摘要:
A method for manufacturing an embossed surface including a polymer composition having reactive moieties and a first glass transition temperature of Tg1. The method includes embossing the surface at temperature Temb; and raising the first glass transition temperature Tg1 of the embossed polymeric surface to a second glass transition temperature Tg2 such that Tg2>Temb. In another embodiment, a method for improving the release of a polymeric surface from an embossing tool includes incorporating of one or more of fluorine atoms, silicon atoms, or siloxane segments into the backbone of the polymer. The methods are particularly suited for direct patterning of photoresists, fabrication of interdigitated electrodes, and fabrication of data storage media.
摘要:
In one aspect the present invention provides a storage medium for data, the storage medium comprising: a) a substrate, a physical portion of which comprises at least one polyimide, and b) at least one data layer on the substrate. The substrate comprising a polyimide exhibits low axial displacement and beneficial damping characteristics.
摘要:
A system, device and methods, for determining at least two analytes, wherein the system and device include at least one resonant sensor circuit that includes a sensing material that predictably affects the resonant complex impedance response of a sensor electrode. The sensing material has at least two material properties that change when the materials are exposed to two or more analytes. The system and device also include a processor that generates a multivariate sensor response pattern that is based at least in part on a change in the two material properties of the sensing material.
摘要:
The invention relates to polymers useful in optoelectronic devices and comprising structural unit of formula I: wherein R1 and R2 are independently at each occurrence, hydrogen, a C1-C20 aliphatic radical, a C3-C20 aromatic radical, or a C3-C20 cycloaliphatic radical; R3 is H or alkyl; a and b are, independently at each occurrence 0, or an integer ranging from 1 to 3; and Ar is a direct bond or aryl.
摘要:
The present invention provides novel polymer compositions comprising a polymeric component and a novel organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compounds used in the polymer compositions are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). Type (1) organic iridium compositions are referred to herein as comprising “organic iridium complexes”. In one aspect, the polymeric component may be an electroactive polymer. The novel polymer compositions of the invention are useful in optoelectronic electronic devices such as OLED devices and photovoltaic devices. In one aspect, the invention provides novel polymer compositions useful in the preparation of OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要:
An optical article comprising a primary mark disposed on the optical article and a secondary mark disposed on the optical article in close proximity to the primary mark. The primary mark comprises a first optical-state change material and the secondary mark comprises a second optical-state change material. The optical article is transformed from a pre-activated state to an activated state when a localized authorized activation method is used that selectively activates the primary mark. The optical article is transformed from a pre-activated state to an deactivated state when a non-localized unauthorized activation method is used that activates the secondary mark along with the primary mark resulting in the second optical-state change material undergoing a reverse color change when compared to the first optical-state change material. An optical article with a single mark including multiple color change optical-state change material is also disclosed. Methods of covering and encapsulating the marks are also disclosed.
摘要:
The present invention provides electronic devices comprising novel polymer compositions which provide for enhanced device performance. The polymer compositions employed comprise a polymeric component and a novel organic iridium compound comprising at least one cyclometallated ligand and at least one ketopyrrole ligand. The organic iridium compounds used in the polymer compositions are referred to as Type (1) organic iridium compositions and are constituted such that no ligand of the novel organic iridium compound has a number average molecular weight of 2,000 grams per mole or greater (as measured by gel permeation chromatography). In one aspect, the polymeric component may be an electroactive polymer. In one aspect, the present invention provides optoelectronic devices, such as OLED devices and photovoltaic devices. In another aspect, the invention provides OLED devices exhibiting enhanced color properties and light output efficiencies.
摘要:
This invention is related to a method for making diether dianhydrides by the reaction of halophthalic anhydride and a metal salt of an aromatic dihydroxy compound in the presence of a solvent and a phase transfer catalyst. Typical phase transfer catalyst include guanidium salts, aminopyridinium salts, or phosphazenium salts.
摘要:
Polycarbonates containing low or undetectable levels of Fries rearrangement products and comprising repeat units derived from one or more of resorcinol, hydroquinone, methylhydroquinone, bisphenol A, and 4,4′-biphenol have been prepared by the melt reaction of one or more of the aforementioned dihydroxy aromatic compounds with an ester-substituted diaryl carbonate such as bis-methyl salicyl carbonate. Low, or in many instances undetectable, levels of Fries rearrangement products are found in the product polycarbonates obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reactions using diphenyl carbonate.
摘要:
A new silicone condensation reaction, the condensation between an alkoxy silane or siloxane and an organo-hydrosilane or siloxane and catalysts therefore is described and claimed.