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公开(公告)号：US07244783B2
公开(公告)日：2007-07-17
申请号：US10875413
申请日：2004-06-24
IPC分类号： C08L53/00
CPC分类号： C08L51/003 , C08F257/00 , C08L23/10 , C08L53/025 , C08L2205/03 , C08F236/04 , C08L2666/02
摘要： A thermoplastic elastomer composition comprised of (a) a thermoplastic resin selected from the group consisting of polyphenylene ether, polypropylene, polyethylene, and polystyrene, (b) a block copolymer selected from the group consisting of styrene-ethylene butylene-styrene, styrene-ethylene propylene-styrene, hydrogenated polybutadiene, hydrogenated polyisoprene, hydrogenated styrene-isoprene random copolymer, styrene-ethylene propylene block copolymer, styrene-ethylene ethylene propylene-styrene and hydrogenated styrene-butadiene random copolymers, (c) a core-shell polymer comprised of a polymeric core and a polymeric shell with the proviso that the polymeric core and/or the polymeric shell may be crosslinked, and (d) an oil.
摘要翻译： 一种热塑性弹性体组合物，其包含（a）选自聚苯醚，聚丙烯，聚乙烯和聚苯乙烯的热塑性树脂，（b）嵌段共聚物，其选自苯乙烯 - 乙烯 - 丁烯 - 苯乙烯，苯乙烯 - 乙烯 丙烯 - 苯乙烯，氢化聚丁二烯，氢化聚异戊二烯，氢化苯乙烯 - 异戊二烯无规共聚物，苯乙烯 - 乙烯丙烯嵌段共聚物，苯乙烯 - 乙烯乙烯丙烯 - 苯乙烯和氢化苯乙烯 - 丁二烯无规共聚物，（c） 聚合物芯和聚合物壳，条件是聚合物芯和/或聚合物壳可以是交联的，和（d）油。
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2.发明授权Core-shell particles synthesized through controlled free radical polymerization 失效通过控制自由基聚合合成的核 - 壳颗粒公开(公告)号：US07344752B2
公开(公告)日：2008-03-18
申请号：US11023868
申请日：2004-12-27
申请人： Lei Zheng , John Thomas Lean , Eric Sean Castner , Thierry Florent Edme Materne , Dane Kenton Parker , Frank James Feher
发明人： Lei Zheng , John Thomas Lean , Eric Sean Castner , Thierry Florent Edme Materne , Dane Kenton Parker , Frank James Feher
CPC分类号： C08F279/02 , C08F257/02 , C08F291/00 , C08F2/38
摘要： The present invention discloses a process for producing a core-shell polymer that comprises: (1) preparing a monomer solution which is comprised of (a) at least one monomer, optional one crosslinking monomer (b) a conjugate acid of a surfactant with a pKa of less than 14, and (c) a controlled free radical polymerization agent; (2) preparing an aqueous medium which is comprised of (a) water, and (b) a conjugate base of a weak acid wherein the pKb of the base is less than 14; and (3) mixing the monomer solution with the aqueous medium under conditions that result in the in-situ formation of an emulsifier to produce a polymerization medium, and (4) initiating free radical polymerization within the polymerization medium to produce a core polymer, wherein the core contains a free radical control agents, (5) adding a second monomer to the polymerization medium containing the core polymer, and (6) allowing polymerization to proceed in the presence of the free radical control agent to produce the core-shell polymer.
摘要翻译： 本发明公开了一种制备核 - 壳聚合物的方法，其包括：（1）制备单体溶液，该单体溶液由（a）至少一种单体，任选的一种交联单体（b）表面活性剂的共轭酸与 pKa小于14，（c）受控自由基聚合剂; （2）制备由（a）水和（b）弱酸的共轭碱组成的水性介质，其中碱的pKb小于14; 和（3）在导致乳化剂原位形成以产生聚合介质的条件下将单体溶液与水性介质混合，和（4）在聚合介质内引发自由基聚合以制备芯聚合物，其中 核心包含自由基控制剂，（5）在含有核聚合物的聚合介质中加入第二单体，和（6）在自由基控制剂的存在下使聚合进行以制备核 - 壳聚合物。
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公开(公告)号：US20050288393A1
公开(公告)日：2005-12-29
申请号：US10875413
申请日：2004-06-24
申请人： John Lean , Manoj Ajbani , Eric Castner , Lei Zheng , Christopher Kiehl
发明人： John Lean , Manoj Ajbani , Eric Castner , Lei Zheng , Christopher Kiehl
IPC分类号： C08L83/00
CPC分类号： C08L51/003 , C08F257/00 , C08L23/10 , C08L53/025 , C08L2205/03 , C08F236/04 , C08L2666/02
摘要： A thermoplastic elastomer composition comprised of (a) a thermoplastic resin selected from the group consisting of polyphenylene ether, polypropylene, polyethylene, and polystyrene, (b) a block copolymer selected from the group consisting of styrene-ethylene butylene-styrene, styrene-ethylene propylene-styrene, hydrogenated polybutadiene, hydrogenated polyisoprene, hydrogenated styrene-isoprene random copolymer, styrene-ethylene propylene block copolymer, styrene-ethylene ethylene propylene-styrene and hydrogenated styrene-butadiene random copolymers, (c) a core-shell polymer comprised of a polymeric core and a polymeric shell with the proviso that the polymeric core and/or the polymeric shell may be crosslinked, and (d) an oil.
摘要翻译： 一种热塑性弹性体组合物，其包含（a）选自聚苯醚，聚丙烯，聚乙烯和聚苯乙烯的热塑性树脂，（b）嵌段共聚物，其选自苯乙烯 - 乙烯 - 丁烯 - 苯乙烯，苯乙烯 - 乙烯 丙烯 - 苯乙烯，氢化聚丁二烯，氢化聚异戊二烯，氢化苯乙烯 - 异戊二烯无规共聚物，苯乙烯 - 乙烯丙烯嵌段共聚物，苯乙烯 - 乙烯乙烯丙烯 - 苯乙烯和氢化苯乙烯 - 丁二烯无规共聚物，（c） 聚合物芯和聚合物壳，条件是聚合物芯和/或聚合物壳可以是交联的，和（d）油。
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公开(公告)号：US07825194B2
公开(公告)日：2010-11-02
申请号：US12287426
申请日：2008-10-10
CPC分类号： C08F257/02 , C08C1/15 , C08F6/22 , C08F236/06 , C08L51/00
摘要： This invention discloses a process for synthesizing a hairy polymer particle which comprises the steps of (1) polymerizing a vinyl aromatic monomer by emulsion polymerization in an aqueous medium to produce core particles, (2) recovering the core particles from the aqueous medium, (3) dispersing the core particles in an organic solvent, (4) adding an organo-lithium compound to the dried core particles in the organic solvent to produce the hairless core initiator, and (5) utilizing the hairless core initiator to initiate the anionic polymerization of a conjugated diolefin monomer in an organic solvent to produce a solution of the hairy polymer particles. The hairy polymer nanoparticles can then be recovered from the organic solvent. These hairy polymer particles are comprised of (1) a core which is comprised of a polymer of a vinyl aromatic monomer and (2) hairs which are polymer chains of a conjugated diolefin monomer, wherein the hairs are covalently bonded to the core. The core is typically spherical in shape, has a diameter of less than 1000 nm, and is comprised of a crosslinked polymer of a vinyl aromatic monomer. The hairy polymer particles of this invention are useful as fillers in rubber compositions used in making articles of manufacture, such as tires, hoses, power transmission belts, windshield wiper blades, and the like.
摘要翻译： 本发明公开了一种合成毛状聚合物颗粒的方法，其包括以下步骤：（1）通过乳液聚合在水性介质中聚合乙烯基芳族单体以产生核心颗粒，（2）从水介质中回收芯颗粒，（3 ）将核心颗粒分散在有机溶剂中，（4）将有机锂化合物加入到有机溶剂中的干燥芯颗粒中以制备无毛芯引发剂，和（5）利用无毛芯引发剂引发阴离子聚合 共轭二烯单体在有机溶剂中以产生毛状聚合物颗粒的溶液。 然后可以从有机溶剂中回收毛状聚合物纳米颗粒。 这些毛发聚合物颗粒包括（1）由乙烯基芳族单体的聚合物组成的芯和（2）作为共轭二烯烃单体的聚合物链的毛发，其中毛发共价键合到芯上。 芯通常为球形，直径小于1000nm，并且由乙烯基芳族单体的交联聚合物组成。 本发明的毛发聚合物颗粒可用作用于制造制品的橡胶组合物中的填料，例如轮胎，软管，动力传动带，挡风玻璃刮水器等。
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公开(公告)号：US20090042719A1
公开(公告)日：2009-02-12
申请号：US12287426
申请日：2008-10-10
IPC分类号： B01J31/12
CPC分类号： C08F257/02 , C08C1/15 , C08F6/22 , C08F236/06 , C08L51/00
摘要： This invention discloses a process for synthesizing a hairy polymer particle which comprises the steps of (1) polymerizing a vinyl aromatic monomer by emulsion polymerization in an aqueous medium to produce core particles, (2) recovering the core particles from the aqueous medium, (3) dispersing the core particles in an organic solvent, (4) adding an organo-lithium compound to the dried core particles in the organic solvent to produce the hairless core initiator, and (5) utilizing the hairless core initiator to initiate the anionic polymerization of a conjugated diolefin monomer in an organic solvent to produce a solution of the hairy polymer particles. The hairy polymer nanoparticles can then be recovered from the organic solvent. These hairy polymer particles are comprised of (1) a core which is comprised of a polymer of a vinyl aromatic monomer and (2) hairs which are polymer chains of a conjugated diolefin monomer, wherein the hairs are covalently bonded to the core. The core is typically spherical in shape, has a diameter of less than 1000 nm, and is comprised of a crosslinked polymer of a vinyl aromatic monomer. The hairy polymer particles of this invention are useful as fillers in rubber compositions used in making articles of manufacture, such as tires, hoses, power transmission belts, windshield wiper blades, and the like.
摘要翻译： 本发明公开了一种合成毛状聚合物颗粒的方法，其包括以下步骤：（1）通过乳液聚合在水性介质中聚合乙烯基芳族单体以产生核心颗粒，（2）从水介质中回收芯颗粒，（3 ）将核心颗粒分散在有机溶剂中，（4）将有机锂化合物加入到有机溶剂中的干燥芯颗粒中以制备无毛芯引发剂，和（5）利用无毛芯引发剂引发阴离子聚合 共轭二烯单体在有机溶剂中以产生毛状聚合物颗粒的溶液。 然后可以从有机溶剂中回收毛状聚合物纳米颗粒。 这些毛发聚合物颗粒包括（1）由乙烯基芳族单体的聚合物组成的芯和（2）作为共轭二烯烃单体的聚合物链的毛发，其中毛发共价键合到芯上。 芯通常为球形，直径小于1000nm，并且由乙烯基芳族单体的交联聚合物组成。 本发明的毛发聚合物颗粒可用作用于制造制品的橡胶组合物中的填料，例如轮胎，软管，动力传动带，挡风玻璃刮水器等。
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公开(公告)号：US20110024011A1
公开(公告)日：2011-02-03
申请号：US12903514
申请日：2010-10-13
申请人： Eric Sean Castner , Lei Zheng , Feng Anne Xie , Ping Zhang
发明人： Eric Sean Castner , Lei Zheng , Feng Anne Xie , Ping Zhang
CPC分类号： C08L51/04 , C08F279/02 , C08L9/06 , Y10S525/902 , Y10T428/2982 , Y10T428/2989 , C08L2666/24 , C08L2666/02 , C08L2666/04
摘要： This invention discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is comprised of (1) a filler, (2) a cured rubbery polymer, and (3) core-shell particles which are comprised of (a) a crosslinked elastomeric core consisting essentially of repeat units that are derived from at least one conjugated diolefin monomer and from 15 weight percent to 30 weight percent at least one crosslinking monomer, wherein the crosslinked elastomeric core is a polymeric composition having a glass transition temperature which is within the range of −20° C. to 20° C., and (b) a polymeric shell which is derived from at least one vinyl aromatic monomer, wherein the polymeric shell has a glass transition temperature which is within the range of 50° C. to 160° C., and wherein the weight ratio of the core to the shell is within the range of 20:1 to 7:1.
摘要翻译： 本发明公开了一种轮胎，其包括具有外圆周胎面的大致环形胎体，两个间隔开的胎圈，从胎圈到胎圈延伸的至少一个帘布层和从所述胎面径向延伸并将所述胎面连接到所述胎圈的侧壁，其中所述胎面 适于与地面接触，并且其中所述胎面由（1）填料，（2）固化的橡胶状聚合物和（3）核 - 壳颗粒组成，所述核 - 壳颗粒由（a）基本上由 的衍生自至少一种共轭二烯单体和15重量％至30重量％至少一种交联单体的重复单元，其中所述交联弹性体芯是玻璃化转变温度在-20℃以下的聚合物组合物 ℃至20℃，和（b）衍生自至少一种乙烯基芳族单体的聚合物壳，其中聚合物壳的玻璃化转变温度在 在50℃至160℃的范围内，并且其中芯与壳的重量比在20:1至7:1的范围内。
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公开(公告)号：US07838112B2
公开(公告)日：2010-11-23
申请号：US10999406
申请日：2004-11-30
申请人： Eric Sean Castner , Lei Zheng , Feng Anne Xie , Ping Zhang
发明人： Eric Sean Castner , Lei Zheng , Feng Anne Xie , Ping Zhang
IPC分类号： B32B5/16
CPC分类号： C08L51/04 , C08F279/02 , C08L9/06 , Y10S525/902 , Y10T428/2982 , Y10T428/2989 , C08L2666/24 , C08L2666/02 , C08L2666/04
摘要： This invention discloses a process for synthesizing a modified crosslinked elastomeric particle which comprises a two-step polymerization of a conjugated diolefin monomer and a vinyl aromatic monomer by emulsion polymerization, wherein the particle is synthesized by the steps of (1) polymerizing a conjugated diolefin monomer, alone or in combination with a vinyl aromatic monomer, and optionally a crosslinking monomer, to create a crosslinked elastomeric core having residual double bonds and an outer surface; (2) polymerizing a monomer of a vinyl aromatic monomer, alone or in combination with a diolefin monomer, to create a polymeric shell, wherein the polymeric shell is grafted to the outer surface of the polymeric core by reacting with the residual double bonds of the polymeric core; and (3) coagulating the core-shell emulsion latex solution to recover the particles.
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公开(公告)号：US07408005B2
公开(公告)日：2008-08-05
申请号：US11072986
申请日：2005-03-05
IPC分类号： C08F279/02
CPC分类号： C08F257/02 , C08C1/15 , C08F6/22 , C08F236/06 , C08L51/00
摘要： This invention discloses a process for synthesizing a hairy polymer particle which comprises the steps of (1) polymerizing a vinyl aromatic monomer by emulsion polymerization in an aqueous medium to produce core particles, (2) recovering the core particles from the aqueous medium, (3) dispersing the core particles in an organic solvent, (4) adding an organo-lithium compound to the dried core particles in the organic solvent to produce the hairless core initiator, and (5) utilizing the hairless core initiator to initiate the anionic polymerization of a conjugated diolefin monomer in an organic solvent to produce a solution of the hairy polymer particles. The hairy polymer nanoparticles can then be recovered from the organic solvent. These hairy polymer particles are comprised of (1) a core which is comprised of a polymer of a vinyl aromatic monomer and (2) hairs which are polymer chains of a conjugated diolefin monomer, wherein the hairs are covalently bonded to the core. The core is typically spherical in shape, has a diameter of less than 1000 nm, and is comprised of a crosslinked polymer of a vinyl aromatic monomer. The hairy polymer particles of this invention are useful as fillers in rubber compositions used in making articles of manufacture, such as tires, hoses, power transmission belts, windshield wiper blades, and the like.
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公开(公告)号：US20050228134A1
公开(公告)日：2005-10-13
申请号：US10823256
申请日：2004-04-13
申请人： Feng Anne Xie , Lei Zheng , Eric Sean Castner
发明人： Feng Anne Xie , Lei Zheng , Eric Sean Castner
IPC分类号： B60C1/00 , C08F265/04 , C08F279/02 , C08F279/04 , C08G63/48 , C08L21/00 , C08L25/00 , C08L27/00 , C08L33/08 , C08L33/18 , C08L33/20 , C08L35/06 , C08L51/00 , C08L51/04 , C08L55/02
CPC分类号： B60C1/0016 , C08F265/04 , C08F279/02 , C08F279/04 , C08L21/00 , C08L25/00 , C08L33/08 , C08L33/18 , C08L33/20 , C08L35/06 , C08L51/003 , C08L51/04 , C08L55/02 , C08L2666/04 , C08L2666/24 , C08L2666/02
摘要： This invention relates to a tread rubber composition for tires with the addition of crosslinked resinous nanoparticles having a high glass transition temperature (Tg) into elastomeric base polymers. The invention demonstrates greatly improved handling performance without deteriorating controllability and stability during high-speed running. The present invention discloses a rubber composition comprising: (1) a rubbery polymer and (2) from 1 phr to 30 phr of pre-crosslinked polymer particles, wherein the pre-crosslinked polymer particles have a particle size which is within the range of 30 nm to 500 nm, wherein the pre-crosslinked polymer is comprised of repeat units that are derived from at least one monomer selected from the group consisting of acrylate monomers, vinyl aromatic monomers, acrylonitrile monomer, and vinyl halide monomers, and wherein the pre-crosslinked polymer has a glass transition temperature which is within the range of 30° C. to 200° C.
摘要翻译： 本发明涉及一种用于轮胎的胎面橡胶组合物，其中将具有高玻璃化转变温度（T g）的交联树脂纳米颗粒加入到弹性体基础聚合物中。 本发明显着提高了处理性能，而不会降低高速运行时的可控性和稳定性。 本发明公开了一种橡胶组合物，其包括：（1）橡胶状聚合物和（2）1〜30phr预交联聚合物颗粒，其中所述预交联聚合物颗粒的粒径在30 其中所述预交联聚合物由衍生自选自丙烯酸酯单体，乙烯基芳族单体，丙烯腈单体和卤乙烯单体中的至少一种单体的重复单元组成， 交联聚合物的玻璃化转变温度在30℃至200℃的范围内
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公开(公告)号：US07812092B2
公开(公告)日：2010-10-12
申请号：US12157237
申请日：2008-06-10
IPC分类号： C08F279/02
CPC分类号： C08F257/02 , C08C1/15 , C08F6/22 , C08F236/06 , C08L51/00
摘要： This invention discloses a process for synthesizing a hairy polymer particle which comprises the steps of (1) polymerizing a vinyl aromatic monomer by emulsion polymerization in an aqueous medium to produce core particles, (2) recovering the core particles from the aqueous medium, (3) dispersing the core particles in an organic solvent, (4) adding an organo-lithium compound to the dried core particles in the organic solvent to produce the hairless core initiator, and (5) utilizing the hairless core initiator to initiate the anionic polymerization of a conjugated diolefin monomer in an organic solvent to produce a solution of the hairy polymer particles. The hairy polymer nanoparticles can then be recovered from the organic solvent. These hairy polymer particles are comprised of (1) a core which is comprised of a polymer of a vinyl aromatic monomer and (2) hairs which are polymer chains of a conjugated diolefin monomer, wherein the hairs are covalently bonded to the core. The core is typically spherical in shape, has a diameter of less than 1000 nm, and is comprised of a crosslinked polymer of a vinyl aromatic monomer. The hairy polymer particles of this invention are useful as fillers in rubber compositions used in making articles of manufacture, such as tires, hoses, power transmission belts, windshield wiper blades, and the like.
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