摘要:
A matrix for retaining the electrolyte in a fuel cell is applied to the surface of one or both of the electrodes by screen printing using an inking vehicle which is an aqueous solution of polyethylene oxide. This method produces a very thin, continuous and uniform matrix layer and is well suited to production operations.
摘要:
A matrix for retaining the electrolyte in a fuel cell is applied to the surface of one or both of the electrodes by screen printing. In a preferred embodiment an aqueous solution of glycol is used as the inking vehicle to screen print a very thin, continuous and uniform matrix layer on the surface of an electrode.
摘要:
Spaced based burst power fuel cells generate large thermal loads in very short time periods. In order to avoid external venting or the use of heavy radiators in space vehicles, such fuel cells must include onboard closed-loop cooling systems. Utilizing subcooled ice as a cooling medium, contactable with either the anode, cathode or coolant recirculating stream provides the fuel cell with a safe, highly efficient and low weight heat absorption capability.
摘要:
Spaced based burst power fuel cells generate large thermal loads in very short time periods. In order to avoid external venting or the use of heavy radiators in space vehicles, such fuel cells must include onboard closed-loop cooling systems. Utilizing multiple heat sinks containing subcooled ice as a cooling medium, sequentially contactable with a coolant that passes through the fuel cell, provides a safe, highly efficient and low weight heat absorption capability.
摘要:
A seal structure 60 for a porous plate of an electrochemical cell, such as plates 18, 20, includes a sealing material disposed in a seal region 66 of the plate to form a hydrophilic barrier to gas with an electrolyte and a hydrophobic layer 62 to block the loss of electrolyte from the hydrophilic layer is disclosed. Various construction details including a method for making the plate are disclosed which increase the cross pressure the sealing region of the plate can withstand. In one embodiment, the seal region 66 is impregnated with powder having a low structure and predetermined particle size using a pressurized liquid carrier. A FEP Teflon film bonds adjacent electrolyte reservoir plates together.
摘要:
A new type of electrochemical cell which can be used for generating electricity or in an electrolysis mode for producing gases such as hydrogen and oxygen comprises laterally spaced apart or side-by-side catalyst layers as electrodes with the gap between the catalyst layers being bridged by a solid electrolyte which provides an ion conductive path from one catalyst layer to the other. The catalyst layers and the electrolyte are preferably in the form of thin films or layers on the surface of an inert supporting substrate. A plurality of these cells may be disposed on the substrate and interconnected electrically forming a network of series and parallel connected cells. Means are provided to feed fuel and oxidant to the electrodes either as separate gases or mixed together if appropriate catalytic materials are selected.
摘要:
The invention is a bi-zone water transport plate for a fuel cell wherein the plate includes a water permeability zone and a bubble barrier zone. The bubble barrier zone extends between all reactive perimeters of the plate, has a pore size of less than 20 microns, and has a thickness of less than 25 percent of a shortest distance between opposed contact surfaces of the plate. The water permeability zone has a pore size of at least 100 percent greater than the pore size of the bubble barrier zone, and has a thickness of greater than 75 percent of the shortest distance between the opposed contact surfaces of the plate. By having a separate bubble barrier zone, the plate affords enhanced water permeability while the bubble barrier maintains a gas seal.
摘要:
The concentration of carbon monoxide in a gaseous medium is reduced by selective catalytic oxidation in the presence of gaseous oxygen by passing the gaseous medium through a catalyst capable of oxidizing carbon monoxide in an exothermic reaction at temperatures within a given temperature range and by controlling the temperatures encountered in the catalyst in such a manner that the exothermic reaction takes place first above a threshold temperature below which the catalyst would be rapidly inactivated at the relatively high carbon monoxide concentrations present in the gaseous medium as it enters the catalyst, and subsequently, after the carbon monoxide concentration has been reduced to an acceptable level, at less than the threshold temperature to further reduce the carbon monoxide concentration to a desired minimum level below that achievable at temperatures above the threshold temperature.
摘要:
A seal structure 60 for a porous plate of an electrochemical cell, such as plates 18, 20, includes a sealing material disposed in a seal region 66 of the plate to form a hydrophilic barrier to gas with an electrolyte and a hydrophobic layer 62 to block the loss of electrolyte from the hydrophilic layer is disclosed. Various construction details including a method for making the plate are disclosed which increase the cross pressure the sealing region of the plate can withstand. In one embodiment, the seal region 66 is impregnated with powder having a low structure and predetermined particle size using a pressurized liquid carrier. A FEP Teflon film bonds adjacent electrolyte reservoir plates together.
摘要:
Molten carbonate fuel cell cathodes formed from a composition comprising oxides of nickel, lithium salts and barium salts having improved strength. These cathodes are fabricated by prefiring oxides of nickel and optionally lithium salts. The prefired powder is optionally leached with an organic acid and optional barium salts may be added. These powders are formed into an electrode and sintered. The resulting electrodes have improved strength.