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    Production of detergent range alcohols and ketones using porphyrin catalysts
    1.
    发明授权
    Production of detergent range alcohols and ketones using porphyrin catalysts 失效
    使用卟啉催化剂生产洗涤剂范围的醇和酮

    公开(公告)号：US4978799A

    公开(公告)日：1990-12-18

    申请号：US428812

    申请日：1989-10-30

    Applicant: John R. Sanderson ,  Edward T. Marquis ,  Howard F. Payton

    Inventor： John R. Sanderson ,  Edward T. Marquis ,  Howard F. Payton

    IPC: C07C29/48 ,  C07C45/28

    CPC classification number: C07C45/28 ,  C07C29/48

    Abstract: A process for the production of detergent range alcohols and ketones by reacting an alkane with a hydroperoxide in the presence of a transition metal porphyrin catalyst is described. Preferred hydroperoxides include cumene hydroperoxide and tertiary butyl hydroperoxide. The transition metal porphyrin catalyst may be transition metal phthalocyanines, transition metalloporphines and the like. The transition metal itself may be iron, manganese, cobalt and mixtures thereof. Suitable ligands include, but are not limited to imidazoles and lithium borate. Other useful additives include alkali metal perchlorates, such as sodium perchlorate, iodosylbenzene and alkali metal superoxides, such as potassium superoxide, and phase transfer catalysts such as tetrabutyl ammonium bromide.

    Abstract translation: 描述了在过渡金属卟啉催化剂存在下通过使烷烃与氢过氧化物反应来生产洗涤剂范围的醇和酮的方法。 优选的氢过氧化物包括氢过氧化枯烯和叔丁基过氧化氢。 过渡金属卟啉催化剂可以是过渡金属酞菁，过渡金属卟啉等。 过渡金属本身可以是铁，锰，钴及其混合物。 合适的配体包括但不限于咪唑和硼酸锂。 其它有用的添加剂包括碱金属高氯酸盐如高氯酸钠，碘代苯和碱金属超氧化物如超氧化钾，以及相转移催化剂如四丁基溴化铵。

    Ketone derivatives of polyoxypropylene glycols
    4.
    发明授权
    Ketone derivatives of polyoxypropylene glycols 失效
    聚氧丙烯二醇的酮衍生物

    公开(公告)号：US4980514A

    公开(公告)日：1990-12-25

    申请号：US444211

    申请日：1989-12-01

    Applicant: John R. Sanderson ,  Edward T. Marquis

    Inventor： John R. Sanderson ,  Edward T. Marquis

    IPC: B01J23/46 ,  C07B61/00 ,  C07C45/29 ,  C07C45/30 ,  C07C49/175 ,  C08G65/32

    CPC classification number: C07C49/175 ,  C07C45/29 ,  C07C45/30

    Abstract: Diketones useful as intermediates for reaction with carboxylic acids to provide surfactants and for reaction with amine adducts to provide fuel additives are prepared from polyoxyalkylene glycols having a molecular weight of about 200 to about 2,000 and having the formula: ##STR1## wherein R is hydrogen or methyl and wherein n is a positive number having a value of 1 to about 50,The polyoxyalkylene polyol is oxidized in the presence of a halogenated alkane solvent and a ruthenium catalyst with an alkali metal or alkaline earth metal hypochlorite at a temperature of about 10.degree. to about 50.degree. C. and a pressure of about 0 to 1,000 psig. over a period of about 10 to about 20 hours to provide the corresponding diketone having the formula: ##STR2## wherein R and n have the meaning given above.

    Abstract translation: 可用作与羧酸反应以提供表面活性剂和与胺加合物反应以提供燃料添加剂的中间体的二酮由具有约200至约2,000的分子量的聚氧亚烷基二醇制备，具有下式：其中R 是氢或甲基，其中n为1至约50的正数。聚氧化烯多元醇在卤化烷烃溶剂和钌催化剂存在下，在碱金属或碱土金属次氯酸盐的存在下，在 约10℃至约50℃，压力为约0至1,000psig。 在约10至约20小时的时间内提供具有下式的相应二酮：其中R和n具有上述含义。

    Catalyst production of tertiary butyl alcohol from tertiary butyl hydroperoxide
    5.
    发明授权
    Catalyst production of tertiary butyl alcohol from tertiary butyl hydroperoxide 失效
    催化剂由叔丁基过氧化氢生产叔丁醇

    公开(公告)号：US4910349A

    公开(公告)日：1990-03-20

    申请号：US94173

    申请日：1987-09-08

    Applicant: John R. Sanderson ,  John F. Knifton ,  Edward T. Marquis

    Inventor： John R. Sanderson ,  John F. Knifton ,  Edward T. Marquis

    IPC: C07C29/132

    CPC classification number: C07C29/132

    Abstract: Tertiary butyl alcohol is prepared by the catalytic decomposition of tertiary butyl hydroperoxide, preferably in solution in tertiary butyl alcohol, in the presence of a metal phthalocyanine catalyst promoted with a rhenium compound, such as a phthalocyanine of a metal of Group IB, Group VIIB or Group VIIIB of the Periodic Table (e.g., chloroferric phthalocyanine and rhenium heptoxide-p-dioxane or oxotrichloro-bis-(triphenylphosphine) rhenium V).

    Abstract translation: 通过叔丁基过氧化氢的催化分解，优选在叔丁醇的溶液中，在用铼化合物，如IB组金属，ⅦB族金属的酞菁等促进的金属酞菁催化剂的存在下，制备叔丁醇， 元素周期表VIIIB组（例如，氯代酞菁和铼的叔丁醇钌或氧三氯 - 双 - （三苯基膦）铼V）。

    Synthesis of vanadium/propylene glycol complexes
    6.
    发明授权
    Synthesis of vanadium/propylene glycol complexes 失效
    钒/丙二醇配合物的合成

    公开(公告)号：US4722919A

    公开(公告)日：1988-02-02

    申请号：US916075

    申请日：1986-10-06

    Applicant: Edward T. Marquis ,  John R. Sanderson

    Inventor： Edward T. Marquis ,  John R. Sanderson

    IPC: B01J31/22

    CPC classification number: B01J31/223 ,  B01J31/4092 ,  B01J2231/72 ,  B01J2531/56

    Abstract: Complexes made by reacting propylene glycol with a vanadium compound soluble therein at an elevated temperature. Mild stripping of the water subsequent to complex formation is preferred. The ratio of moles of propylene glycol to gram atoms of vanadium in the complex forming reaction ranges from 7:1 to 20:1.

    Abstract translation: 通过使丙二醇与可溶于其中的钒化合物在升高的温度下反应制得的络合物。 复合物形成后水的轻度汽提是优选的。 络合物形成反应中丙二醇与钒原子数的摩尔比为7:1至20:1。

    Synthetic lubricant base stocks by co-reaction of olefins and anisole compounds
    8.
    发明授权
    Synthetic lubricant base stocks by co-reaction of olefins and anisole compounds 失效
    通过烯烃和苯甲醚化合物的共反应合成润滑剂基础油料

    公开(公告)号：US5202040A

    公开(公告)日：1993-04-13

    申请号：US536906

    申请日：1990-06-12

    Applicant: John R. Sanderson ,  Edward T. Marquis

    Inventor： John R. Sanderson ,  Edward T. Marquis

    IPC: C10M111/04

    CPC classification number: C10M111/04 ,  C10M2203/06 ,  C10M2205/028 ,  C10M2205/0285 ,  C10M2207/04 ,  C10M2207/0406

    Abstract: Synthetic lubricant base stocks having an increased viscosity are disclosed. These synthetic lubricant base stocks comprises a mixture of (1) oligomers prepared from a linear olefin having from 10 to 24 carbon atoms; and (2) alkylated anisole having an alkyl group containing from 10 to 24 carbon atoms. These synthetic lubricant base stocks may be prepared by co-reacting a linear olefin having from 10 to 24 carbon atoms and anisole. Optionally, the mixture of oligomers and alkylated anisoles may be hydrogenated, to prepare a mixture of reduced oligomers and alkylated methoxycyclohexanes.

    Abstract translation: 公开了具有增加粘度的合成润滑剂基础油料。 这些合成润滑剂基础油料包含（1）由具有10-24个碳原子的直链烯烃制备的低聚物的混合物; 和（2）具有含有10-24个碳原子的烷基的烷基化苯甲醚。 这些合成润滑剂基础油料可以通过使具有10-24个碳原子的直链烯烃与苯甲醚共反应来制备。 任选地，可以将低聚物和烷基化茴香醚的混合物氢化，以制备还原性低聚物和烷基化甲氧基环己烷的混合物。

    Production of detergent range alcohols and ketones using acetylacetonate catalysts
    10.
    发明授权
    Production of detergent range alcohols and ketones using acetylacetonate catalysts 失效
    使用乙酰丙酮催化剂生产洗涤剂范围的醇和酮

    公开(公告)号：US4978800A

    公开(公告)日：1990-12-18

    申请号：US428703

    申请日：1989-10-30

    Applicant: John R. Sanderson ,  Edward T. Marquis ,  John F. Knifton

    Inventor： John R. Sanderson ,  Edward T. Marquis ,  John F. Knifton

    IPC: C07C29/48 ,  C07C45/28

    CPC classification number: C07C29/48 ,  C07C45/28

    Abstract: A process for the production of detergent range alcohols and ketones by reacting an alkane with a hydroperoxide in the presence of a transition metal acetylacetonate catalyst is described. Preferred hydroperoxides include cumene hydroperoxide and tertiary butyl hydroperoxide. The transition metal itself may be iron, ruthenium, chromium and mixtures thereof. If iron acetylacetonate is used as a catalyst, copper (II) acetate may be usefully employed as a co-catalyst.

    Abstract translation: 描述了在过渡金属乙酰丙酮化物催化剂存在下通过使烷烃与氢过氧化物反应来生产洗涤剂范围的醇和酮的方法。 优选的氢过氧化物包括氢过氧化枯烯和叔丁基过氧化氢。 过渡金属本身可以是铁，钌，铬及其混合物。 如果使用乙酰丙酮铁作为催化剂，乙酸铜（II）可用作助催化剂。

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