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    Electrochromic polymers and polymer electrochromic devices
    1.
    发明授权
    Electrochromic polymers and polymer electrochromic devices 有权
    电致变色聚合物和聚合物电致变色器件

    公开(公告)号：US06791738B2

    公开(公告)日：2004-09-14

    申请号：US10302164

    申请日：2002-11-21

    申请人： John R. Reynolds ,  Kyukwan Zong ,  Irina Schwendeman ,  Gursel Sonmez ,  Philippe Schottland ,  Avni A. Argun ,  Pierre-Henri Aubert

    发明人： John R. Reynolds ,  Kyukwan Zong ,  Irina Schwendeman ,  Gursel Sonmez ,  Philippe Schottland ,  Avni A. Argun ,  Pierre-Henri Aubert

    IPC分类号： G02F115

    CPC分类号： C09K9/02 ,  C08G61/123 ,  C08G61/124 ,  C08G61/126 ,  G02F2001/1502

    摘要： The subject invention pertains to electrochromic polymers and polymer electrochromic devices. In a specific embodiment, two complementary polymers can be matched and incorporated into dual polymer electrochromic devices. The anodically coloring polymers in accordance with the subject invention can allow control over the color, brightness, and environmental stability of an electrochromic window. In addition, high device contrast ratios, high transmittance changes, and high luminance changes can be achieved, along with half-second switching times for full color change. Also provided are electrochromic devices such as advertising signage, video monitors, stadium scoreboards, computers, announcement boards, warning systems for cell phones, warning/information systems for automobiles, greeting cards, electrochromic windows, billboards, electronic books, and electrical wiring. The subject invention also provides for the use of complementary electrochromic polymers in the manufacture of electrochromic devices. In some embodiments, the devices of the invention can be prepared using metal vapor deposition or line patterning.

    摘要翻译： 本发明涉及电致变色聚合物和聚合物电致变色装置。 在一个具体的实施方案中，两个互补的聚合物可以匹配并结合到双聚合物电致变色装置中。 根据本发明的阳极着色聚合物可以控制电致变色窗的颜色，亮度和环境稳定性。 此外，可以实现高器件对比度，高透射率变化和高亮度变化，以及全色变化的半秒切换时间。 还提供了诸如广告标牌，视频监视器，体育场记分牌，计算机，公告板，手机警告系统，汽车警告/信息系统，贺卡，电致变色窗，广告牌，电子书和电线的电致变色装置。 本发明还提供了互补电致变色聚合物在制造电致变色器件中的应用。 在一些实施例中，可以使用金属气相沉积或线图案化来制备本发明的装置。

    Process for preparing a compound containing a heteroaromatic group with one or more ether substituents
    2.
    发明授权
    Process for preparing a compound containing a heteroaromatic group with one or more ether substituents 失效
    制备含有一个或多个醚取代基的杂芳族基团的化合物的方法

    公开(公告)号：US06734312B2

    公开(公告)日：2004-05-11

    申请号：US10325424

    申请日：2002-12-20

    申请人： John R. Reynolds ,  Bert Groenendaal ,  Kyukwan Zong ,  Luis Madrigal

    发明人： John R. Reynolds ,  Bert Groenendaal ,  Kyukwan Zong ,  Luis Madrigal

    IPC分类号： C07D49502

    CPC分类号： C07D491/04 ,  C07D495/04

    摘要： A process for preparing a heteroaromatic compound having a heteroaromatic nucleus substituted with one or more ether groups comprising the step of: condensing at least one hydroxy-group of a compound having said heteroaromatic nucleus, said at least one hydroxy group (—OH) being substituted at &agr;- or &bgr;-positions with respect to a heteroatom of said heteroaromatic nucleus, with an alcohol containing one or more primary or secondary alcohol groups, optionally substituted with nitro, amide, ester, halogen, cyano or (hetero)aromatic groups, using the redox couple of a triaryl- or trialkylphosphine and an azodioxo-compound at a temperature between −40° C. and 160° C.

    摘要翻译： 一种制备具有被一个或多个醚基取代的杂芳族核的杂芳族化合物的方法，包括以下步骤：将具有所述杂芳族核的化合物的至少一个羟基缩合，所述至少一个羟基（-OH）被取代 含有一个或多个伯或仲醇基的醇，任选被硝基，酰胺，酯，卤素，氰基或（杂）芳族基团取代的醇，使用在所述杂芳族核的杂原子的α位或β位上，使用 在-40℃至160℃的温度下，三芳基 - 或三烷基膦和偶氮二氧化合物的氧化还原对。