或表示任选取代的选自烷基,烯基,炔基和芳烷基的基团,R 2表示任选取代的基团,其选自 由烷基,烯基,炔基,环烷基,环烯基,芳烷基,芳基,烷氧基,烯氧基和炔氧基组成,或者R1和R2与它们所键合的氮原子一起形成任选取代的饱和或不饱和的氮杂环基, 其可以含有另外的杂原子,并且苯并基团可以被稠合,并且R 3表示任选取代的环烷基。 公式的中间体也是新的。

    Pesticidal 3-aryl-pyrrolidine-2,4-diones
    4.
    发明授权
    Pesticidal 3-aryl-pyrrolidine-2,4-diones 失效
    杀虫剂3-芳基 - 吡咯烷-2,4-二酮

    公开(公告)号:US5186737A

    公开(公告)日:1993-02-16

    申请号:US678479

    申请日:1991-04-01

    摘要: Insecticidal, acaricidal, herbicidal and antimycotic 3-aryl-pyrrolidine-2,4-diones of the formula ##STR1## in which X represents alkyl, halogen or alkoxy,Y represents hydrogen, alkyl, halogen, alkoxy or halogenoalkyl,Z represents alkyl, halogen or alkoxy,n represents a number from 0-3,R represents hydrogen or represents the groups --CO--R.sup.1 or --CO--O--R.sup.2, in whichR.sup.1 represents alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or cycloalkyl which can be interrupted by hetero atoms, each of which radicals is optionally substituted by halogen, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl or substituted hetaryloxyalkyl, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl and substituted hetaryloxyalkyl, andR.sup.2 represents alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or optionally substituted phenyl or cycloalkyl, each of which radicals is optionally substituted by halogen,A represents alkyl, alkenyl, alkinyl, alkoxyalkyl, polyalkoxyalkyl, alkylthioalkyl, or cycloalkyl which is optionally interrupted by a hetero atom, each of which radicals is optionally subsituted by halogen, or represents arylalkyl which is optionally substituted by halogen, alkyl, halogenoalkyl, alkoxy or nitro,B and C* independently of one another represent hydrogen, alkyl or alkoxyalkyl.

    摘要翻译: 式(I)的杀虫,杀螨,除草和抗真菌性3-芳基 - 吡咯烷-2,4-二酮其中X代表烷基,卤素或烷氧基,Y代表氢,烷基,卤素,烷氧基或卤代烷基,Z 表示烷基,卤素或烷氧基,n表示0-3的数,R表示氢或表示基团-CO-R1或-CO-O-R2,其中R1表示烷基,烯基,烷氧基烷基,烷硫基烷基,聚烷氧基烷基或环烷基 任何取代的苯基,取代的杂芳基,取代的苯氧基烷基或取代的噻唑烷基,或代表任意取代的苯基,任选取代的苯基烷基,取代的杂芳基, 取代的苯氧基烷基和取代的硫代氧基烷基,R 2表示烷基,链烯基,烷氧基烷基,聚烷氧基烷基或任选取代的苯基或环烷基,各w 任选被卤素取代的基团,A代表烷基,烯基,炔基,烷氧基烷基,聚烷氧基烷基,烷硫基烷基或环烷基,任选被杂原子中断,每个基团任选被卤素取代,或表示任选取代的芳基烷基 卤素,烷基,卤代烷基,烷氧基或硝基,B和C *彼此独立地表示氢,烷基或烷氧基烷基。

    Pesticidal tautomers of 3-aryl-pyrrolidine-2,4-diones and use thereas
    5.
    发明授权
    Pesticidal tautomers of 3-aryl-pyrrolidine-2,4-diones and use thereas 失效
    3-芳基 - 吡咯烷-2,4-二酮的杀虫互变异构体

    公开(公告)号:US5045560A

    公开(公告)日:1991-09-03

    申请号:US460208

    申请日:1990-01-02

    摘要: Insecticidal, acaricidal, herbicidal and antimycotic 3-aryl-pyrrolidine-2,4-diones of the formula ##STR1## in which X represents alkyl, halogen or alkoxy,Y represents hydrogen, alkyl, halogen, alkoxy or halogenoalkyl,Z represents alkyl, halogen or alkoxy,n represents a number from 0-3,R represents hydrogen or represents the groups --CO--R.sup.1 or --CO--O--R.sup.2, in whichR.sup.1 represents alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, polyalkoxyalkyl or cycloalkyl which can be interrupted by hetero atoms, each of which radicals is optionally substituted by halogen, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl or substituted hetaryloxyalkyl, or represents optionally substituted phenyl, optionally substituted phenylalkyl, substituted hetaryl, substituted phenoxyalkyl and substituted hetaryloxyalkyl, andR.sup.2 represents alkyl, alkenyl, alkoxyalkyl, polyalkoxyalkyl or optionally substituted phenyl or cycloalkyl, each of which radicals is optionally substituted by halogen,A represents alkyl, alkenyl, alkinyl, alkoxyalkyl, polyalkoxyalkyl, alkylthioalkyl, or cycloalkyl which is optionally interrupted by a hetero atom, each of which radicals is optionally substituted by halogen, or represents arylalkyl which is optionally substituted by halogen, alkyl, halogenoalkyl, alkoxy or nitro,B and C* independently of one another represent hydrogen, alkyl or alkoxyalkyl.

    摘要翻译: 式(I)的杀虫,杀螨,除草和抗真菌性3-芳基 - 吡咯烷-2,4-二酮其中X代表烷基,卤素或烷氧基,Y代表氢,烷基,卤素,烷氧基或卤代烷基,Z 表示烷基,卤素或烷氧基,n表示0-3的数,R表示氢或表示基团-CO-R1或-CO-O-R2,其中R1表示烷基,烯基,烷氧基烷基,烷硫基烷基,聚烷氧基烷基或环烷基 任何取代的苯基,取代的杂芳基,取代的苯氧基烷基或取代的噻唑烷基,或代表任意取代的苯基,任选取代的苯基烷基,取代的杂芳基, 取代的苯氧基烷基和取代的硫代氧基烷基,R 2表示烷基,链烯基,烷氧基烷基,聚烷氧基烷基或任选取代的苯基或环烷基,各w 任选被卤素取代的基团,A代表烷基,链烯基,炔基,烷氧基烷基,聚烷氧基烷基,烷硫基烷基或环烷基,任选被杂原子间隔,每个基团任选被卤素取代,或表示任选取代的芳基烷基 卤素,烷基,卤代烷基,烷氧基或硝基,B和C *彼此独立地表示氢,烷基或烷氧基烷基。

    Process for the preparation of 2-amino-2-arylethanols and novel
intermediates
    6.
    发明授权
    Process for the preparation of 2-amino-2-arylethanols and novel intermediates 失效
    制备2-氨基-2-芳基乙醇和新型中间体的方法

    公开(公告)号:US6031134A

    公开(公告)日:2000-02-29

    申请号:US185864

    申请日:1998-11-04

    摘要: The invention relates to a novel process for the preparation of 2-amino-2-arylehanols of the formula (I) ##STR1## in which Ar represents aryl or hetaryl each unsubstituted or identically or differently monosubstituted to pentasubstituted, where as substituents there may be mentioned:halogen, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, unsubstituted or substituted cycloalkyloxy or unsubstituted or substituted phenyl,which comprises catalytically hydrogenating .alpha.-hydroxyketoximes of the formula (II) ##STR2## in which Ar has the meaning given above,using Raney nickel or Raney cobalt in the presence of a diluent and in the presence of a base andnovel 2-amino-2-arylethanols and novel .alpha.-hydroxyketoximes.

    摘要翻译: 本发明涉及一种制备式(I)的2-氨基-2-芳基醇的新方法,其中Ar表示芳基或杂芳基,其各自未取代或相同或不同地单取代至五取代,其中作为取代基可以提及:卤素 烷基,卤代烷基,烷氧基,卤代烷氧基,未取代或取代的环烷氧基或未取代或取代的苯基,其包括在存在下使用阮内镍或阮内钴催化氢化式(II)的α-羟基酮肟,其中Ar具有上述含义 的碱和新的2-氨基-2-芳基乙醇和新的α-羟基肟的存在下进行。

    Process for the preparation of 2-amino-2-arylethanols and novel
intermediates
    8.
    发明授权
    Process for the preparation of 2-amino-2-arylethanols and novel intermediates 失效
    制备2-氨基-2-芳基乙醇和新型中间体的方法

    公开(公告)号:US6022995A

    公开(公告)日:2000-02-08

    申请号:US723968

    申请日:1996-09-27

    摘要: The invention relates to a novel process for the preparation of 2-amino-2-arylethanols of the formula (I) ##STR1## in which Ar represents aryl or hetaryl each unsubstituted or identically or differently monosubstituted to pentasubstituted, where as substituents there may be mentioned:halogen, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, unsubstituted or substituted cycloalkyloxy or unsubstituted or substituted phenyl,which comprises catalytically hydrogenating .alpha.-hydroxyketoximes of the formula (II) ##STR2## in which Ar has the meaning given above,using Raney nickel or Raney cobalt in the presence of a diluent and in the presence of a base andnovel 2-amino-2-arylethanols and novel .alpha.-hydroxyketoximes.

    摘要翻译: 本发明涉及一种制备式(I)的2-氨基-2-芳基乙醇的新方法,其中Ar表示芳基或杂芳基,其各自未取代或相同或不同单取代至五取代,其中可以提及的取代基:卤素 烷基,卤代烷基,烷氧基,卤代烷氧基,未取代或取代的环烷氧基或未取代或取代的苯基,其包括在存在下使用阮内镍或阮内钴催化氢化式(II)的α-羟基酮肟,其中Ar具有上述含义 的碱和新的2-氨基-2-芳基乙醇和新的α-羟基肟的存在下进行。

    Process for the preparation of 2-amino-2-arylethanols and novel
intermediates
    9.
    发明授权
    Process for the preparation of 2-amino-2-arylethanols and novel intermediates 失效
    制备2-氨基-2-芳基乙醇和新型中间体的方法

    公开(公告)号:US5602282A

    公开(公告)日:1997-02-11

    申请号:US511207

    申请日:1995-08-04

    摘要: The invention relates to a novel process for the preparation of 2-amino-2-arylethanols of the formula (I) ##STR1## in which Ar represents aryl or hetaryl each unsubstituted or identically or differently monosubstituted to pentasubstituted, where as substituents there may be mentioned:halogen, alkyl, halogenoalkyl, alkoxy, halogenoalkoxy, unsubstituted substituted cycloalkyloxy or unsubstituted or substituted phenyl,which comprises catalytically hydrogenating .alpha.-hydroxyketoximes of the formula (II) ##STR2## in which Ar has the meaning given above,using Raney nickel or Raney cobalt in the presence of a diluent and in the presence of a base andnovel 2-amino-2-arylethanols and novel .alpha.-hydroxyketoximes.

    摘要翻译: 本发明涉及一种制备式(I)的2-氨基-2-芳基乙醇的新方法,其中Ar表示芳基或杂芳基,其各自未取代或相同或不同地单取代至五取代,其中作为取代基 可以提及:卤素,烷基,卤代烷基,烷氧基,卤代烷氧基,未取代的取代的环烷氧基或未取代或取代的苯基,其包括催化氢化式(II)的α-羟基肟(II),其中Ar具有给定的含义 在稀释剂存在下和在碱和新的2-氨基-2-芳基乙醇和新的α-羟基肟的存在下使用阮内镍或阮内钴。

    Method for production of Δ1-pyrrolines
    10.
    发明授权
    Method for production of Δ1-pyrrolines 失效
    Delta1-吡咯啉的生产方法

    公开(公告)号:US07250521B2

    公开(公告)日:2007-07-31

    申请号:US10474106

    申请日:2002-04-08

    IPC分类号: C07D207/18

    CPC分类号: C07D207/20

    摘要: 2,5-Bisaryl-Δ1-pyrrolines of the formula (I) in which Ar1 and Ar2 are as defined in the description can be prepared by reacting aroylpyrrolidinones of the formula (II) in which Ar1 and Ar2 are as defined in the description with an acid, if appropriate in the presence of a diluent.

    摘要翻译: 其中Ar 1和Ar 2的式(I)的2,5-二芳基 - 三(1) - 吡咯啉如说明书中所定义 可以通过使如式(II)的芳酰基吡咯烷酮(其中Ar 1和Ar 2)如本说明书所定义的那样与酸反应来制备,如果合适的话,在 冲淡。