摘要:
Pressureless sintering of silicon carbide to produce ceramic bodies having 75% and greater theoretical densities, can be accomplished by firing shaped bodies, containing finely divided silicon carbide, boron source such as boron carbide, carbon source such as phenolic resin and a temporary binder, at a sintering temperature of from about 1900.degree. C. to about 2500.degree. C.
摘要:
A dense thermal shock resistant silicon carbide ceramic body and its method of manufacture which comprises heat sintering a shaped body comprising particulate silicon carbide and an additive selected from boron nitride, boron phosphide, aluminum diboride and mixtures thereof.
摘要:
Pressureless sintering of silicon carbide to produce ceramic bodies having 75% and greater theoretical densities, can be accomplished by firing shaped bodies, containing finely divided silicon carbide, boron source such as boron carbide, carbon source such as phenolic resin and a temporary binder, at a sintering temperature of from about 1900.degree. C to about 2500.degree. C.
摘要:
Pressureless sintered silicon carbide ceramic bodies, having an equiaxed microstructure and an alpha crystalline habit can be produced by firing shaped bodies, containing finely divided silicon carbide, boron source such as boron carbide, carbon source such as phenolic resin and a temporary binder, at a sintering temperature of from about 1900.degree. C. to about 2250.degree. C., depending on the sintering atmosphere, under conditions such that a coating of carbon source is maintained on the finely divided silicon carbide, and sufficient boron is maintained within the shaped body during firing. Boron can be maintained within the shaped body by various techniques, such as the use of a "seasoned boat" or graphite container for the body being sintered, which has been saturated with boron by exposure to boron at or about the temperature of sintering.There is also disclosed a process for producing a sintered silicon carbide ceramic body, with or without the equiaxed crystal microstructure, from silicon carbide powders of alpha or beta crystal structure, or amorphous noncrystalline silicon carbide, or mixtures thereof.
摘要:
A powder containing substantial amounts of alpha phase silicon carbide suitable for use in subsequent sintering operations to obtain a high-density, high-strength ceramic product is described. The powder may consist substantially entirely of alpha silicon carbide or may consist of mixtures of alpha and beta phase silicon carbide. The silicon carbide powder of the present invention has an average particle size of from about 0.10 to about 2.50 microns and may contain maximum amounts of the following materials by weight based upon 100 parts of powder.______________________________________ SiO.sub.2 2.00 Free Silicon 0.25 Iron 0.50 Alkali and Alkaline Earth Metals 0.50 Total Metal Oxides 3.75 ______________________________________ Sinterable powders and methods of producing sintered products from the powders are also described.
摘要:
Pressureless sintered silicon carbide ceramic bodies, having an equiaxed microstructure and an alpha crystalline habit can be produced by firing shaped bodies, containing finely divided silicon carbide, boron source such as boron carbide, carbon source such as phenolic resin and a temporary binder, at a sintering temperature of from about 1900.degree. C. to about 2250.degree. C., depending on the sintering atmosphere, under conditions such that a coating of carbon source is maintained on the finely divided silicon carbide, and sufficient boron is maintained within the shaped body during firing. Boron can be maintained within the shaped body by various techniques, such as the use of a "seasoned boat" or graphite container for the body being sintered, which has been saturated with boron by exposure to boron at or about the temperature of sintering.There is also disclosed a process for producing a sintered silicon carbide ceramic body, with or without the equiaxed crystal microstructure, from silicon carbide powders of alpha or beta crystal structure, or amorphous noncrystalline silicon carbide, or mixtures thereof.
摘要:
A method for making a dense thermal shock resistant silicon carbide ceramic body by hot pressing a blend of silicon carbide and from about 0.2 to about 2 weight percent of aluminum diboride and the resulting body.
摘要:
The invention provides a silicon carbide fiber carrying an aluminum nitride coating between about 1 and about 15 micrometers thick. The AlN coating serves as a debond layer which improves the fracture toughness of composite materials in which the coated fiber is a reinforcement phase.
摘要:
The invention provides silicon carbide fiber-reinforced, reaction-bonded silicon carbide composites suitable for high temperature applications in which the silicon carbide fiber is coated with AlN, BN or TiB.sub.2. The composites offer superior fracture toughness which is ascribed to fiber pullout. The invention also includes a process for making the composites.
摘要:
The invention includes a process for producing a reaction bonded silicon carbide composite reinforced with coated silicon carbide fibers which is suitable for high temperature applications. The process includes the steps of coating SiC fibers with AlN, BN or TiB.sub.2 ; treating the coated fibers with a mixture of SiC powder, water and a surfactant; preparing a slurry comprising SiC powder and water; infiltrating the coated fibers with the slurry to form a cast; drying the cast to form a green body; and reaction bonding the green body to form a dense SiC fiber reinforced reaction bonded matrix composite.The invention further includes a SiC fiber reinforced SiC composite comprising a reaction bonded SiC matrix, a SiC fiber reinforcement possessing thermal stability at high temperatures and an interface coating on the fibers having chemical and mechanical compatibility with the SiC matrix and with the SiC fibers.