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公开(公告)号：US5214223A
公开(公告)日：1993-05-25
申请号：US912981
申请日：1992-07-14
IPC分类号： B01J31/02 , B01J31/26 , C01B7/19 , C07C17/087 , C07C17/21
CPC分类号： B01J31/0227 , B01J31/0225 , B01J31/26 , C01B7/191 , C07C17/087 , C07C17/21 , B01J2231/32
摘要： A method of preparing fluorine-containing ethane derivatives using a catalyst mixture which comprises a metal halide and a sulfonic acid derivative is described. The method is particularly well suited for preparing CF.sub.3 CHCl.sub.2 (R123) from perchloroethylene and for preparing CF.sub.3 CH.sub.2 F (R134a) from trifluoroethylene.
摘要翻译： 描述了使用包含金属卤化物和磺酸衍生物的催化剂混合物制备含氟乙烷衍生物的方法。 该方法特别适用于从全氯乙烯制备CF 3 CHCl 2（R123）和从三氟乙烯制备CF 3 CH 2 F（R134a）。
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公开(公告)号：US5171900A
公开(公告)日：1992-12-15
申请号：US683834
申请日：1991-04-11
IPC分类号： B01J27/10 , B01J31/02 , B01J31/26 , B01J31/36 , C01B7/19 , C07B61/00 , C07C17/06 , C07C17/087 , C07C17/20 , C07C17/21 , C07C19/08 , C07C19/12
CPC分类号： B01J31/0227 , B01J31/26 , C01B7/191 , C07C17/087 , C07C17/21 , B01J2231/32
摘要： A method of preparing fluorine-containing ethane derivatives using a catalyst mixture which comprises a metal halide and a sulfonic acid derivative is described. The method is particularly well suited for preparing CF.sub.3 CHCl.sub.2 (R123) from perchloroethylene and for preparing CF.sub.3 CH.sub.2 F (R134a) from trifluoroethylene.
摘要翻译： 描述了使用包含金属卤化物和磺酸衍生物的催化剂混合物制备含氟乙烷衍生物的方法。 该方法特别适用于从全氯乙烯制备CF 3 CHCl 2（R123）和从三氟乙烯制备CF 3 CH 2 F（R134a）。
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公开(公告)号：US5679613A
公开(公告)日：1997-10-21
申请号：US414236
申请日：1995-03-31
IPC分类号： B01J27/10 , B01J27/12 , B01J27/125 , B01J27/128 , C07B61/00 , C07C17/20 , C07C17/358 , C07C19/12 , B01J27/06
CPC分类号： B01J27/128 , B01J27/10 , B01J27/12 , B01J27/125 , C07C17/358
摘要： A process for preparing R113a from Rl13, and R123 from R123a or R123b by rearrangement over AlCl.sub.3, in which when the reaction mixture is heated sudden start-up of the reaction, which often causes large amounts of heat to be released and the reaction to run away, is prevented by using a specially activated AlCl.sub.3, which has been activated by means of a metal halide selected from the group consisting of NaF.multidot.nHF with 0
摘要翻译： 通过在AlCl 3上重排从R133制备R113a的R123和R123a或R123b的R123，其中当反应混合物被加热突然启动时，这通常导致大量的热被释放并且反应进行 通过使用已经通过选自具有0
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公开(公告)号：US5227546A
公开(公告)日：1993-07-13
申请号：US940207
申请日：1992-09-08
IPC分类号： B01J31/02 , B01J23/20 , B01J27/02 , B01J27/06 , C07B61/00 , C07C17/087 , C07C17/20 , C07C17/21 , C07C19/08
CPC分类号： B01J27/02 , B01J23/20 , B01J27/06 , C07C17/206 , C07C17/21
摘要： A process for preparing fluorine-containing ethane derivatives using hydrogen fluoride and a catalytically active formulation comprising a tantalum fluorosulfonate compound or a niobium fluorosulfonate compound is described. The process is particularly suitable for preparing ethane derivatives which contain a CF.sub.3 group, for example for preparing C.sub.3 CHCl.sub.2 (R123) from perchloroethylene.
摘要翻译： 描述了使用氟化氢制备含氟乙烷衍生物的方法和含有氟代磺酸钨化合物或氟代磺酸铌化合物的催化活性制剂。 该方法特别适用于制备含有CF 3基团的乙烷衍生物，例如用于从全氯乙烯制备C3CHCl2（R123）。
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公开(公告)号：US5430201A
公开(公告)日：1995-07-04
申请号：US323015
申请日：1994-10-14
IPC分类号： B01J27/10 , B01J27/12 , B01J27/125 , B01J27/128 , C07B61/00 , C07C17/20 , C07C17/358 , C07C19/12 , C07C19/08
CPC分类号： B01J27/128 , B01J27/10 , B01J27/12 , B01J27/125 , C07C17/358
摘要： A process for preparing R113a from R113, and R123 from R123a or R123b by rearrangement over AlCl.sub.3, in which when the reaction mixture is heated sudden start-up of the reaction, which often causes large amounts of heat to be released and the reaction to run away, is prevented by using a specially activated AlCl.sub.3, which has been activated by means of a metal halide selected from the group consisting of NaF.nHF with 0
摘要翻译： 从R113制备R113a的方法，R123a或R123b的R123通过在AlCl 3上重排而制备，其中当反应混合物被加热突然启动时，这通常导致大量的热量被释放并且反应运行 通过使用已经通过选自具有0
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公开(公告)号：US5283381A
公开(公告)日：1994-02-01
申请号：US51898
申请日：1993-04-26
IPC分类号： B01J31/02 , B01J23/20 , B01J27/02 , B01J27/06 , C07B61/00 , C07C17/087 , C07C17/20 , C07C17/21 , C07C19/08 , C07C17/00
CPC分类号： B01J27/02 , B01J23/20 , B01J27/06 , C07C17/206 , C07C17/21
摘要： A process for preparing fluorine-containing ethane derivatives using hydrogen fluoride and a catalytically active formulation comprising a tantalum fluorosulfonate compound or a niobium fluorosulfonate compound is described. The process is particularly suitable for preparing ethane derivatives which contain a CF.sub.3 group, for example for preparing CF.sub.3 CHCl.sub.2 (R123) from perchloroethylene.
摘要翻译： 描述了使用氟化氢制备含氟乙烷衍生物的方法和含有氟代磺酸钨化合物或氟代磺酸铌化合物的催化活性制剂。 该方法特别适用于制备含有CF 3基团的乙烷衍生物，例如用于从全氯乙烯制备CF 3 CHCl 2（R123）。
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公开(公告)号：US5481029A
公开(公告)日：1996-01-02
申请号：US233622
申请日：1994-04-26
申请人： Max Braun , Johannes Eicher , Werner Rudolph , Kerstin Eichholz
发明人： Max Braun , Johannes Eicher , Werner Rudolph , Kerstin Eichholz
IPC分类号： B01J31/02 , C07B61/00 , C07C45/48 , C07C45/65 , C07C45/67 , C07C49/04 , C07C49/167 , C07C67/10 , C07C67/313 , C07C67/343 , C07C69/63 , C07C69/716
CPC分类号： C07C45/48 , C07C45/676 , C07C49/167 , C07C67/10
摘要： A process for preparing ketones, for example CF.sub.3 C(O)CH.sub.3, CF.sub.3 C(O)CH.sub.2 C(O)CF.sub.3 and CF.sub.3 C(O)CF.sub.2 H, in which .beta.-ketoesters are transesterified and decarboxylated using a carboxylic acid, for example trifluoroacetic acid, in the presence of a catalyst, particularly an "onium" salt of a carboxylic acid or an effective amount of a proton-donating acid, preferably a sulfonic acid such as alkyl- or arylsulfonic acids, or a mineral acid. The process is advantageously carried out in the absence of water, so that no formation of acetals or hydrates occurs, and no dehydrating step is needed. The process is simple to carry out, and if transesterification is carried out with a sufficiently active carboxylic acid, for example with trifluoroacetic acid, the presence of an additional catalyst is unnecessary.
摘要翻译： 制备酮的方法，例如CF 3 C（O）CH 3，CF 3 C（O）CH 2 C（O）CF 3和CF 3 C（O）CF 2 H），其中β-酮酯使用羧酸（例如三氟乙酸）进行酯交换和脱羧 存在催化剂，特别是羧酸的“鎓”盐或有效量的质子供体酸，优选磺酸如烷基或芳基磺酸或无机酸。 该方法有利地在没有水的情况下进行，使得不会发生缩醛或水合物的形成，并且不需要脱水步骤。 该方法很容易进行，如果用足够活泼的羧酸（例如三氟乙酸）进行酯交换反应，则不需要另外的催化剂的存在。
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公开(公告)号：US5382721A
公开(公告)日：1995-01-17
申请号：US72759
申请日：1993-06-07
申请人： Pascal Pennetreau , Francine Janssens , Max Braun , Johannes Eicher , Werner Rudolph , Eckhard Hausmann
发明人： Pascal Pennetreau , Francine Janssens , Max Braun , Johannes Eicher , Werner Rudolph , Eckhard Hausmann
IPC分类号： B01J21/06 , B01J23/14 , B01J27/08 , C07B61/00 , C07C17/04 , C07C17/087 , C07C19/08 , C07C17/08
CPC分类号： C07C17/087
摘要： Process for the preparation of 1,1,1,2-tetrafluoroethane by reaction of hydrogen fluoride with a trihaloethylene according to which trifluoroethylene is chosen as trihaloethylene and the reaction is carried out in the liquid phase.
摘要翻译： 通过氟化氢与三卤乙烯的反应制备1,1,1,2-四氟乙烷的方法，根据该方法，三氟乙烯被选择为三卤代乙烯，反应在液相中进行。
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9.发明授权Process for working up a hydrogen fluoride phase from a fluorination reaction mixture 失效从氟化反应混合物中处理氟化氢相的方法
公开(公告)号：US5300709A
公开(公告)日：1994-04-05
申请号：US3001
申请日：1993-01-11
摘要： A process for working up the hydrogen fluoride phase of reaction mixtures from fluorination reactions comprising contacting the hydrogen fluoride phase with oleum in order to obtain dried hydrogen fluoride, which can be recycled to the fluorination reaction.
摘要翻译： 一种从氟化反应处理反应混合物的氟化氢相的方法，包括使氟化氢相与发烟硫酸接触以获得干燥的氟化氢，其可被再循环至氟化反应。
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公开(公告)号：US5336817A
公开(公告)日：1994-08-09
申请号：US950497
申请日：1992-09-25
IPC分类号： B01J31/02 , B01J27/02 , B01J27/06 , C07B61/00 , C07C17/20 , C07C17/21 , C07C17/25 , C07C19/08 , C07C21/18 , C07C17/08
摘要： A method of preparing CH.sub.2 FCF.sub.3 from fluorodichloro-ethylene using a catalytically active niobium, tantalum or molybdenum fluorosulfonate compound or a catalyst mixture which comprises a niobium, tantalum or molybdenum halide and a sulfonic acid derivative.
摘要翻译： 使用催化活性的铌，钼或钼氟磺酸盐化合物或包含铌，钽或钼卤化物和磺酸衍生物的催化剂混合物从氟代二氯乙烯制备CH 2 FCF 3的方法。
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