公开(公告)号：US07951865B1

公开(公告)日：2011-05-31

申请号：US12821487

申请日：2010-06-23

申请人： John W. Paul ,  C. Anthony Smith ,  Jerrel C. Anderson ,  Stephen J. Bennison ,  Sam L. Samuels ,  Steven C. Pesek

发明人： John W. Paul ,  C. Anthony Smith ,  Jerrel C. Anderson ,  Stephen J. Bennison ,  Sam L. Samuels ,  Steven C. Pesek

IPC分类号： C08L31/00 ,  B32B27/00 ,  B32B15/08 ,  B32B27/30

CPC分类号： B32B17/10743 ,  B32B17/10036 ,  B32B17/10834 ,  B32B17/10871 ,  B32B17/1099 ,  C08F8/44 ,  C08F210/02 ,  C08J5/18 ,  C08J2323/08 ,  Y10T428/24777 ,  Y10T428/31645 ,  Y10T428/31692 ,  Y10T428/31855 ,  Y10T428/31935 ,  C08F220/04

摘要： The present invention is an improved polymeric resin composition comprising or consisting essentially of from about 70 wt % to about 79 wt % units derived from ethylene and from about 21 wt % to about 30 wt % units derived from an α,β-unsaturated carboxylic acid having from 3 to 8 carbons. Resins of the present invention are particularly suitable for preparing transparent laminates useful as glazing elements that provide a greater measure of safety than non-laminated glazing elements. Laminates of the present invention have 3% haze or less without the addition of amines.

摘要翻译： 本发明是一种改进的聚合物树脂组合物，其包含或基本上由衍生自乙烯的约70重量％至约79重量％的单元和源自α，β-不饱和羧酸的约21重量％至约30重量％的单元 具有3至8个碳原子的酸。 本发明的树脂特别适用于制备可用作玻璃元件的透明层压材料，其提供比非层压玻璃元件更大的安全性。 本发明的叠层体没有添加胺时具有3％的雾度或更小。

公开(公告)号：US07763360B2

公开(公告)日：2010-07-27

申请号：US11263015

申请日：2005-10-31

申请人： John W. Paul ,  C. Anthony Smith ,  Jerrel C. Anderson ,  Stephen J. Bennison ,  Sam L. Samuels ,  Steven C. Pesek

发明人： John W. Paul ,  C. Anthony Smith ,  Jerrel C. Anderson ,  Stephen J. Bennison ,  Sam L. Samuels ,  Steven C. Pesek

IPC分类号： B32B27/00 ,  B32B15/08 ,  B32B27/30

CPC分类号： B32B17/10743 ,  B32B17/10036 ,  B32B17/10834 ,  B32B17/10871 ,  B32B17/1099 ,  C08F8/44 ,  C08F210/02 ,  C08J5/18 ,  C08J2323/08 ,  Y10T428/24777 ,  Y10T428/31645 ,  Y10T428/31692 ,  Y10T428/31855 ,  Y10T428/31935 ,  C08F220/04

摘要： The present invention is an improved polymeric resin composition comprising or consisting essentially of from about 70 wt % to about 79 wt % units derived from ethylene and from about 21 wt % to about 30 wt % units derived from an α, β-unsaturated carboxylic acid having from 3 to 8 carbons. Resins of the present invention are particularly suitable for preparing transparent laminates useful as glazing elements that provide a greater measure of safety than non-laminated glazing elements. Laminates of the present invention have 3% haze or less without the addition of amines.

摘要翻译： 本发明是一种改进的聚合物树脂组合物，其包含或基本上由衍生自乙烯的约70重量％至约79重量％的单元和源自α，β-不饱和羧酸的约21重量％至约30重量％的单元 具有3至8个碳原子的酸。 本发明的树脂特别适用于制备可用作玻璃元件的透明层压材料，其比非层压玻璃元件提供更大的安全性。 本发明的叠层体没有添加胺时具有3％的雾度或更小。

公开(公告)号：US20070289693A1

公开(公告)日：2007-12-20

申请号：US11454057

申请日：2006-06-15

申请人： Jerrel C. Anderson ,  Richard A. Hayes ,  Steven C. Pesek ,  John W. Paul ,  C. Anthony Smith ,  Stephen J. Bennison ,  Sam L. Samuels

发明人： Jerrel C. Anderson ,  Richard A. Hayes ,  Steven C. Pesek ,  John W. Paul ,  C. Anthony Smith ,  Stephen J. Bennison ,  Sam L. Samuels

IPC分类号： B32B27/30

CPC分类号： B32B17/1099 ,  B32B17/10678 ,  B32B17/10743 ,  B32B17/10871 ,  Y10T428/31935

摘要： The present invention is an improved polymeric resin composition comprising units derived from ethylene, from about 20 wt % to about 30 wt % units derived from an α,β-unsaturated carboxylic acid having from 3 to 8 carbons, and optionally an effective amount of at least one additive selected from the group consisting of hindered amine light stabilizers, UV light absorbers, and thermal stabilizers. Resins of the present invention are particularly suitable for preparing transparent laminates useful as glazing elements that provide a greater measure of safety than non-laminated glazing elements.

摘要翻译： 本发明是改进的聚合物树脂组合物，其包含衍生自乙烯的单元，约20重量％至约30重量％的衍生自具有3至8个碳原子的α，β-不饱和羧酸的单元，以及任选地有效量的 选自受阻胺光稳定剂，UV光吸收剂和热稳定剂的至少一种添加剂。 本发明的树脂特别适用于制备可用作玻璃元件的透明层压材料，其提供比非层压玻璃元件更大的安全性。

公开(公告)号：US20090242030A1

公开(公告)日：2009-10-01

申请号：US12411863

申请日：2009-03-26

申请人： CYNTHIA H. KIRSCHNER ,  Jerrel C. Anderson ,  Stephen J. Bennison ,  Richard Allen Hayes ,  David F. Kristunas

发明人： CYNTHIA H. KIRSCHNER ,  Jerrel C. Anderson ,  Stephen J. Bennison ,  Richard Allen Hayes ,  David F. Kristunas

IPC分类号： H01L31/0256

CPC分类号： B32B27/08 ,  B32B7/12 ,  B32B9/005 ,  B32B9/045 ,  B32B15/08 ,  B32B15/09 ,  B32B17/064 ,  B32B17/10018 ,  B32B17/10743 ,  B32B17/10761 ,  B32B17/10853 ,  B32B18/00 ,  B32B27/16 ,  B32B27/18 ,  B32B27/22 ,  B32B27/28 ,  B32B27/30 ,  B32B27/32 ,  B32B27/34 ,  B32B27/36 ,  B32B27/38 ,  B32B27/40 ,  B32B27/42 ,  B32B2255/10 ,  B32B2255/26 ,  B32B2270/00 ,  B32B2307/50 ,  B32B2307/518 ,  B32B2307/54 ,  B32B2307/554 ,  B32B2307/558 ,  B32B2307/734 ,  B32B2367/00 ,  B32B2419/00 ,  B32B2457/12 ,  B32B2605/006 ,  H01L31/0481 ,  Y02E10/50 ,  Y10T428/24942 ,  Y10T428/26 ,  Y10T428/31511 ,  Y10T428/31565 ,  Y10T428/31663 ,  Y10T428/31786 ,  Y10T428/31797

摘要： Provided is a high performance anti-spall laminate article comprising a bi-layer polymeric composite. The bi-layer composite includes a polymeric sheet and a poly(ethylene terephthalate) (PET) film laminated to each other. The PET film has a tensile modulus of about 600,000 psi or higher in both the machine direction (MD) and the transverse direction (TD), a shock brittleness index of about 55 Joules or higher in the machine direction and about 25 joules or higher in the transverse direction, and a percent elongation at break (EOB) of about 110-160 in the machine direction and about 60-110 in the transverse direction.

摘要翻译： 提供了一种包含双层聚合物复合材料的高性能防剥落层压制品。 双层复合材料包括聚合物片材和彼此层压的聚对苯二甲酸乙二醇酯（PET）膜。 PET膜在机械方向（MD）和横向（TD）上的拉伸模量为约600,000psi或更高，冲击脆性指数在机器方向约为55焦耳或更高，约25焦耳或更高 横向和百分比断裂伸长率（EOB）在机器方向约为110-160°，横向方向为约60-110。

公开(公告)号：US08399097B2

公开(公告)日：2013-03-19

申请号：US12610688

申请日：2009-11-02

申请人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

发明人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B17/10 ,  B32B27/32 ,  B32B15/08 ,  B32B27/36

CPC分类号： C08F220/06 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  Y10T428/31507 ,  Y10T428/31645 ,  Y10T428/31692 ,  Y10T428/31938

摘要： A safety laminate comprises an interlayer that comprises an ionomer that is the neutralized product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of a first α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of a first α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms; and has a melt flow rate of about 10 to about 4000 g/10 min. When neutralized to a level of about 40% to about 90% and when comprising counterions that consist essentially of sodium cations, the precursor acid copolymer produces a sodium ionomer that has a melt flow rate of about 0.7 to about 25 g/10 min and a freeze enthalpy that is not detectable or that is less than about 3.0 j/g. The ionomer composition may further comprise a second ionomer that has a melt flow rate of about 10 g/10 min or less.

摘要翻译： 安全层压板包括中间层，其包含作为前体酸共聚物的中和物的离聚物。 前体酸共聚物包含具有2至10个碳原子的第一α-烯烃和约20至约30重量％的具有3-8个碳原子的第一个α，β-烯属不饱和羧酸的共聚单元的共聚单元; 并具有约10至约4000g / 10min的熔体流动速率。 当中和至约40％至约90％的水平时，当包含基本上由钠阳离子组成的抗衡离子时，前体酸共聚物产生熔体流动速率为约0.7至约25g / 10min的钠离聚物， 不可检测的或低于约3.0J / g的冷冻焓。 离聚物组合物还可以包含熔体流动速率为约10g / 10分钟或更短的第二离聚物。

公开(公告)号：US07960017B2

公开(公告)日：2011-06-14

申请号：US11584988

申请日：2006-10-23

申请人： Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith ,  Stephen J. Bennison ,  Richard Allen Hayes

发明人： Steven C. Pesek ,  Sam Louis Samuels ,  Charles Anthony Smith ,  Stephen J. Bennison ,  Richard Allen Hayes

IPC分类号： B32B27/32 ,  B32B27/36 ,  B32B27/30 ,  B32B17/06

CPC分类号： B32B17/10036 ,  B32B17/10743 ,  B32B27/08 ,  B32B27/302 ,  B32B27/308 ,  B32B27/32 ,  B32B27/365 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/0876 ,  C08L33/02 ,  C08L2205/02 ,  Y10T428/31507 ,  Y10T428/31855 ,  Y10T428/31935 ,  Y10T428/31938 ,  C08L2666/04 ,  C08L2666/06

摘要： The invention describes a polymeric sheet that has at least one layer that comprises an ionomer or ionomer blend that incorporates a partially neutralized alpha, beta-ethylenically unsaturated carboxylic acid component and is useful in glass laminate applications. The ionomer or ionomer blend contains one or more monovalent metal ions in an amount ranging from about 1 to about 60%, preferably about 10 to about 55%, and more preferably about 15 to about 50%, and one or more polyvalent metal ions in an amount ranging from about 40 to about 99%, preferably about 45 to about 90%, and more preferably about 50 to about 85%. This ratio range of monovalent and polyvalent metal neutralization ions provides synergistically greater adhesion to glass than found for either the monovalent or the polyvalent metal neutralization ions alone.

摘要翻译： 本发明描述了一种聚合物片材，其具有至少一层包含离聚物或离聚物共混物的层，该混合物掺入部分中和的α，β-烯键式不饱和羧酸组分，并且可用于玻璃层压应用。 离聚物或离聚物共混物含有一种或多种一价金属离子，其量为约1至约60％，优选约10至约55％，更优选约15至约50％，以及一种或多种多价金属离子 约40至约99％，优选约45至约90％，更优选约50至约85％的量。 单价和多价金属中和离子的这种比例范围提供了与单独或多价金属中和离子单独发现的对玻璃的协同增加的粘合力。

公开(公告)号：US20100167061A1

公开(公告)日：2010-07-01

申请号：US12610701

申请日：2009-11-02

申请人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

发明人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B27/32 ,  B32B27/36 ,  B32B27/08 ,  B32B27/00 ,  B32B27/40 ,  B32B17/10

CPC分类号： B32B17/10743 ,  B32B17/10018 ,  B32B2367/00 ,  Y10T428/31507 ,  Y10T428/31573 ,  Y10T428/31645 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31913 ,  Y10T428/31938

摘要： A laminate comprises an ionomeric interlayer sheet which, in turn, comprises or is prepared from a sodium/zinc mixed ionomer that comprises carboxylate groups and a combination of counterions that consists essentially of sodium cations and zinc cations. The sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin and an α,β-ethylenically unsaturated carboxylic acid, and it has a melt flow rate of about 70 to about 1000 g/10 min. In addition, the precursor acid copolymer, when neutralized to a level of about 40% to about 90%, and when comprising counterions that consist essentially of sodium ions, produces a sodium ionomer that has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry.

摘要翻译： 层压材料包括离聚物中间层片材，其又包含钠盐/锌混合离子交换聚合物或由钠/锌混合离聚​​物制备，所述钠/锌混合离聚​​物包含羧酸根基团和基本上由钠阳离子和锌阳离子组成的抗衡离子的组合。 钠/锌混合离聚​​物是前体酸共聚物的中和产物。 前体酸共聚物包括α-烯烃和α，β-烯键式不饱和羧酸的共聚单元，其熔体流动速率为约70至约1000g / 10min。 此外，当将前体酸共聚物中和至约40％至约90％的水平时，并且当包含基本上由钠离子组成的抗衡离子时，产生具有不可检测或较少的冷冻焓的钠离聚物 当用差示扫描量热法测定时，约为3.0J / g。

公开(公告)号：US20100112356A1

公开(公告)日：2010-05-06

申请号：US12610688

申请日：2009-11-02

申请人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

发明人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W. Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B17/10 ,  B32B27/32 ,  B32B15/08 ,  B32B27/36

CPC分类号： C08F220/06 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  Y10T428/31507 ,  Y10T428/31645 ,  Y10T428/31692 ,  Y10T428/31938

摘要： A safety laminate comprises an interlayer that comprises an ionomer that is the neutralized product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of a first α-olefin having 2 to 10 carbon atoms and about 20 to about 30 wt % of copolymerized units of a first α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms; and has a melt flow rate of about 10 to about 4000 g/10 min. When neutralized to a level of about 40% to about 90% and when comprising counterions that consist essentially of sodium cations, the precursor acid copolymer produces a sodium ionomer that has a melt flow rate of about 0.7 to about 25 g/10 min and a freeze enthalpy that is not detectable or that is less than about 3.0 j/g. The ionomer composition may further comprise a second ionomer that has a melt flow rate of about 10 g/10 min or less.

摘要翻译： 安全层压板包括中间层，其包含作为前体酸共聚物的中和物的离聚物。 前体酸共聚物包含具有2至10个碳原子的第一α-烯烃和约20至约30重量％的具有3-8个碳原子的第一个α，β-烯属不饱和羧酸的共聚单元的共聚单元; 并具有约10至约4000g / 10min的熔体流动速率。 当中和至约40％至约90％的水平时，当包含基本上由钠阳离子组成的抗衡离子时，前体酸共聚物产生熔体流动速率为约0.7至约25g / 10min的钠离聚物， 不可检测的或低于约3.0J / g的冷冻焓。 离聚物组合物还可以包含熔体流动速率为约10g / 10分钟或更短的第二离聚物。

公开(公告)号：US08399098B2

公开(公告)日：2013-03-19

申请号：US12610701

申请日：2009-11-02

申请人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

发明人： Stephen J. Bennison ,  Richard Allen Hayes ,  Steven C. Pesek ,  W Alexander Shaffer ,  Charles Anthony Smith

IPC分类号： B32B27/32 ,  B32B27/36 ,  B32B27/08 ,  B32B27/00 ,  B32B27/40 ,  B32B17/10 ,  C08F20/06 ,  C08F8/00 ,  C08L31/00

CPC分类号： B32B17/10743 ,  B32B17/10018 ,  B32B2367/00 ,  Y10T428/31507 ,  Y10T428/31573 ,  Y10T428/31645 ,  Y10T428/3175 ,  Y10T428/31797 ,  Y10T428/31913 ,  Y10T428/31938

摘要： A laminate comprises an ionomeric interlayer sheet which, in turn, comprises or is prepared from a sodium/zinc mixed ionomer that comprises carboxylate groups and a combination of counterions that consists essentially of sodium cations and zinc cations. The sodium/zinc mixed ionomer is the neutralization product of a precursor acid copolymer. The precursor acid copolymer comprises copolymerized units of an α-olefin and an α,β-ethylenically unsaturated carboxylic acid, and it has a melt flow rate of about 70 to about 1000 g/10 min. In addition, the precursor acid copolymer, when neutralized to a level of about 40% to about 90%, and when comprising counterions that consist essentially of sodium ions, produces a sodium ionomer that has a freeze enthalpy that is not detectable or that is less than about 3.0 j/g, when determined by differential scanning calorimetry.

摘要翻译： 层压材料包括离聚物中间层片材，其又包含钠盐/锌混合离子交换聚合物或由钠/锌混合离聚​​物制备，所述钠/锌混合离聚​​物包含羧酸根基团和基本上由钠阳离子和锌阳离子组成的抗衡离子的组合。 钠/锌混合离聚​​物是前体酸共聚物的中和产物。 前体酸共聚物包括α-烯烃和α，β-烯键式不饱和羧酸的共聚单元，其熔体流动速率为约70至约1000g / 10min。 此外，当将前体酸共聚物中和至约40％至约90％的水平时，并且当包含基本上由钠离子组成的抗衡离子时，产生具有不可检测或较少的冷冻焓的钠离聚物 当用差示扫描量热法测定时，约为3.0J / g。

公开(公告)号：US07919175B2

公开(公告)日：2011-04-05

申请号：US12618036

申请日：2009-11-13

申请人： Stephen J. Bennison ,  David F. Kristunas ,  Andres Ovalle

发明人： Stephen J. Bennison ,  David F. Kristunas ,  Andres Ovalle

IPC分类号： B32B7/02 ,  B32B17/10

CPC分类号： B32B17/10761 ,  B32B17/10045 ,  B32B17/10743 ,  B32B2369/00 ,  F41H5/0407 ,  Y10T428/24967 ,  Y10T428/26 ,  Y10T428/263 ,  Y10T428/269 ,  Y10T428/31507 ,  Y10T428/31525 ,  Y10T428/31533 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31601 ,  Y10T428/31612 ,  Y10T428/31616 ,  Y10T428/31627 ,  Y10T428/3163 ,  Y10T428/31638 ,  Y10T428/31645 ,  Y10T428/31649

摘要： Provided is a transparent and light-weight ballistic resistant safety glazing comprising an ionomer sheet. The ionomer sheet comprises an ionomer derived from a parent acid copolymer that comprises copolymerized units of an α-olefin having 2 to 10 carbon atoms and, based on the total weight of the acid copolymer, about 20 to about 30 wt % of copolymerized units of an α,β-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms. The ionomer is neutralized to a level of about 5% to about 90%, based on the total carboxylic acid content of the acid copolymer, and further comprises at least one cation. Further provided are articles comprising the light-weight ballistic resistant safety glazing.

摘要翻译： 提供了包含离聚物片的透明和轻质防弹安全玻璃。 离聚物片材包含衍生自母体酸共聚物的离聚物，其包含具有2至10个碳原子的α-烯烃的共聚单元，并且基于酸共聚物的总重量，约20至约30重量％的共聚单元 具有3-8个碳原子的α，β-烯属不饱和羧酸。 基于酸共聚物的总羧酸含量将离聚物中和至约5％至约90％的水平，并且还包含至少一种阳离子。 还提供了包括轻质防弹安全玻璃的物品。