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    Purification of cumene recycle streams
    3.
    发明授权
    Purification of cumene recycle streams 失效
    异丙苯循环物流的净化

    公开(公告)号：US5025112A

    公开(公告)日：1991-06-18

    申请号：US580035

    申请日：1990-09-10

    Applicant: John R. Sanderson ,  Edward T. Marquis ,  John F. Knifton

    Inventor： John R. Sanderson ,  Edward T. Marquis ,  John F. Knifton

    IPC: B01J21/16 ,  B01J27/182 ,  C07B61/00 ,  C07C7/148 ,  C07C15/085

    CPC classification number: C07C7/148 ,  Y02P20/52

    Abstract: A method for purifying a cumene recycle stream by removing 2-phenyl-2-propanol and cumene hydroperoxide before the cumene is distilled and recycled to the peroxidation reactor which comprises reacting the recycle cumene in the presence of an acid treated montmorillonite clay of the formula:M.sub.x/n.sup.n+.sub..y H.sub.2 O(Al.sub.4-x Mg.sub.x) (Si.sub.8)O.sub.20 (OH).sub.4or in the presence of a catalyst comprising phosphoric acid on silica.

    Abstract translation: 一种在异丙基苯蒸馏并再循环至过氧化反应器之前通过除去2-苯基-2-丙醇和异丙基氢过氧化氢来净化枯烯循环物流的方法，该方法包括在下列通式的酸处理蒙脱石粘土存在下使回收枯烯反应： Mx / nn + .yH2O（Al4-xMgx）（Si8）O20（OH）4或在二氧化硅上含有磷酸的催化剂存在下进行。

    Catalytic decomposition of tertiary butyl hydroperoxide
    4.
    发明授权
    Catalytic decomposition of tertiary butyl hydroperoxide 失效
    叔丁基过氧化氢的催化分解

    公开(公告)号：US4912266A

    公开(公告)日：1990-03-27

    申请号：US94174

    申请日：1987-09-08

    Applicant: John R. Sanderson ,  John F. Knifton ,  Edward T. Marquis ,  Mark A. Mueller

    Inventor： John R. Sanderson ,  John F. Knifton ,  Edward T. Marquis ,  Mark A. Mueller

    IPC: C07C29/132

    CPC classification number: C07C29/132

    Abstract: In order to prepare a feedstock, isobutane is reacted with oxygen in an oxidation zone to provide an oxidation product comprising a solution of tertiary butyl hydroperoxide in unreacted isobutane. A catalyst may be present to catalyze the reaction of the oxygen with the isobutane if desired.The feedstock is charged to a catalytic decomposition zone wherein the tertiary butyl hydroperoxide is decomposed in the presence of an imidazole-promoted metal phthalocyanine catalyst to provide a decomposition reaction product characterized by a compartively high conversion rate and a compartively high selectively of tertiary butyl hydroperoxide to tertiary butyl alcohol.

    Abstract translation: 为了制备原料，异丁烷在氧化区与氧反应以提供包含叔丁基过氧化氢在未反应的异丁烷中的溶液的氧化产物。 如果需要，可以存在催化剂来催化氧与异丁烷的反应。 将原料装入催化分解区，其中叔丁基过氧化氢在咪唑促进金属酞菁催化剂存在下分解，得到特征在于高转化率和高选择性的叔丁基过氧化氢的分解反应产物， 叔丁醇。

    Process for preparing oligomers having low unsaturation
    5.
    发明授权
    Process for preparing oligomers having low unsaturation 失效
    制备具有低不均匀性的低聚物的方法

    公开(公告)号：US5233116A

    公开(公告)日：1993-08-03

    申请号：US705435

    申请日：1991-05-24

    Applicant: John R. Sanderson ,  John F. Knifton ,  Edward T. Marquis

    Inventor： John R. Sanderson ,  John F. Knifton ,  Edward T. Marquis

    IPC: B01J21/16 ,  C07B61/00 ,  C07C2/08 ,  C07C2/14 ,  C07C11/02

    CPC classification number: C07C2/08 ,  C07C2521/16

    Abstract: Synthetic lubricant base stocks may be prepared in good yield by oligomerizing linear olefin monomers using certain acidic calcium montmorillonite clay catalysts. When the oligomers are prepared at a temperature greater than about 200.degree. C., and any unreacted linear olefin monomer is removed, oligomers having an iodine value less than about 3 mg/g are obtained. An even lower iodine value is obtained when a hydrocarbon possessing a tertiary hydrogen is mixed with the linear olefin feed, and the mixture is contacted with the clay at a temperature greater than about 200.degree. C. Little or no hydrogenation may be required of oligomers prepared in this manner to obtain base stocks suitable for use as synthetic lubricants.

    Catalyst production of tertiary butyl alcohol from tertiary butyl hydroperoxide
    7.
    发明授权
    Catalyst production of tertiary butyl alcohol from tertiary butyl hydroperoxide 失效
    催化剂由叔丁基过氧化氢生产叔丁醇

    公开(公告)号：US4910349A

    公开(公告)日：1990-03-20

    申请号：US94173

    申请日：1987-09-08

    Applicant: John R. Sanderson ,  John F. Knifton ,  Edward T. Marquis

    Inventor： John R. Sanderson ,  John F. Knifton ,  Edward T. Marquis

    IPC: C07C29/132

    CPC classification number: C07C29/132

    Abstract: Tertiary butyl alcohol is prepared by the catalytic decomposition of tertiary butyl hydroperoxide, preferably in solution in tertiary butyl alcohol, in the presence of a metal phthalocyanine catalyst promoted with a rhenium compound, such as a phthalocyanine of a metal of Group IB, Group VIIB or Group VIIIB of the Periodic Table (e.g., chloroferric phthalocyanine and rhenium heptoxide-p-dioxane or oxotrichloro-bis-(triphenylphosphine) rhenium V).

    Abstract translation: 通过叔丁基过氧化氢的催化分解，优选在叔丁醇的溶液中，在用铼化合物，如IB组金属，ⅦB族金属的酞菁等促进的金属酞菁催化剂的存在下，制备叔丁醇， 元素周期表VIIIB组（例如，氯代酞菁和铼的叔丁醇钌或氧三氯 - 双 - （三苯基膦）铼V）。

    Production of detergent range alcohols and ketones using acetylacetonate catalysts
    8.
    发明授权
    Production of detergent range alcohols and ketones using acetylacetonate catalysts 失效
    使用乙酰丙酮催化剂生产洗涤剂范围的醇和酮

    公开(公告)号：US4978800A

    公开(公告)日：1990-12-18

    申请号：US428703

    申请日：1989-10-30

    Applicant: John R. Sanderson ,  Edward T. Marquis ,  John F. Knifton

    Inventor： John R. Sanderson ,  Edward T. Marquis ,  John F. Knifton

    IPC: C07C29/48 ,  C07C45/28

    CPC classification number: C07C29/48 ,  C07C45/28

    Abstract: A process for the production of detergent range alcohols and ketones by reacting an alkane with a hydroperoxide in the presence of a transition metal acetylacetonate catalyst is described. Preferred hydroperoxides include cumene hydroperoxide and tertiary butyl hydroperoxide. The transition metal itself may be iron, ruthenium, chromium and mixtures thereof. If iron acetylacetonate is used as a catalyst, copper (II) acetate may be usefully employed as a co-catalyst.

    Abstract translation: 描述了在过渡金属乙酰丙酮化物催化剂存在下通过使烷烃与氢过氧化物反应来生产洗涤剂范围的醇和酮的方法。 优选的氢过氧化物包括氢过氧化枯烯和叔丁基过氧化氢。 过渡金属本身可以是铁，钌，铬及其混合物。 如果使用乙酰丙酮铁作为催化剂，乙酸铜（II）可用作助催化剂。

    Tertiary butyl hydroperoxide decomposition
    9.
    发明授权
    Tertiary butyl hydroperoxide decomposition 失效
    叔丁基过氧化氢分解

    公开(公告)号：US4922036A

    公开(公告)日：1990-05-01

    申请号：US94175

    申请日：1987-09-08

    Applicant: John R. Sanderson ,  Edward T. Marquis ,  John F. Knifton

    Inventor： John R. Sanderson ,  Edward T. Marquis ,  John F. Knifton

    IPC: C07C29/132

    CPC classification number: C07C29/132

    Abstract: Tertiary butyl alcohol is prepared by the catalytic decomposition of tertiary butyl hydroperoxide, preferably in solution in tertiary butyl alcohol, in the presence of a borate-promoted metal phthalocyanine catalyst such as a Group IB, VIIB or VIIIB metal phthalocyanine and a Group IA, IIA or IIB metal borate, for example, chloroferric phthalocyanine and lithium borate, barium borate, zinc borate or sodium metaborate.

    Abstract translation: 在硼酸盐促进的金属酞菁催化剂如IB，VIIB或VIIIB族金属酞菁和IAA IIA族的存在下，通过叔丁基过氧化氢的催化分解，优选在叔丁醇溶液中催化分解叔丁醇。 或IIB金属硼酸盐，例如氯代酞菁和硼酸锂，硼酸钡，硼酸锌或偏硼酸钠。

    Olefin epoxidation of olefins in a polar medium
    10.
    发明授权
    Olefin epoxidation of olefins in a polar medium 失效
    烯烃在极性介质中的烯烃环氧化

    公开(公告)号：US4891437A

    公开(公告)日：1990-01-02

    申请号：US133664

    申请日：1987-12-16

    Applicant: Edward T. Marquis ,  Kenneth P. Keating ,  John F. Knifton ,  William A. Smith ,  John R. Sanderson ,  Jonathan Lustri

    Inventor： Edward T. Marquis ,  Kenneth P. Keating ,  John F. Knifton ,  William A. Smith ,  John R. Sanderson ,  Jonathan Lustri

    IPC: C07D301/19 ,  C07D303/04

    CPC classification number: C07D301/19 ,  C07D303/04

    Abstract: A hydroperoxide charge stock (t-butyl hydroperoxide or t-amyl hydroperoxide) is reacted with a C.sub.3 to C.sub.20 olefin charge stock in liquid phase in a reaction zone in the presence of a catalytically effective amount of a soluble molybdenum catalyst to form a product olefin epoxide corresponding to the olefin charge stock and a product alcohol corresponding to the hydroperoxide charge (t-butyl alcohol or t-amyl alcohol), which process is improved in accordance with the present invention by maintaining a reaction medium composed of more than 60 wt % of polar components (hydroperoxide charge stock, product alcohol and product epoxide) in the reaction zone by charging to the reaction zone at least about a 30 wt % solution of the hydroperoxide charge stock in the corresponding product alcohol and charging said olefin charge stock to said reaction zone in an amount relative to the amount of said charged solution of charged hydroperoxide in product alcohol sufficient to provide a ratio of from about 0.5 to about 2 moles of charged olefin per mole of charged hydroperoxide.The preferred olefin charge stock is propylene and the preferred hydroperoxide charge stock is t-butyl hydroperoxide. The corresponding epoxide in this situation is propylene oxide and the corresponding product alcohol is t-butyl alcohol.

    Abstract translation: 在催化有效量的可溶性钼催化剂的存在下，将氢过氧化物电荷原料（叔丁基过氧化氢或叔戊基过氧化氢）与液相中的C3至C20烯烃加料原料在反应区中反应以形成产物烯烃 对应于烯烃电荷原料的环氧化物和对应于氢过氧化物电荷的产物醇（叔丁醇或叔戊醇），根据本发明，通过保持由60重量％以上的反应介质组成的反应介质， 的反应区中的极性组分（氢过氧化物电荷原料，产物醇和产物环氧化物）通过向反应区中加入至少约30重量％的氢过氧化物电荷原料在相应产物醇中的溶液，并将所述烯烃电荷原料装入所述 反应区的量相对于产物醇中充入的氢过氧化物的所述带电溶液的量足以提供从ab的比例 每摩尔加入的氢过氧化物中含有0.5至约2摩尔的带电烯烃。 优选的烯烃电荷原料是丙烯，优选的氢过氧化物电荷原料是叔丁基过氧化氢。 在这种情况下相应的环氧化物是环氧丙烷，相应的产物醇是叔丁醇。

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