摘要:
dicalcium phosphate is prepared from phosphate rock by a process which comprises reacting phosphate rock with sulfur dioxide and an organic carbonyl compound for 0.5 to 10 hours while maintaining the temperature of the reaction mixture below 50.degree. C. The reaction yields a mixture of gangue, solid calcium .alpha.-hydroxy sulfonate and soluble dicalcium phosphate. The solids are separated from the liquid and P.sub.2 O.sub.5 values adhering to the solid are washed free with a mixture of carbonyl, water, and sulfur dioxide. The wash effluent is recycled to the process and both carbonyl and some sulfur dioxide are recovered from the filter cake by heating it. The offgas from the heated filter cake is recycled to the process and the dry filter cake, now largely calcium sulfite hemihydrate, is discarded.Dicalcium phosphate is precipitated from the reaction mixture filtrate in high yield by partially distilling sulfur dioxide from the filtrate. The precipitated anhydrous dicalcium phosphate is separated from the liquid and dried. Offgas from this drying process as well as both distillate and filtrate is returned to the process. Thus, the only starting materials consumed in the process are phosphate rock and sulfur dioxide. All carbonyl is recovered for recycle.
摘要:
a method of recovering uranium from wet-process phosphoric acid wherein the acid is treated with a mixture of an ammonium salt or ammonia, a metallic reducing agent such as iron, aluminum or zinc, and then a miscible solvent such as methanol. The precipitated solids, which are separated from the purified phosphoric acid, consist of a mixture of metal phosphates and uranium. This solid is dissolved in acid and the uranium recovered from the solution by liquid-liquid solvent extraction. The miscible solvent and some water are distilled away from the purified phosphoric acid. The distillate is rectified, the water discarded, and the miscible solvent recovered for recycle.When the miscible solvent is methanol, the optimum ranges of ammonia and methanol are 0.05 to 0.20 gram atom nitrogen per gram atom phosphorus and 1.93 to 3.15 pounds methanol per pound of orthophosphoric acid. The amount of reducing agent added should be sufficient to reduce all uraniun to U(IV). Under these conditions, >99 percent of the uranium is precipitated from the wet-process acid. About 90 percent of the phosphorus in the acid is recovered as purified phosphoric acid.
摘要:
A method of preparing dicalcium phosphate from phosphate rock wherein the rock is treated with a mixture of water, carbonyl, and sulfur dioxide. Solids are separated from the liquid phase. The solid phase consists of a mixture of gangue, and calcium .alpha.-hydroxysulfonate. Carbonyl and part of the sulfur dioxide are recovered from the solid by low temperature thermal decomposition. Dicalcium phosphate is precipitated from the liquid phase by partial distilling of SO.sub.2. All carbonyl is recovered for recycle.
摘要:
A method of recovering uranium from wet-process phosphoric acid wherein the acid is treated with a mixture of an ammonium salt or ammonia, a reducing agent, and then a miscible solvent. Solids are separated from the phosphoric acid liquid phase. The solid consists of a mixture of metal phosphates and uranium. It is washed free of adhering phosphoric acid with fresh miscible solvent. The solid is dried and dissolved in acid whereupon uranium is recovered from the solution. Miscible solvent and water are distilled away from the phosphoric acid. The distillate is rectified and water discarded. All miscible solvent is recovered for recycle.
摘要:
A method of selectively extracting calcite and dolomite away from apatite in phosphate rock or phosphatic limestone wherein the phosphate rock or phosphatic limestone is treated with a mixture of sulfur dioxide, water, and a carbonyl compound. Solids are separated from the liquid phase. The solids consist principally of apatite admixed with clay, quartz, and other accessory minerals originally in the rock. The solids are heated to drive off adhering sulfur dioxide, water, and carbonyl. The liquid phase consists of carbonyl, water, sulfur dioxide, and magnesium and calcium ions. Heating this liquid preferentially precipitates CaSO.sub.3.1/2H.sub.2 O. This solid is filtered off and the filtrate further heated to precipitate MgSO.sub.3.3H.sub.2 O largely free of CaSO.sub.3.1/2H.sub.2 O. All offgas and filtrate is returned to the process. Examination of extraction results shows that high temperature extraction favors dolomite extraction and low temperature extraction favors apatite extraction. Thus, operating at elevated temperature allows dolomite to be selectively extracted from the apatite in phosphate rock.
摘要:
A method of selectively extracting calcite and dolomite away from apatite in phosphate rock or phosphatic limestone wherein the phosphate rock or phosphatic limestone is treated with a mixture of sulfur dioxide, water, and a carbonyl compound. Solids are separated from the liquid phase. The solids consist principally of apatite admixed with clay, quartz, and other accessory minerals originally in the rock. The solids are heated to drive off adhering sulfur dioxide, water, and carbonyl. The liquid phase consists of carbonyl, water, sulfur dioxide, and magnesium and calcium ions. Heating this liquid preferentially precipitates CaSO.sub.3.1/2H.sub.2 O. This solid is filtered off and the filtrate further heated to precipitate MgSO.sub.3.3H.sub.2 O largely free of CaSO.sub.3.1/2H.sub.2 O. All off gas and filtrate is returned to the process.
摘要:
a process for the removal and recovery of sulfur oxides from gas streams by contacting the gas stream with an aqueous suspension of melamine containing an oxidation inhibitor such as para-phenylenediamine whereupon a mixture of solid, hydrated melamine sulfites and solid, hydrated melamine sulfate is formed. The solids are then separated from the reaction product and the clarified liquid recycled. The solids are then heated to temperatures up to 200.degree. C to decompose the hydrated melamine sulfites into free melamine, gaseous water, and sulfur dioxide, and the gaseous water and sulfur dioxide withdrawn as product. The hot solids are cooled and split into two portions. One portion is recycled and the other portion is treated with an aqueous inorganic base stronger than melamine such as ammonia or potassium hydroxide to decompose the contained melamine sulfate into free melamine and a basic sulfate salt solution. The basic sulfate salt solution is separated from the melamine and withdrawn as product and the melamine is recycled to the process.
摘要:
A process for the removal and recovery of sulfur oxides from gas streams by contacting the gas stream with an aqueous suspension of melamine whereupon a mixture of solid, hydrated melamine sulfites, hydrated melamine sulfate is formed. The solids are separated from the reaction product and the clarified liquid recycled. The solids are then heated to temperatures up to 200.degree. C. to decompose the hydrated melamine sulfites into free melamine, gaseous water, and sulfur dioxide, and the gaseous water and sulfur dioxide withdrawn as product. The hot solids are cooled and split into two portions. One portion is recycled and the other portion is treated with a base stronger than melamine to decompose the contained melamine sulfate into free melamine and a basic sulfate salt solution. The basic sulfate salt solution is separated from the melamine and withdrawn as product and the melamine is recycled to the process.
摘要:
Embodiment No. 1. Urea phosphate prepared from wet-process phosphoric acid is heated with monopotassium orthophosphate in a mole ratio of 0.25 to 4.0 at 130.degree. to 200.degree. C. to form an ammonium potassium polyphosphate having an average chain length between 1.2 and 2.5. The ammonium potassium polyphosphate is dissolved in aqueous ammonia to yield concentrated fertilizer solutions containing the three major nutrients and over 50 percent total plant food.Embodiment No. 2. Phosphoric acid containing 54 to 76 percent P.sub.2 O.sub.5 is heated with urea (urea:H.sub.3 PO.sub.4 mole ratio 0.5 to 2.0) and monopotassium orthophosphate (urea:KH.sub.2 PO.sub.4 mole ratio 0.25 to 4.0) at 130.degree. to 200.degree. C. to form an ammonium potassium polyphosphate having an average chain length between 1.2 and 2.5. The ammonium potassium polyphosphate is dissolved in aqueous ammonia to yield concentrated fertilizer solutions containing the three major nutrients and over 50 percent total plant food.
摘要翻译:实施例1:由湿法磷酸制备的磷酸尿素在130〜200℃下以0.25〜4.0的摩尔比与正磷酸单钾一起加热,形成平均链长为1.2〜2.5的多磷酸铵钾 。 将多磷酸铵钾溶解在氨水中,得到含有三种主要营养素和超过50%总植物食物的浓缩肥料溶液。 实施例2:在130〜200℃下,将含有54〜76%的P2O5的磷酸与尿素(尿素:H 3 PO 4的摩尔比为0.5〜2.0)和一磷酸一钾(尿素:KH 2 PO 4的摩尔比为0.25〜4.0)加热,形成 平均链长为1.2〜2.5的多磷酸铵钾。 将多磷酸铵钾溶解在氨水中,得到含有三种主要营养素和超过50%总植物食物的浓缩肥料溶液。
摘要:
Purified diammonium phosphate is produced by neutralizing relatively pure melamine orthophosphate, prepared from wet-process phosphoric acid, with ammonia in a hot solution of diammonium phosphate to give a slurry of melamine in concentrated diammonium phosphate solution. The liberated melamine is virtually insoluble in concentrated diammonium phosphate solutions; it is filtered from the hot mixture, washed, and recycled to produce more melamine phosphate by reaction with wet-process phosphoric acid. The hot, concentrated diammonium phosphate filtrate is cooled to precipitate purified diammonium phosphate crystals. The product is separated from its mother liquor by filtration, and the resulting filtrate is recycled to the reactor. The small amount of impurities introduced with the melamine phosphate are removed partly with the liberated melamine and partly by centrifugation of the diammonium phosphate solution. The only starting materials for the process are phosphoric acid and ammonia.