公开(公告)号：US06620400B2

公开(公告)日：2003-09-16

申请号：US09952357

申请日：2001-09-12

申请人： Yuan Gao ,  Marina Yakovleva ,  Hugh H. Wang ,  John F. Engel

发明人： Yuan Gao ,  Marina Yakovleva ,  Hugh H. Wang ,  John F. Engel

IPC分类号： C01D1500

CPC分类号： H01M4/525 ,  C01G1/02 ,  C01G45/1228 ,  C01G51/42 ,  C01G51/44 ,  C01G53/42 ,  C01G53/44 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/86 ,  C01P2002/88 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/028

摘要： The present invention includes substantially single-phase lithium metal oxide compounds having hexagonal layered crystal structures that are substantially free of localized cubic spinel-like structural phases. The lithium metal oxides of the invention have the formula Li&agr;M&bgr;A&ggr;O2, wherein M is one or more transition metals, A is one or more dopants having an average oxidation state N such that +2.5≦N≦+3.5, 0.90≦&agr;≦1.10, and &bgr;+&ggr;=1. The present invention also includes dilithiated forms of these compounds, lithium and lithium-ion secondary batteries using these compounds as positive electrode materials, and methods of preparing these compounds.

摘要翻译： 本发明包括基本上没有局部立方尖晶石状结构相的具有六方层状晶体结构的单相锂金属氧化物化合物。 本发明的锂金属氧化物具有式LialphaMetaAgammaO2，其中M是一种或多种过渡金属，A是一种或多种具有平均氧化态N的掺杂剂，使得+2.5≤N≤3.5,0.90< = 1.10，β+γ= 1。 本发明还包括这些化合物的稀释形式，使用这些化合物作为正极材料的锂和锂离子二次电池及其制备方法。

公开(公告)号：US5605872A

公开(公告)日：1997-02-25

申请号：US459585

申请日：1995-06-02

申请人： John F. Engel ,  Conrad W. Kamienski ,  James A. Schwindeman ,  Randy W. Hall ,  Robert C. Morrison ,  B. Troy Dover

发明人： John F. Engel ,  Conrad W. Kamienski ,  James A. Schwindeman ,  Randy W. Hall ,  Robert C. Morrison ,  B. Troy Dover

IPC分类号： C08F4/46 ,  C08F4/48 ,  C08F12/04 ,  C08F36/04 ,  B01J31/12 ,  B01J31/18

CPC分类号： C08F12/04 ,  C08F36/04

摘要： A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of the following general structures: ##STR1## wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.

摘要翻译： 制备以下一般结构的单官能胺引发剂的烃溶液的方法：MQnZN（A（R1R2R3））2金属，选自锂，钠和钾，Q是衍生的饱和或不饱和烃基 通过并入选自共轭二烯烃和烯基取代的芳族烃的化合物; Z是含有3-25个碳原子的烃系链基团; A是选自元素周期表IVa的元素，R1，R2和R3独立地选自氢，烷基，取代的烷基，环烷基，芳基或取代的芳基，m是0-7的整数，n是 1至5的整数，通过该方法制备的单官能胺引发剂，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。

公开(公告)号：US5600021A

公开(公告)日：1997-02-04

申请号：US458602

申请日：1995-06-02

申请人： James A. Schwindeman ,  Eric J. Granger ,  John F. Engel ,  Conrad W. Kamienski

发明人： James A. Schwindeman ,  Eric J. Granger ,  John F. Engel ,  Conrad W. Kamienski

IPC分类号： C07F1/02 ,  C08C19/44 ,  C08F4/08 ,  C08F4/42 ,  C08F4/46 ,  C08F4/48 ,  C08F8/00 ,  C08F36/00 ,  C08F36/04 ,  C08F279/00 ,  C08F279/02 ,  C07C43/04

CPC分类号： C08C19/44 ,  C07F1/02 ,  C08F36/04 ,  C08F4/48

摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure:M--Z--O--C(R.sup.1 R.sup.2 R.sup.3)wherein M is an alkali metal; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, aryl or substituted aryl groups, and their employment as initiators in the anionic polymerization of olefin containing monomers in an inert, hydrocarbon solvent comprising reacting an omega-protected-1-haloalkyl with lithium metal dispersion having a particle size between 10 and 300 millimicrons in size, at a temperature between 35.degree. and 130.degree. C. in an alkane solvent containing 5 to 10 carbon atoms.

摘要翻译： 一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Z-O-C（R 1 R 2 R 3）其中M为碱金属; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; 并且R 1，R 2和R 3独立地选自氢，烷基，取代的烷基，芳基或取代的芳基，并且它们用作惰性烃溶剂中含烯烃单体的阴离子聚合中的引发剂，包括使ω-保护的 - 在具有5至10个碳原子的烷烃溶剂中，在35至130℃之间的温度下，具有尺寸在10-300毫微米之间的锂金属分散体的1-卤代烷基。

公开(公告)号：US5567774A

公开(公告)日：1996-10-22

申请号：US460300

申请日：1995-06-02

申请人： James A. Schwindeman ,  Eric J. Granger ,  John F. Engel ,  Conrad W. Kamienski

发明人： James A. Schwindeman ,  Eric J. Granger ,  John F. Engel ,  Conrad W. Kamienski

IPC分类号： C07F1/02 ,  C08C19/44 ,  C08F4/08 ,  C08F4/42 ,  C08F4/46 ,  C08F4/48 ,  C08F8/00 ,  C08F36/00 ,  C08F36/04 ,  C08F279/00 ,  C08F279/02 ,  C08F8/30 ,  C08F8/08

CPC分类号： C08C19/44 ,  C07F1/02 ,  C08F36/04 ,  C08F4/48

摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure:M--Z--O--C(R.sup.1 R.sup.2 R.sup.3)wherein M is an alkali metal; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, aryl or substituted aryl groups, and their employment as initiators in the anionic polymerization of olefin containing monomers in an inert, hydrocarbon solvent comprising reacting an omega-protected-1-haloalkyl with lithium metal dispersion having a particle size between 10 and 300 millimicrons in size, at a temperature between 35.degree. and 130.degree. C. in an alkane solvent containing 5 to 10 carbon atoms.

摘要翻译： 一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Z-O-C（R 1 R 2 R 3）其中M为碱金属; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; 并且R 1，R 2和R 3独立地选自氢，烷基，取代的烷基，芳基或取代的芳基，并且它们用作惰性烃溶剂中含烯烃单体的阴离子聚合中的引发剂，包括使ω-保护的 - 在具有5至10个碳原子的烷烃溶剂中，在35至130℃之间的温度下，具有尺寸在10-300毫微米之间的锂金属分散体的1-卤代烷基。

公开(公告)号：US5527753A

公开(公告)日：1996-06-18

申请号：US354998

申请日：1994-12-13

申请人： John F. Engel ,  Conrad W. Kamienski ,  James A. Schwindeman ,  Randy W. Hall ,  Robert C. Morrison ,  B. Troy Dover

发明人： John F. Engel ,  Conrad W. Kamienski ,  James A. Schwindeman ,  Randy W. Hall ,  Robert C. Morrison ,  B. Troy Dover

IPC分类号： C08F4/46 ,  C08F4/48 ,  C08F12/04 ,  C08F36/04 ,  B01J31/12 ,  B01J31/18

CPC分类号： C08F12/04 ,  C08F36/04

摘要： A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of the following general structures: ##STR1## wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.

摘要翻译： 制备以下一般结构的单官能胺引发剂的烃溶液的方法：MQnZN（A（R1R2R3））2金属，选自锂，钠和钾，Q是衍生的饱和或不饱和烃基 通过并入选自共轭二烯烃和烯基取代的芳族烃的化合物; Z是含有3-25个碳原子的烃系链基团; A是选自元素周期表IVa的元素，R1，R2和R3独立地选自氢，烷基，取代的烷基，环烷基，芳基或取代的芳基，m是0-7的整数，n是 1至5的整数，通过该方法制备的单官能胺引发剂，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。

公开(公告)号：US4395567A

公开(公告)日：1983-07-26

申请号：US327839

申请日：1981-12-07

申请人： John F. Engel

发明人： John F. Engel

IPC分类号： A01N37/10 ,  A01N53/00 ,  C07C57/38 ,  C07C61/40 ,  C07F9/54 ,  C07C69/743

CPC分类号： C07C57/38 ,  A01N37/10 ,  A01N53/00 ,  C07C61/40 ,  C07F9/5442

摘要： 1R,cis-trifluoromethylethenylcyclopropanecarbonyl compounds of the formula ##STR1## in which X is halogen and R is halogen, hydroxy, lower alkoxy or an optionally substituted 1,1'-biphenyl-3-methyloxy group, their method of preparation and utility as insecticides and intermediates therefore are described and exemplified.

摘要翻译： 1R，其中X为卤素且R为卤素，羟基，低级烷氧基或任选取代的1,1'-联苯-3-甲氧基的式“IMAGE”的顺式 - 三氟甲基乙酰基环丙烷羰基化合物，其制备方法及其用作杀虫剂 因此描述和示例中间体。

公开(公告)号：US4235927A

公开(公告)日：1980-11-25

申请号：US55212

申请日：1979-07-06

申请人： John F. Engel

发明人： John F. Engel

IPC分类号： A01N37/10 ,  A01N53/00 ,  A01N53/04 ,  C07C17/26 ,  C07C29/52 ,  C07C35/32 ,  C07C57/38 ,  C07C61/40 ,  C07F9/54 ,  A01N9/28 ,  C07D307/54

CPC分类号： C07F9/5442 ,  A01N37/10 ,  A01N53/00 ,  C07C17/2635 ,  C07C29/52 ,  C07C35/32 ,  C07C57/38 ,  C07C61/40

摘要： Perhaloalkylvinylcyclopropanecarboxylates having the general formula ##STR1## are disclosed wherein one of Y and Z is a perhaloalkyl group and the other is hydrogen, halogen, or lower alkyl. Compounds in which R is hydroxy, halogen or lower alkoxy are intermediates for preparation of insecticidal esters in which R is an optionally substituted benzylfurylmethoxy group. The insecticidal efficacy and preparation of the compounds and intermediates therefor are described and exemplified.

摘要翻译： 公开了具有通式“IMAGE”I的全卤代烷基乙烯基环丙烷羧酸酯，其中Y和Z之一是全卤代烷基，另一个是氢，卤素或低级烷基。 其中R是羟基，卤素或低级烷氧基的化合物是制备杀虫剂的中间体，其中R是任选取代的苄基甲氧基。 化合物及其中间体的杀虫功效及其制备方法进行了说明和实例。

公开(公告)号：US07074382B2

公开(公告)日：2006-07-11

申请号：US10170180

申请日：2002-06-12

申请人： Yuan Gao ,  Marina Yakovleva ,  Hugh H. Wang ,  John F. Engel

发明人： Yuan Gao ,  Marina Yakovleva ,  Hugh H. Wang ,  John F. Engel

IPC分类号： C01D15/00 ,  C01G51/00

CPC分类号： H01M4/525 ,  C01G1/02 ,  C01G45/1228 ,  C01G51/42 ,  C01G51/44 ,  C01G53/42 ,  C01G53/44 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/86 ,  C01P2002/88 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/028

摘要： The present invention includes substantially single-phase lithium metal oxide compounds having hexagonal layered crystal structures that are substantially free of localized cubic spinel-like structural phases. The lithium metal oxides of the invention have the formula LiαMβAγO2, wherein M is one or more transition metals, A is one or more dopants having an average oxidation state N such that +2.5≦N≦+3.5, 0.90≦α≦1.10, and β+γ=1. The present invention also includes dilithiated forms of these compounds, lithium and lithium-ion secondary batteries using these compounds as positive electrode materials, and methods of preparing these compounds.

摘要翻译： 本发明包括基本上没有局部立方尖晶石状结构相的具有六方层状晶体结构的单相锂金属氧化物化合物。 本发明的锂金属氧化物具有下式：其中M是 一种或多种过渡金属，A是一种或多种具有平均氧化态N的掺杂剂，使得+2.5≤N≤3.5,0.90<=α1= 1.10和β+γ= 1。 本发明还包括这些化合物的稀释形式，使用这些化合物作为正极材料的锂和锂离子二次电池及其制备方法。

公开(公告)号：US5332853A

公开(公告)日：1994-07-26

申请号：US92319

申请日：1993-07-14

申请人： Robert C. Morrison ,  Randy W. Hall ,  B. Troy Dover ,  Conrad W. Kamienski ,  John F. Engel

发明人： Robert C. Morrison ,  Randy W. Hall ,  B. Troy Dover ,  Conrad W. Kamienski ,  John F. Engel

IPC分类号： B01J31/02 ,  B01J31/12 ,  C07B61/00 ,  C07F1/00 ,  C07F1/02 ,  C07F7/08 ,  C07F7/12 ,  C07F7/04

CPC分类号： C07F1/02 ,  C07F1/00 ,  C07F7/0896 ,  C07F7/122

摘要： This application concerns a process for alkylating, in a hydrocarbon solvent reaction medium, metalloidal substrates such as alkylating a chlorosilane with an alkyllithium containing 3 to 8 carbon atoms by conducting these reactions in the presence of a catalyst selected from primary and secondary alcohols, and their respective metal alkoxides, cyclic ethers, hydrocarbyl ethers, hydrocarbyl silyl ethers, and tertiary amines.

摘要翻译： 本申请涉及一种在烃溶剂反应介质中烷基化的方法，例如通过在选自伯醇和仲醇的催化剂存在下进行这些反应而将含有3-8个碳原子的烷基锂烷基化氯代硅烷的金属基底， 各自的金属醇盐，环醚，烃基醚，烃基甲硅烷基醚和叔胺。

公开(公告)号：US5223536A

公开(公告)日：1993-06-29

申请号：US734421

申请日：1991-07-23

申请人： Thomas G. Cullen ,  Scott McN. Sieburth ,  Gary A. Meier ,  John F. Engel

发明人： Thomas G. Cullen ,  Scott McN. Sieburth ,  Gary A. Meier ,  John F. Engel

IPC分类号： A01N31/14 ,  A01N37/38 ,  A01N37/44 ,  C07C43/29 ,  C07D213/64 ,  C07D213/643

CPC分类号： C07D213/643 ,  A01N31/14 ,  A01N37/38 ,  A01N37/44 ,  C07C43/29 ,  C07C2101/02

摘要： The 1,4-diaryl-1-cyclopropyl-4-substituted butane pesticides of the following formula are effective as insecticides and acaricides: ##STR1## in which X and Y are independently hydrogen, halogen, alkyl, alkoxy, cycloalkylalkoxy, alkylcarbonyl, alkoxycarbonyl, haloalkyl, haloalkoxy, alkylthio, haloalkylthio, alkylsulfinyl, alkylsulfonyl, trialkylamino, nitro, or cyano; or X and Y together are --OCH.sub.2 O-- or --OCF.sub.2 O-- bridging the 2-3 or 3-4 positions of the phenyl ring; Ar is 3-phenoxyphenyl, 4-fluoro-3-phenoxyphenyl, 6-phenoxypyridin-2-yl, or 2-methyl(1,1'-biphenyl)-3-yl;R is cyano, methyl, trifluoromethyl, alkenyl, alkynyl, or halogen.

摘要翻译： 下式的1,4-二芳基-1-环丙基-4-取代丁烷农药作为杀虫剂和杀螨剂是有效的：其中X和Y独立地是氢，卤素，烷基，烷氧基，环烷基烷氧基，烷基羰基，烷氧基羰基 卤代烷基，卤代烷氧基，烷硫基，卤代烷硫基，烷基亚磺酰基，烷基磺酰基，三烷基氨基，硝基或氰基; 或X和Y一起是-OCH 2 O-或-OCF 2 O-桥接苯环的2-3或3-4位; Ar是3-苯氧基苯基，4-氟-3-苯氧基苯基，6-苯氧基吡啶-2-基或2-甲基（1,1'-联苯基）-3-基; R是氰基，甲基，三氟甲基，烯基，炔基或卤素。