公开(公告)号：US20070196582A1

公开(公告)日：2007-08-23

申请号：US11359019

申请日：2006-02-22

申请人： John Sinko ,  Donghong Li ,  Darryl Cielinski ,  John Hennes

发明人： John Sinko ,  Donghong Li ,  Darryl Cielinski ,  John Hennes

IPC分类号： B05D3/02 ,  C09D5/14 ,  C09D5/16

CPC分类号： C09D5/14 ,  B27K3/16

摘要： A multi-functional aqueous protective treatment for wood substrates. The treatment comprises an aqueous solution of a zirconyl compound and incorporated bio-active constituents, providing protection against bio-degradation of wood and against degradation of aesthetic value of applied wood coatings by spontaneous staining and also protects against termites or other “in-depth” bio-degradation factors.

摘要翻译： 木质底物的多功能水性保护处理。 该处理包括氧化锆化合物的水溶液和掺入的生物活性组分，提供防止木材生物降解的保护性，并通过自发染色降低施用的木材涂层的美观价值，并且还防止白蚁或其他“深入” 生物降解因子。

公开(公告)号：US20050022693A1

公开(公告)日：2005-02-03

申请号：US10877946

申请日：2004-06-25

申请人： John Sinko ,  Martin Kendig

发明人： John Sinko ,  Martin Kendig

IPC分类号： C04B9/02 ,  C04B14/04 ,  C09C1/02 ,  C09C1/34 ,  C09C1/40 ,  C09D5/08 ,  C23C22/66 ,  C23C22/67 ,  C23C22/74 ,  C23C26/00 ,  C23F20060101

CPC分类号： C23C22/74 ,  C01P2002/22 ,  C01P2002/82 ,  C09C1/02 ,  C09C1/40 ,  C09D5/084 ,  C23C22/66 ,  C23C22/67 ,  C23C26/00

摘要： A pigment grade corrosion inhibitor and a method of forming the inhibitor is disclosed. The inhibitor is comprised of a host species comprised of an inorganic compound having a layered structure and a guest species comprised an anionic species of a weak acid. The host species is preferably a double hydroxide having a structure of: [M(II)1-xM(III)x(OH−)2] [An−x/n.y H2O], where M(II) is a divalent metal cationic species, M(III) is a trivalent metal cationic species, and An− is an anionic species, preferably with the species present in a range of: 0.2≦M(III)/(M(II)+M(III))≦0.4. The guest species include: ortho-phosphoric, pyrophosphoric, tripoly-phosphoric, polyphosphoric acid; mono- and di-alkyl or aryl-esters of ortho-phosphoric and pyrophosphoric acid; metaphosphoric, trimeta-phosphoric, poly-metaphosphoric acid; phosphorous (phosphonic) acid; derivatives of phosphonic acid; alkyl and aryl esters of thio-phosphoric and dithio-phosphoric acid; molybdic, phospho-molybdic, silico-molybdic acid; boric acid; cyanamidic acid; nitrous acid; derivatives of thio- and dithiocarbonic acid, including o-alkyl esters; derivatives of dithiocarbamic acid, including N-alkyl dithiocarbamates; pyrrolidinecarbodithioic acid; thio-organic compounds functionalized with at least one —SH group of acidic character, including: 2,5-dimercapto-1,3,4-thiadiazole (DMTD), 2,4-dimercapto-s-triazolo-[4,3-b]-1,3-4 thiadiazole, trithiocyanuric acid (TMT), and dithiocyanuric acid, various N—,S— and N,N—, S,S— and N,S-substituted derivatives of the above DMTD and TMT compounds; various S-substituted derivatives of trithiocyanuric acid; dimer and polymer derivatives of the above DMTD and TMT compounds, including 5,5′ dithio-bis (1,3,4 thiadiazole-2(3H)-thione or (DMTD)2, and (DMTD)n, polymers of DMTD and (TMT)2, dimers and polymers of TMT; various combinations of all the above; soluble salts of DMTD and TMT; poly-ammonium salt of DMTD or (DMTD)n and TMT formed with polyamines; mercapto-benzothiazole, mercapto-benzoxazole, mercapto-benzimidazole, and combinations, thereof; di- and poly-mercapto compounds, including: di-mercapto derivatives of thiophene, pyrrole, furane, diazoles, and thiadiazoles; di- and tri-mercapto derivatives of pyridine, diazines, triazines, benzimidazole, and benzothiazole, including dimercaptopyridine, 2, 4-dithiohydantoine, and 2,4,-dimercapto-6-amino-5-triazine; and carboxylic and di-carboxylic acids, including ascorbic, salicylic acid, phthalic acid, nitro-phthalic acid, succinic acid, and derivatives of succinic acid, including 1-(benzothiazol-2-ylthio)succinic acid.

公开(公告)号：US07662312B2

公开(公告)日：2010-02-16

申请号：US11982011

申请日：2007-11-01

申请人： John Sinko ,  Martin W. Kendig

发明人： John Sinko ,  Martin W. Kendig

IPC分类号： C09K3/00 ,  C23F11/00 ,  B05D3/02

CPC分类号： C23C22/74 ,  C01P2002/22 ,  C01P2002/82 ,  C09C1/02 ,  C09C1/40 ,  C09D5/084 ,  C23C22/66 ,  C23C22/67 ,  C23C26/00

摘要： A pigment grade corrosion inhibitor and a method of applying the inhibitor is disclosed. The inhibitor is comprised of a host species comprised of an inorganic compound having a layered structure and a guest species comprised an anionic species of a weak acid. The host species is preferably a double hydroxide having a structure of: [M(II)1−x M(III)x (OH−)2] [An−x/n.y H2O], where M(II) is a divalent metal cationic species, M(III) is a trivalent metal cationic species, and An− is an anionic species, preferably with the species present in a range of: 0.2≦M(III)/(M(II)+M(III))≦0.4. The guest species include: various phosphoric acids and derivatives thereof; boric acid; cyanamidic acid; nitrous acid; derivatives of thio- and dithiocarbonic acid; thio-organic compounds functionalized with at least one —SH group of acidic character, including: 2,5-dimercapto-1,3,4-thiadiazole (DMTD), 2,4-dimercapto-s-triazolo-[4,3-b]-1,3-4 thiadiazole, trithiocyanuric acid (TMT), and dithiocyanuric acid.

摘要翻译： 公开了一种颜料级缓蚀剂及其应用抑制剂的方法。 抑制剂包括由具有层状结构的无机化合物和包含弱酸的阴离子种类的客体物质组成的宿主物质。 主要物质优选是具有以下结构的双氢氧化物：[M（II）1-x M（III）x（OH-）2] [An-x / nYH 2 O]，其中M（II）是二价金属 阳离子种类，M（III）是三价金属阳离子物质，An-是阴离子物质，优选物质存在于：0.2≤M（III）/（M（II）+ M（III） ）<= 0.4。 客体物种包括：各种磷酸及其衍生物; 硼酸 氰amid酸 亚硝酸; 硫代和二硫代碳酸的衍生物; 具有至少一个酸性特征的-SH基官能化的硫代有机化合物，包括：2,5-二巯基-1,3,4-噻二唑（DMTD），2,4-二巯基-s-三唑并[4,3- b] -1,3,4-噻二唑，三硫代氰尿酸（TMT）和二硫氰尿酸。

公开(公告)号：US07662241B2

公开(公告)日：2010-02-16

申请号：US10784541

申请日：2004-02-23

申请人： John Sinko

发明人： John Sinko

IPC分类号： C23C22/48 ,  C23C22/56 ,  C23C22/00

CPC分类号： C23C22/68 ,  C09D5/086 ,  C23C22/50 ,  C23C22/56 ,  C23F11/161 ,  Y10T428/265 ,  Y10T428/31681

摘要： A corrosion-inhibiting composition for application to a metal substrate, such as aluminum or steel, and in connection with a paint, and the synthesis of the composition. The active inhibitor constituent of the composition can be selected from the group consisting of 2,5-dimercapto-1,3,4 thiadiazole (DMTD), 2,4-dimercapto-s-triazolo-[4,3-b]-1,3-4-thiadiazole, trithiocyanuric acid (TMT), and derivatives of DMTD and TMT, including various N— or S— and N, N—, S— and N—,S-substituted derivatives of DMTD, including salts of DMTD of the general formula: M(DMTD)n, where n=1,2 or 3, and M is a metal cation and preferably M=Zn(II), Bi(III), Co(II), Ni(II), Cd(II), Pb(II), Ag(I), Sb(III), Cu(II), Li(I), Ca(II), Sr(II), Mg(II), La(III), Ce(III), Pr(III), Al(III) or Zr(IV). DMTD, TMT, and their derivatives may also be combined with phosphates, molybdates, borates, silicates, tungstates, phosphotungstates, phosphomolybdates, cyanamides, carbonates, SiO2 and mixtures thereof.

摘要翻译： 用于金属基材（如铝或钢）以及与涂料相关的腐蚀抑制组合物和组合物的合成。 该组合物的活性抑制剂组分可以选自2,5-二巯基-1,3,4-噻二唑（DMTD），2,4-二巯基-s-三唑并[4,3-b] -1 ，3,4-噻二唑，三硫代氰尿酸（TMT）以及DMTD和TMT的衍生物，包括DMTD的各种N-或S-和N，N-，S-和N-，S-取代衍生物，包括DMTD的盐 通式为M（DMTD）n，其中n = 1,2或3，M为金属阳离子，优选M = Zn（II），Bi（III），Co（II），Ni（II） Cd（Ⅱ），Pb（Ⅱ），Ag（Ⅰ），Sb（Ⅲ），Cu（Ⅱ），Li（Ⅰ） Ce（III），Pr（III），Al（III）或Zr（IV）。 DMTD，TMT及其衍生物也可以与磷酸盐，钼酸盐，硼酸盐，硅酸盐，钨酸盐，磷钨酸盐，磷钼酸盐，氰酰胺，碳酸盐，SiO 2及其混合物组合。

公开(公告)号：US5759705A

公开(公告)日：1998-06-02

申请号：US833867

申请日：1997-04-10

申请人： John Sinko

发明人： John Sinko

IPC分类号： B05D7/06 ,  B27K3/36 ,  B27K3/52 ,  B32B21/04

CPC分类号： B27K3/16 ,  B05D7/06 ,  B27K3/34 ,  B27K3/346 ,  Y10T428/31989

摘要： A process of treating wood to reduce the tannin staining of coatings subsequently applied includes the steps of providing a solution of a zirconyl compound in a carrier liquid such as water, applying the solution to a wood surface, and, drying the solution. The pore structure of the wood is modified or sealed so that staining of coating compositions applied subsequently over the surface is reduced. The process is particularly beneficial in cases where the coating composition a clear or a light-colored latex paint, especially white. The preferred zirconyl compound is zirconyl acetate. The treating solution may be modified by addition thereto of a lanthanide compound, especially cerium, to provide UV light protection to a substrate and further by one or more metal cations to impart mildewicidal activity to the composition.

摘要翻译： 处理木材以减少随后涂覆的涂层的单宁污染的方法包括以下步骤：在载体液体如水中提供锆基化合物溶液，将溶液施用于木材表面，并干燥溶液。 木材的孔结构被改性或密封，使得随后涂覆在表面上的涂料组合物的染色减少。 该方法在涂料组合物为透明或浅色乳胶漆，特别是白色的情况下特别有利。 优选的锆化合物是乙酸氧锆。 处理溶液可以通过添加镧系元素化合物，特别是铈来改性，以向基底提供UV光保护，并且进一步由一种或多种金属阳离子赋予组合物防霉活性。

公开(公告)号：US5558706A

公开(公告)日：1996-09-24

申请号：US754448

申请日：1995-12-15

申请人： John Sinko

发明人： John Sinko

IPC分类号： C03C17/38 ,  C09D5/08 ,  C04B14/36

CPC分类号： C03C17/38 ,  C09D5/084

摘要： A corrosion inhibitor pigment composition is based a solid solution of (Ni.sup.2+ +Co.sup.2+)-bis-hydrogen cyanamide.

摘要翻译： 缓蚀剂颜料组合物是（Ni2 + + Co2 +） - 双 - 氢氰胺的固溶体。

公开(公告)号：US5529811A

公开(公告)日：1996-06-25

申请号：US367100

申请日：1994-12-30

申请人： John Sinko

发明人： John Sinko

IPC分类号： C09D5/00 ,  C09D5/14 ,  B05D1/18

CPC分类号： C09D5/14 ,  C09D5/002

摘要： A process of inhibiting of the staining of a film forming finish applied to a tannin containing wood substrate includes the step of applying to the wood substrate prior to or concurrently with the film forming finish, a protective coating containing an effective amount of zinc cyanamide to inhibit the migration of tannins from the substrate into the finish.

摘要翻译： 抑制涂布在含有单宁的木质基材上的成膜整理剂的染色过程包括在成膜之前或同时进行涂布到木材基材上的步骤，包含有效量的氰氨腈以抑制 单宁从底物迁移到完成。

公开(公告)号：US5378446A

公开(公告)日：1995-01-03

申请号：US195783

申请日：1994-02-14

申请人： John Sinko

发明人： John Sinko

IPC分类号： C01C3/16 ,  C09D5/08

CPC分类号： C09D5/084 ,  C01C3/16

摘要： Improved corrosion preventive pigment grade zinc cyanamide suitable for protective coatings is prepared by providing a hydrated slurry of finely divided, dispersed basic zinc carbonate, mixing with said slurry a stabilized soluble aqueous solution of hydrogen cyanamide to form zinc cyanamide having a crystalline structure characterized by the presence of an intense IR absorption spectral band at 2200 cm.sup.-1 and the substantial absence of component bands at 2050 cm.sup.-1 and 700 cm.sup.-1.

摘要翻译： 通过提供细碎的分散的碱式碳酸锌的水合浆料，与稳定的可溶性氨基氰水溶液混合，形成具有结晶结构的锌氰胺，其特征在于： 在2200cm -1处存在强烈的IR吸收光谱带，并且在2050cm -1和700cm -1处基本上不存在成分谱带。

公开(公告)号：US20080258114A1

公开(公告)日：2008-10-23

申请号：US11982011

申请日：2007-11-01

申请人： John Sinko ,  Martin W. Kendig

发明人： John Sinko ,  Martin W. Kendig

IPC分类号： C23F11/14 ,  C23F11/10 ,  C23F11/16

CPC分类号： C23C22/74 ,  C01P2002/22 ,  C01P2002/82 ,  C09C1/02 ,  C09C1/40 ,  C09D5/084 ,  C23C22/66 ,  C23C22/67 ,  C23C26/00

摘要： A pigment grade corrosion inhibitor and a method of applying the inhibitor is disclosed. The inhibitor is comprised of a host species comprised of an inorganic compound having a layered structure and a guest species comprised an anionic species of a weak acid. The host species is preferably a double hydroxide having a structure of: [M(II)1-x M(III)x (OH−)2] [An−x/n·y H2O], where M(II) is a divalent metal cationic species, M(III) is a trivalent metal cationic species, and An− is an anionic species, preferably with the species present in a range of: 0.2≦M(III)/(M(II)+M(III))≦0.4. The guest species include: various phosphoric acids and derivatives thereof; boric acid; cyanamidic acid; nitrous acid; derivatives of thio- and dithiocarbonic acid; thio-organic compounds functionalized with at least one —SH group of acidic character, including: 2,5-dimercapto-1,3,4-thiadiazole (DMTD), 2,4-dimercapto-s-triazolo-[4,3-b]-1,3-4 thiadiazole, trithiocyanuric acid (TMT), and dithiocyanuric acid.

摘要翻译： 公开了一种颜料级缓蚀剂及其应用抑制剂的方法。 抑制剂包括由具有层状结构的无机化合物和包含弱酸的阴离子种类的客体物质组成的宿主物质。 主体物质优选是具有以下结构的双氢氧化物：[M（II）1-x M（III）x（OH） - ）其中M（II）为H（O）2，其中M（II） 是二价金属阳离子物质，M（III）是三价金属阳离子物质，并且A-N-H是阴离子物质，优选物质存在于以下范围内：0.2≤M（III ）/（M（II）+ M（III））<= 0.4。 客体物种包括：各种磷酸及其衍生物; 硼酸 氰amid酸; 亚硝酸; 硫代和二硫代碳酸的衍生物; 具有至少一个酸性特征的-SH基官能化的硫代有机化合物，包括：2,5-二巯基-1,3,4-噻二唑（DMTD），2,4-二巯基-s-三唑并[4,3- b] -1,3,4-噻二唑，三硫代氰尿酸（TMT）和二硫氰尿酸。

公开(公告)号：US06447594B1

公开(公告)日：2002-09-10

申请号：US09880666

申请日：2001-06-13

申请人： John Sinko ,  Michael Denesha

发明人： John Sinko ,  Michael Denesha

IPC分类号： C09C134

CPC分类号： C09C1/34 ,  C01P2004/61 ,  C01P2004/80 ,  C01P2006/10 ,  C01P2006/60 ,  C01P2006/80 ,  C01P2006/90

摘要： A process for producing a strontium chromate corrosion inhibitor includes the steps of providing an aqueous slurry containing dispersed particulate strontium chromate, adding to the slurry a phosphoric acid or a neutral or acidic soluble salt of a phosphoric acid selected from the group consisting of ortho-phosphoric, pyro-phosphoric, tri-phosphoric, polyphosphoric, metaphosphoric, polymetaphosphoric, cyclic tri-metaphosphoric acid, and phosphorous acid, and, filtering and drying the resultant material whereby particulate strontium chromate of reduced solubility is produced.

摘要翻译： 制备铬酸锶腐蚀抑制剂的方法包括以下步骤：提供含有分散的颗粒状锶铬酸盐的含水浆料，向该浆料中加入磷酸或磷酸的中性或酸性可溶性盐，所述磷酸选自正磷酸 焦磷酸，三磷酸，多磷酸，偏磷酸，聚偏磷酸，环状三偏磷酸和亚磷酸，并且过滤并干燥所得材料，由此产生溶解度降低的颗粒状锶铬酸盐。